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AP Chemistry Thermodynamics Test Review

Total questions: 60

Worksheet time: 1hrs 20mins

Name
Class
Date
1.

Which change is exothermic?

a)

negative delta H

b)

heat is absorbed by system

c)

temperature decreases

d)

bubbles form

2.

Which is exothermic?

a)

temperature decreases

b)

heat is released by system

c)

liquid changes to gas

d)

products are at higher energy than reactants

3.

which is exothermic?

a)

temperature decreases

b)

breaking bonds

c)

system releasing heat to surroundings

d)

chemical reaction

4.

Which is NOT endothermic

a)

positive delta H

b)

heat is a reactant

c)

heat is right of arrow

d)

bonds breaking

5.

which is endothermic?

a)

IMFs broken

b)

negative delta H

c)

products are lower energy than reactants

d)

temperature increases

6.

Which is endothermic?

a)

bonds formed

b)

phase change gas --> liquid

c)

temperature increases

d)

positive delta H

7.

Which change is the MOST exothermic?

a)

condensing

b)

vaporizing

c)

fusion

d)

solidification

8.

Which changes is the MOST endothermic?

a)

Condensing

b)

Vaporizing

c)

Fusion

d)

Solidification

9.

Which substance would be able to absorb the most energy if each sample experiences the same temperature change?

a)

50 grams of aluminum

b)

5 grams of aluminum

c)

150 grams of aluminum

d)

1000 gram of aluminum

10.

Which substance would experience the biggest temperature change if each sample absorbed the same energy?

a)

100 grams of water

b)

25 grams of water

c)

5 grams of water

d)

2500 grams of water

11.

heat released

a)

exothermic

b)

endothermic

12.

bonds broken

a)

exothermic

b)

endothermic

13.

temperature increases

a)

exothermic

b)

endothermic

14.

products have lower potential energy than reactants

a)

exothermic

b)

endothermic

15.

condensing

a)

exothermic

b)

endothermic

16.

bonds form

a)

exothermic

b)

endothermic

17.

negative delta H

a)

exothermic

b)

endothermic

18.

2NaCl + 35 kJ --> 2Na + Cl2

a)

exothermic

b)

endothermic

19.

positive delta H

a)

exothermic

b)

endothermic

20.

temperature decreases

a)

exothermic

b)

endothermic

21.

The specific heat of liquid bromine is 0.2 J/gK. How much heat is required to raise the temperature of 100. grams of bromine from 15 K to 25 K?

a)

30 J

b)

500 J

c)

20 J

d)

200 J

22.

The specific heat of liquid bromine is 0.20 J/gK. What is the MOLAR heat capacity of this substance?

a)

32 J/gK

b)

16 J/gK

c)

9.0 J/gK

d)

0.23 J/gK

23.

What is the FINAL temperature of a 10.0 gram sample of water, at 25 C, if it absorbs 100 calories of heat? Specific heat of water is 1 calorie/gC

a)

15

b)

25

c)

35

d)

25,000

24.

The specific heat of water is 1 calorie/g C. What is the molar heat capacity?

a)

18 calorie/mol C

b)

0.056 calorie/mol C

c)

4.2 calorie/mol C

d)

76 calorie/mol C

25.

How much heat is released when 36 grams of water is frozen at 0 C? The heat of solidification is 6.02 kJ/mol.

a)

18 kJ

b)

220 kJ

c)

12 kJ

d)

2 kJ

26.

What is the heat of fusion, in kJ/g, if 150 gram sample absorbs 750 kJ when it melts at a constant temperature?

a)

900 kJ/g

b)

0.20 kJ/g

c)

110,000 kJ/g

d)

5.0 kJ/g

27.

Which phase change would have the most negative value for the same substance?

a)

heat of fusion

b)

heat of solidification

c)

heat of vaporization

d)

heat of condensation

28.

The enthalpy change for 2Na + Cl2 --> 2NaCl is -35 kJ. What is the heat of reaction for 2NaCl --> 2Na + Cl2

a)

- 35 kJ

b)

35 kJ

c)

70 kJ

d)

- 70 kJ

29.

The heat of reaction for 2H2 + O2 --> 2H2O is -40 kJ. What is the heat of reaction for H2O --> H2 + 1/2 O2?

a)

- 40 kJ

b)

20 kJ

c)

- 80 kJ

d)

80 kJ

30.

2H2O + 25 kJ --> 2H2 + O2 How much energy is absorbed when 36 grams of water is decomposed?

a)

25 kJ

b)

50 kJ

c)

12.5 kJ

d)

900 kJ

31.

How much heat is released when 3 moles of methane is reacted? CH4 + O2 --> CO2 + H2O + 80 kJ

a)

1300 kJ

b)

0.038 kJ

c)

27 kJ

d)

240 kJ

32.

4500 kJ of energy was produced. How many moles of oxygen were created? 2CO2 --> 2CO + O2 + 100 kJ

a)

4400 moles

b)

32 moles

c)

45 moles

d)

2.2 moles

33.

What is the heat capacity for 50 grams of copper if the specific heat is 0.3 J/gC?

a)

6.0 J/C

b)

170 J/C

c)

15 J/C

d)

64 J/C

34.

Which would have the highest heat capacity?

a)

50 grams of Al, Cp = 4.7 J/gK

b)

50 grams of H2O, Cp = 4.2 J/gK

c)

50 grams C, Cp = 0.78 J/gK

d)

50 grams of Cu, Cp = 0.39 J/gK

35.

Which has the HIGHEST entropy change?

a)

1 --> 2 particles

b)

gas --> liquid

c)

solid --> gas

d)

low to high temperature (same phase)

36.

Entropy is always ________ in the Universe

a)

increasing

b)

decreasing

c)

constant

37.

Which is a positive sign for S

a)

decrease in entropy

b)

solidification

c)

1 --> 2 particles

d)

decreasing volume for a gas

38.

Which has a negative sign for S?

a)

water evaporating

b)

NaCl dissolving in water

c)

water freezing

d)

sublimation of CO2

39.

Which has a positive sign for S?

a)

2Na (s) + Cl2 (g) --> 2NaCl (s)

b)

H2O (g) --> H2O (l)

c)

H+ (aq) + NO3- (aq) --> HNO3 (l)

d)

CaCl2 (s) --> Ca2+ (aq) + 2Cl- (aq)

40.

C2H6 (g) --> C2H4 (g) + H2 (g)

a)

+ delta S

b)

- delta S

41.

water turning into steam

a)

+ delta S

b)

- delta S

42.

a mixture of gases is separated into 2 different containers

a)

+ delta S

b)

- delta S

43.

reaction is spontaneous

a)

- delta G

b)

+ delta G

44.

reaction is ALWAYS spontaneous

a)

- H, - S

b)

+ H, + S

c)

+ H, - S

d)

- H, + S

45.

reaction is NEVER spontenous

a)

exothermic, decrease in entropy

b)

exothermic, increase in entropy

c)

endothermic, decrease in entropy

d)

endothermic, increase in entropy

46.

spontaneous reaction means

a)

reaction is fast

b)

reaction occurs

c)

reaction is exothermic

d)

delta G is positive

47.

a reaction that is exothermic and has a decrease in entropy is

a)

spontaneous at high temps

b)

spontaneous at low temps

c)

always spontaneous

d)

never spontaneous

48.

a reaction that is exothermic and has an increase of entropy

a)

is spontaneous at high temps

b)

is spontaneous at low temps

c)

is always spontaneous

d)

is never spontaneous

49.

enthalpy is

a)

H

b)

G

c)

S

d)

E

50.

entropy is

a)

H

b)

S

c)

G

d)

E

51.

enthalpy is driving force when

a)

exothermic

b)

endothermic

c)

increase in entropy

d)

decrease in entropy

52.

entropy is the driving force when

a)

exothermic

b)

endothermic

c)

entropy increasing

d)

entropy decreasing

53.

endothermic and decrease in entropy is spontaneous at

a)

high temps

b)

low temps

c)

never spontaneous

d)

always spontaneous

54.

If a reaction occurs, then delta G is

a)

negative

b)

positive

c)

can't tell

d)

0

55.

An endothermic reaction that experiences an increase in entropy is

a)

always spontaneous

b)

never spontaneous

c)

spontaneous at HIGH temps

d)

spontaneous at LOW temps

56.

an exothermic reaction is not spontaneous at high temps. what can you say about entropy?

a)

negative S

b)

positive S

57.

How can you make an enthalpy driven reaction spontaneous?

a)

You can't

b)

increase temps

c)

decrease temps

d)

it's always spontaneous

58.

How can you make an entropy driven reaction spontaneous?

a)

increase temps

b)

decrease temps

c)

you can't

d)

it's always spontaneous

59.

What are the signs on G, H, and S if a solid is combined with another solid, a gas forms and the temperature drops?

a)

+, +, +

b)

- , - , -

c)

- ,+, +

d)

+ , +, -

60.

What is the driving force of a reaction that has a + H and a + S?

a)

temperature

b)

enthalpy

c)

entropy

d)

this reaction is never spontaneous