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Unit 6: Thermodynamics

Total questions: 25

Worksheet time: 17mins

Name
Class
Date
1.

643 Joules of heat are generated and 321 Joules of work are done on the system during a chemical reaction. Calculate the change in the internal energy of the chemical system.

a)

-322 Joules

b)

322 Joules

c)

643 Joules

d)

964 Joules

2.

A chemical reaction is run in which 513 Joules of heat are absorbed and the internal energy changes by +1234 Joules. Calculate "w" for the system.

a)

-721 Joules

b)

721 Joules

c)

1747 Joules

d)

1026 Joules

3.

If 200 kJ of energy are evolved in a reaction, is this reaction endothermic or exothermic and what is the value of "q"?

a)

exothermic; 200 kJ

b)

exothermic; -200 kJ

c)

endothermic; 200 kJ

d)

endothermic; -200 kJ

4.

Does this image depict an exothermic or endothermic reaction

a)

exothermic

b)

endothermic

5.

Which energy diagram, A or B, depicts a reaction with a positive value of H?

a)

A

b)

B

6.

What is the energy change when the temperature of 13.6 grams of gaseous nitrogen is decreased from 31.2 C to 23.2 C?


Specific heat of nitrogen: 1.04 J/g*C

a)

-109 J

b)

769 J

c)

-113 J

d)

113 J

7.

When a sample of gaseous nitrogen is heated, 313 Joules of energy are added to a 12.4 gram sample and the final temperature is 24.7 C. What is the initial temperature of the nitrogen?


Specific heat of nitrogen: 1.04 J/g*C

a)

-0.429 C

b)

95700 C

c)

0.429 C

d)

24.7 C

8.

A 47 gram aluminum spoon (specific heat 0.88 J/g*C ) at 29 C is placed in 185 grams of water (specific heat 4.184 J/g*C) at 90 C and the temperature of the two become equal. What is the final temperature when the two become equal?

a)

93 C

b)

87 C

c)

-93 C

d)

-87 C

9.

A 70 gram copper fork (specific heat 0.386 J/g*C ) at 20 C is placed in 170 grams of water (specific heat 4.184 J/g*C ) at 80 C and the temperature of the two become equal. What is the final temperature when the two become equal?

a)

82 C

b)

78 C

c)

-82 C

d)

-78 C

10.

During an experiment, the teacher discovers that it takes 240 Joules to increase the temperature of 12.0 grams of solid aluminum from 25.4 C to 40.1 C. Calculate the specific heat of aluminum from her experiment.

a)

1.36 J/g*C

b)

3.66 J/g*C

c)

0.900 J/g*C

d)

-1.36 J/g*C

11.

How many Joules are needed to heat 463 grams of liquid water from 0 C to 100 C?


Specific heat capacity of water: 4.184 J/g*C

a)

-193700 Joules

b)

193.7 Joules

c)

197300 Joules

d)

193700 Joules

12.

How many Joules are required to heat 120 grams of water from 20 C to 130 C?


Specific heat of water: 4.184 J/g*C

Specific heat of steam: 2.02 J/g*C

Heat of vaporization: 2260 J/g

a)

318600 J

b)

311400 J

c)

278500 J

d)

47440 J

13.

How many Joules are released by the water when the temperature of 15.0 grams is changed from 20.0 C to 10.0 C?


Specific heat of water: 4.184 J/g*C

a)

62.8 J

b)

-628 J

c)

628 J

d)

150 J

14.

How many kJ are required to heat 80 grams of water from -40C to 150C ?


Specific heat of ice: 2.06 J/g*C

Heat of fusion: 334 J/g

Specific heat of water: 4.184 J/g*C

Heat of vaporization: 2260 J/g

Specific heat of water vapor: 2.02 J/g*C

a)

1128000 kJ

b)

-1128000 kJ

c)

1128 kJ

d)

-1128 kJ

15.

CH4(g) + 2O2(g) --> CO2(g) + 2H2O(g)

Calculate the standard enthalpy of reaction and is the reaction exothermic or endothermic.


Standard enthalpies:

CH4: -75 kJ/mol

O2: 0 kJ/mol

CO2: -394 kJ/mol

H2O: -284 kJ/mol

a)

-887 kJ ; exothermic

b)

-887 kJ ; endothermic

c)

887 kJ ; exothermic

d)

887 kJ ; endothermic

16.

2NO(g) + O2(g) --> 2NO2(g)

Calculate the enthalpy of formation and if the reaction is endothermic or exothermic.


Enthalpies of formation:

O2(g): 0 kJ/mol

NO(g): 90.25 kJ/mol

NO2(g): 33.18 kJ/mol

a)

114.1 kJ ; endothermic

b)

114.1 kJ ; exothermic

c)

-114.1 kJ ; endothermic

d)

-114.1 kJ ; exothermic

17.

2H2(g) + O2 --> 2H2O(g)

Using the average bond enthalpies below, calculate the change in enthalpy.


H--H : 436 kJ/mol

O2 : 495 kJ/mol

O--H : 463 kJ/mol

a)

-485 J

b)

485 kJ

c)

-485 kJ

d)

-441 kJ

18.

CH4(g) + Cl2(g) --> CH3Cl(g) + HCl(g)

Using the average bond enthalpies below, calculate the change in enthalpy.


C--H: 413 kJ/mol

Cl--Cl : 242 kJ/mol

C--Cl : 328 kJ/mol

H--Cl : 431 kJ/mol

a)

-104 kJ

b)

104 kJ

c)

104 J

d)

-104 J

19.

The standard enthalpy for the reaction below is 940 kJ at 298 K.

TiO2(s)--> Ti(s) + O2(g)


What is the standard enthalpy change at 298 K for the reaction below?

2Ti(s) + 2O2(g) --> 2TiO2(s)

a)

940 kJ

b)

-940 kJ

c)

1880 kJ

d)

-1880 kJ

20.

The standard enthalpy change at 298 K for the reaction below is 92.2 kJ.

2NH3(g)--> N2(g) +3 H2(g)


What is the standard enthalpy change at 298 K for the reaction below?

1/2 N2(g) + 3/2 H2(g) --> NH3(g)

a)

-46.1 kJ

b)

46.1 kJ

c)

92.2 kJ

d)

-92.2 kJ

21.

(1.) 2HgO(s) --> 2Hg(l) + O2(g) {standard enthalpy is 181.6 kJ}

(2.) HgCl2(s) --> Hg(l) + Cl2(g) {standard enthalpy is 224.3 kJ}


What is the standard enthalpy change for the reaction below?

(3.) 2HgCl2(s) + O2(g) --> 2HgO(s) + 2Cl2(g)

a)

267 kJ

b)

-267 kJ

c)

630 kJ

d)

42.7 kJ

22.

(1.) 2PbO(s) --> 2Pb(s) + O2(g) {standard enthalpy change is 434.6 kJ}

(2.) 2Zn(s) + O2(g) --> 2ZnO(s) {standard enthalpy change is -696.6 kJ}


What is the standard enthalpy change for the reaction below?

(3.) PbO(s) + Zn(s) --> Pb(s) + ZnO(s)

a)

131 kJ

b)

-131 kJ

c)

-262 kJ

d)

86.3 kJ

23.

Which image (A, B, or C) depicts the system with the greatest average kinetic energy?

a)

A

b)

B

c)

C

24.

True or False : The colder the temperature, the lower the average kinetic energy.

a)

True

b)

False

25.

True or False : At thermal equilibrium, the average kinetic energy of both bodies are the same, so the temperatures of both bodies are the same.

a)

True

b)

False