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mass spectrometry

Total questions: 16

Worksheet time: 9mins

Name
Class
Date
1.
What are the steps of operation in the mass spectrometer?
a)
Accelerate, Deflect,Ionize, Detect
b)
Deflect,Ionize, Accelerate, Detect
c)
Ionize, Accelerate, Deflect, Detect
d)
Detect, Accelerate, Deflect, Ionize
2.
Which species would get deflected by the greatest degree in the mass spectrometer?
a)
12C+
b)
13C+
c)
13C2+
d)
14C+
3.
What do the heights of the peaks represent in the mass spectrum?
a)
number of isotopes
b)
relative abundance of each isotope
c)
average atomic mass
d)
charge:mass ratio
4.
How many isotopes are shown in this mass spectrum?
a)
1
b)
84
c)
86
d)
4
5.
What do you expect the molar mass to be for this element?
a)
91.4 g/mol
b)
90.0 g/mol
c)
4 g/mol
d)
50. g/mol
6.
Based on the mass spectrum, which isotope of chlorine is most abundant?
a)
35Cl
b)
37Cl
c)
70Cl
d)
72Cl
7.
Where is the base peak?
a)
57 amu
b)
29 amu
c)
72 amu
d)
43 amu
8.
What kind of particles are used in mass spectrometry?
a)
Anions
b)
Cations
9.

What substance does this mass spectra represent?

a)

hexane

b)

pentane

c)

butane

d)

pentene

10.

What cation does the "83" peak represent?

a)

CH3COCHC

b)

CH3COCHCCH2

c)

CH3COCHCCH3

d)

CH3COC

11.

In this mass spectra what does the M+1 and M+2 peaks represent?

a)

They represent the molecular ion that contains C isotope 13 and 14.

b)

They represent other fragments of the molecular ion.

c)

They represent the base peak.

d)

They represent isotopes of Carbon (13 and 14).

12.

What does the M+2 peak represent?

a)

The mass spectra is not for 2-chloropropane

b)

The M+2 peak is wrong.

c)

80 is the molecular mass of the 2-chloroproane where Cl is isotope 35

d)

80 is the molecular mass of the 2-chloroproane where Cl is isotope 37

13.

What is an analytical technique?

a)

A procedure that uses machines.

b)

A procedure that allows you to investigate a known compound

c)

A procedure that allows you to investigate an unknown substance and discover its identity.

d)

A procedure that allows you to discover new elements.

14.

What ratio does the mass spectrometer detect?

a)

mass of main radical

b)

mass of molecular ion

c)

charge to mass ratio

d)

mass to charge ratio

15.

What species does the molecular ion break down to?

a)

Cations

b)

Radical and cation

c)

Radicals

d)

Radical and anion

16.

Why do the fragments help us to identify the molecule?

a)

The cations allow us only to identify the molecular mass.

b)

It is not possible to identify the exact final molecule.

c)

Because knowing all possible fragments help us to identify branches and possible isomers.

d)

Because the fragments allow us to identify the different atoms that make up the molecule.