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Chapter 6 HPLC

Total questions: 14

Worksheet time: 8mins

Name
Class
Date
1.

HPLC methods include

a)

liquid/liquid (partition) chromatography

b)

liquid/solid (adsorption) chromatography

c)

ion exchange nd size exclusion chromatography

d)

all of the option correct

2.
The substance in the mixture that has the greatest affinity for the mobile phase will travel
a)
fastest
b)
slowest
3.
Which of the following can be used to find the concentration of a substance in HPLC
a)
Rf value
b)
Rt value
c)
peak area
d)
peak width
4.
What two properties affect the Rt of a compound?
I Size/weight
II Polarity
III melting point
a)
I only
b)
II only
c)
III only
d)
I and II
5.
In order to compare to chromatograms what must be kept the same?
a)
stationary  phase
b)
mobile phase
c)
temperature
d)
all of the above
6.

Based on a normal chromatography, the stationary phase is polar.

a)

TRUE

b)

FALSE

c)

Depends on the substance

7.

What does 'normal phase' means?

a)

Polarity of the mobile phase is higher than stationary phase

b)

Both stationary and mobile phase have the same polarity

c)

Polarity of the stationary phase is higher than mobile phase

8.

Which one of these do not associate with the HPLC component?

a)

UV detector

b)

Pump

c)

Degasser

d)

Atomizer

9.

Choose the wrong characteristics of the eluent that can be used in the HPLC

a)

Must be pure

b)

Can be used without degassing

c)

Must complied to HPLC standard

d)

May have constant or gradient polarity

10.

Choose the wrong statement regarding the column.

a)

Usually made of stainless steel material

b)

Packing materials commonly used are silica or resin

c)

Longer column will give longer time for the mixture to separate and thus gives better resolution

d)

Higher column ID can provide higher separation sensitivity

11.

Which one of these that is not the common detector in HPLC?

a)

Infra Red

b)

Ultraviolet light

c)

Flourescent

d)

Mass Spectroscopy

12.

What can be done to optimize the separation?

a)

Adjusting operational variables

b)

Careful selection of the column format

c)

Calibration of the HPLC before conducting any analysis

d)

Selecting the optimum temperature for the separation

13.
A low retention time indicates
a)
a high affinity to the mobile phase
b)
a low affinity to the stationary phase
c)
a high solubility in the mobile phase
d)
all of the above
14.

Which one of these that can't be detected by HPLC?

a)

Functional groups

b)

Molecular structure

c)

Polar compound

d)

Non polar compound