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IONIC EQUILIBRIA 1

Total questions: 15

Worksheet time: 19mins

Name
Class
Date
1.

HCO3- ion acts as Bronsted-Lowry acid in the reaction

a)

HCO3(aq)+H3O+(aq)2H2O(l)+CO 2HCO_3^-(aq)+H_3O^+(aq)\rightarrow2H_2O(l)+CO\ _2

b)

HCO3(aq)+H2O(l)H2CO3(aq)+OH(aq)HCO_{3^-}(aq)+H_2O(l)→H_2CO_3(aq)+OH^-(aq)

c)

HCO3(aq)+OH(aq)H2O(l)+CO32(aq)HCO_3^-(aq)+OH^-(aq)→H_2O(l)+CO_3^{2^-}\left(aq\right)

d)

HCO3(aq)+HSO4(aq)H2CO3(aq)+SO42(aq))HCO_3^-(aq)+HSO_4^-(aq)→H_2CO_3(aq)+SO_{4^2}-\left(aq)\right)

2.

The pH value of a solution of NaOH 2.50x10-3 M is

a)

2.60

b)

4.50

c)

11.40

d)

12.30

3.

Calculate the concentration of hydroxide ions in an aqueous solution containing 4.0x10-8 M hydronium ions.

a)

4.0x10-22

b)

2.5x10-7

c)

1.0x10-12

d)

4.0x10-8

4.

The Kb values of the following bases are

C6H7O6- Kb = 1.3x10-10

C2H5NH2 Kb = 5.6x10-4

C5H5N Kb = 1.7x10-9

Choose the arrangement of the conjugate acids of the above bases in order of increasing acidity.

a)

C6H7O6H < C5H5NH+ < C2H5NH3+

b)

C5H5NH+ < C2H5NH3+ < C6H7O6H

c)

C6H7O6H < C2H5NH3+ < C5H5NH+

d)

C2H5NH3+ < C5H5NH+ < C6H7O6H

5.

The following solutions are buffer solutions EXCEPT

a)

NH3 and NH4Cl

b)

HC2H3O2 and NH4C2H3O2

c)

HC2H3O2 and NaC2H3O2

d)

NH3 and (NH4)2SO4

6.

pH of a solution comprising of benzoic acid, C6H5COOH 0.25 M and sodium benzoate, C6H5COONa 0.15 M is

[Ka C6H5COOH = 6.5x10-5]

a)

3.40

b)

3.97

c)

4.41

d)

4.83

7.

Which of the following salts forms an aqueous solution with the lowest pH value?

a)

NH4NO3

b)

Ca(NO3)2

c)

KNO3

d)

Mg(NO3)2

8.

For a titration between sulphuric acid and an aqueous solution of ammonia, the most suitable indicator (with its pH range) is

a)

ethyl red (4.5-6.5)

b)

phenol red (6.7-8.5)

c)

phenolphthalein (8.3-10.0)

d)

alizarin yellow (10.1-12.0)

9.

1. Choose the TRUE statement(s) by referring to the ionisation constants for several bases given.

Base Kb

p 4.3x10-3

q 4.1x10-5

r 6.7x10-4

a)

p is the strongest base

b)

q has the highest pKb value

c)

p, q and r have pH > 9.5

10.

Salt(s) that produce(s) acidic aqueous solution(s) is (are)

a)

 Na2SO4Na_2SO_4   

b)

 Na4NO3Na_4NO_3  

c)

 NaH2PO4NaH_2PO_4  

11.
Which graph shows how pH changes when weak base added to strong acid?
a)
A
b)
B
c)
C
d)
D
12.
Which acid base pair produce the titration curve shown below?
a)
HCI + KOH
b)
HCI + NH3
c)
CH3COOH + KOH
d)
CH3COOH + NH3
13.
What is the volume of weak base 0.1M NH4OH needed to neutralize 25 ml 0.1M weak acid?
a)
12.5 ml
b)
25 ml
c)
50 ml 
d)
more than 25 ml
14.
What are the products of the neutralization shown below?
Ca(OH)2  +  H2CO3  -->  
a)
H2O  +  Ca2CO3
b)
CaO +  CO3
c)
H2O  +  CaCO3
15.

Why is indicator added to a titration?

a)

To test for acids

b)

to show the endpoint

c)

to prove a reaction has happened

d)

to show a colour