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Chemistry AS Module 4.2 Foundations

Total questions: 20

Worksheet time: 10mins

Name
Class
Date
1.

What type of alcohol is this?

a)

Primary

b)

Secondary

c)

Tertiary

2.

Select the true statements about alcohols:

a)

Hydrogen bonding occurs between alcohol molecules

b)

Alcohols have a lower boiling point compared to the corresponding alkane

c)

Long carbon chain alcohols are soluble in water

d)

Alcohol are less volatile compared to the corresponding alkane

3.

What is the product from heating a secondary alcohol under reflux?

a)

Carboxylic acid

b)

Ketone

c)

Tertiary alcohol

d)

aldehyde

4.

What observation is made when a primary or secondary alcohol is oxidised using acidified potassium dichromate?

a)

Colour change from green to orange

b)

Colour change from orange to green

c)

Colour change from red to green

d)

Colour change from blue to yellow

5.

What ester is formed when ethanoic acid reacts with methanol?

a)

Methy ethyl ester

b)

Ethyl methanoate

c)

Methyl ethanoate

d)

Propanoic ester

6.

When alcohols are heated with a strong acid, what type of compound is formed?

a)

Ketone

b)

Alkene

c)

Alkane

d)

Aldehyde

7.

Haloalkanes can react with OH- to form alcohols. What type of reaction is this called?

a)

Electrophilic addition

b)

Electrophilic substitution

c)

Nucleophilic addition

d)

Nucleophilic substitution

8.

The rate of hydrolysis is fastest for which haloalkane?

a)

1-Fluorobutane

b)

1-chlorobutane

c)

1-bromobutane

d)

1-iodobutane

9.

What technique is shown here:

(a)  

10.

A separating funnel is used to:

a)

separate miscible liquids

b)

Separate a solid from a liquid

c)

separate immiscible liquids

d)

To remove water from the product

11.

What functional group would be tested for when using silver nitrate, ethanol and water?

a)

unsaturated hydrocarbon

b)

haloalkane

c)

carbonyl

d)

alcohol

12.

If Tollen's reagent is added to a compound and it forms a silver mirror, what functional group is present?

a)

Ketone

b)

aldehyde

c)

carboxylic acid

d)

alcohol

13.

Select all possible ways a haloalkane can be prepared:

a)

Radical substitution of an alkane

b)

dehydration of an alcohol

c)

halogenation of an alkene

d)

substitution of an alcohol

14.

Select all that can be made directly from a primary alcohol:

a)

Aldehyde

b)

Ketone

c)

Carboxylic acid

d)

Haloalkane

15.

What functional group is present in this IR spectrum?

a)

Alcohol

b)

Ester

c)

Carboxylic acid

d)

Ketone

16.

Select all correct wave numbers that would be present in 2-hydroxypentanal

a)

3200–3550 cm–1

b)

2500–3300 cm–1

c)

1640–1750 cm–1

17.

This show the mass spectra of pentane. What is the m/z value?

(a)  

18.

Identify the correct fragment ion shown in a mass spectra that would give a m/z value of 57:

a)

C4H8+

b)

C4H9+

c)

C4H10+

19.

This show a mass spectra for pent-1-ene. Identify what the fragment would be with m/z 27?

a)

H2C=CH2+

b)

HC=CH2+

c)

H2C=CH+

d)

H3C-CH+

20.

Pentane and 2-Methylbutane are structural isomers. Looking at the fragmentation pattern on the mass spectra, what isomer is this most likely to be?

a)

Pentane

b)

2-Methylbutane