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Trial UPS Chapter 6: Chemical Equilibrium

Total questions: 20

Worksheet time: 10mins

Name
Class
Date
1.
What are the two factors to look for when determining if the reaction is at equilibrium?
a)
Forward reaction rate is faster than the reverse and concentrations are equal
b)
Forward and reverse reaction rates are equal and concentration is constant
c)
Forward and revers reaction rates are equal and concentration is equal
d)
Forward reaction rate is faster than the reverse and concentration is equal
2.

For the reaction...

SO2 (g) + O2 (g) ⇌ SO3(g)

If the concentration of SO2 is increased, the equilibrium of the reaction will shift ___________.

a)

left

b)

right

c)

left and right

d)

neither left nor right

3.

For the reaction...

N2 (g) + 3 H2(g) ⇌ 2 NH3 (g)


If the pressure in the system is increased, which substance(s) will increase in concentration?

a)

N2

b)

H2

c)

N2 and H2

d)

NH3

4.
2SO2(g)+O2(g)⇌2SO3(g)
Removing O2(g) will
a)
shift equilibrium right
b)
shift equilibrium left
c)
increase pressure
d)
have no change
5.

Which of the following is NOT true at equilibrium?

a)

The forward and reverse reactions proceed at the same rate.

b)

The concentrations of reactants and products do not change.

c)

The concentration of the reactants is equal to the concentration of the products.

d)

The forward and reverse reactions continue to occur.

6.

H2(g)+Cl2(g)⇌2HCl(g)

The forward reaction is exothermic. What will happen to the equilibrium if the temperature is increased?

a)

equilibrium shifts right

b)

equilibrium shifts left

c)

You cannot predict the effect

d)

no change

7.
At what time the reaction reached equilibrium?
a)
t1
b)
t2
c)
t3
d)
t4
8.

What kind of equilibrium does the reaction below show?

H2(g) +I2(g) ↔ 2HI(g)

a)

Heterogeneous equilibrium, all the reactants and products are in the same physical state.

b)

Homogeneous equilibrium, all the reactants and products are in the same physical state.

c)

Heterogeneous equilibrium, the reactants and products are present in more than one physical state

d)

Homogeneous equilibrium, the reactants and products are present in more than one physical state

9.
Which of the two graphs reaches equilibrium?
a)
The left one.
b)
The right one.
c)
Both of them.
d)
Neither.
10.

Le Chatelier's Principle states that:

a)

a disturbing force must be applied to a system in order for it to reach equilibrium.

b)

when a system at equilibrium is disturbed, a new equilibrium constant is established.

c)

when a chemical system at equilibrium is disturbed, the system shifts in order to minimize the effect.

d)

when a chemical system is at equilibrium it is no longer possible to alter the system.

11.

What is the equilibrium expression for:

Fe3O4(s) + 4H2(g) <=> 3Fe(s) + 4H2O(g)

Kc =

a)

[Fe]3 [H2O]4 / [Fe3O4] [H2]4

b)

[Fe3O4] [H2]4 / [Fe]3 [H2O]4

c)

[H2O]4 / [H2]4

d)

[Fe] [H2O] / [Fe3O4] [H2]

12.

 CO2 (g) + C (s)  2CO (g)CO_2\ \left(g\right)\ +\ C\ \left(s\right)\ \leftrightarrow\ 2CO\ \left(g\right)  
Adding a catalyst will

a)

Shift Left (towards reactants)

b)

Shift Right (towards products)

c)

Speed up the reaction and shift the equilibrium

d)

Speed up the reaction and NOT affect equilibrium

13.

 CO2 (g) + C (s)  2CO (g)CO_2\ \left(g\right)\ +\ C\ \left(s\right)\ \leftrightarrow\ 2CO\ \left(g\right)  
Decreasing the volume

a)

Shift towards the side with LESS moles

b)

Shift towards the side with MORE moles

c)

Speed up the reaction and shift the equilibrium

d)

Speed up the reaction and NOT affect equilibrium

14.
What is the equilibrium-constant expression for 
CO2(g) + H2(g) ↔ CO(g) + H2O(l)
a)
Kc= [CO][H2O] / [CO2][H2]  
b)
Kc= [CO2][H2] / [CO]
c)
Kc= [CO2][H2] / [CO][H2O]
d)
Kc= [CO] / [CO2][H2]  
15.
In the equation Kc = Kp(RT)Δn , the Δn means
a)
The sum of all the moles.
b)
moles of products - moles of reactants
c)
moles of reactants - moles of product
d)
reaction order
16.
For the equilibrium
2SO3(g) ↔ 2SO2(g) + O2(g)
Kc = 4.08x10-3 at 1000K
What is Kp?
a)
3.45 x 105
b)
2.99
c)
0.335
d)
3.4 x 10-5
17.

Which factor will effect the change in equilibrium constant?

a)

Pressure

b)

Concentration

c)

Add inert gas

d)

Temperature

18.

Predict the change in equilibrium position when Ne gas is added at constant volume to an equilibrium system.

a)

Equilibrium position remain unchanged.

b)

Equilibrium shift to the side with more number of moles.

c)

Equilibrium position shift to the right.

d)

Equilibrium shift to the side with less number of moles.

19.

For an endothermic reaction, increasing the temperature

a)

does not shift the equilibrium since K is a constant.

b)

increases the rate of the reverse reaction to form more reactants.

c)

increases the rate of the forward reaction to form more products.

d)

increases the rate of the reverse reaction to form more products.

20.

PCl3 (g) + Cl2 (g) ↔ PCl5 (g) + HEAT

Which of the following causes an increase in equilibrium constant, K?

a)

Increase in pressure

b)

Increase in temperature

c)

Decrease in temperature

d)

Increase the concentration of PCl3