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d-orbital splitting

Total questions: 13

Worksheet time: 16mins

Name
Class
Date
1.

t2g orbitals are

a)

singly degenerated

b)

doubly degenerated

c)

triply degenerated

d)

None

2.

eg orbitals are

a)

singly degenerated

b)

doubly degenerated

c)

triply degenerated

d)

None

3.

The “d” orbitals present on the axes are .............

a)

dxz

b)

dyz

c)

dx2-y2, dz2

d)

dxy

4.

electronic configuration of Fe2+

a)

[Ar] 3d6 4s2

b)

[Ar] 3d6 4s0

c)

[Ar] 3d4 4s2

d)

[Ar] 3d4 4s0

5.

Geometry of sp3d2 hybridization

a)

Tetrahedral

b)

Octahedral

c)

Square planar

d)

trigonal bi pyramidal

6.

Geometry of sp3 hybridization

a)

Tetrahedral

b)

Octahedral

c)

Square planar

d)

Trigonal bi pyramidal

7.

What is the coordination number of Fe in following complex?

K3[Fe(NH3)3Cl3]Cl2

a)

4

b)

6

c)

8

d)

11

8.

What is the charge of central Fe in following complex?

K3[Fe(NH3)3Cl3]Cl2

a)

0

b)

+2

c)

+3

d)

+4

9.

Orbital with high energy in octahedral complexes

a)

eg

b)

t2g

c)

All orbitals energy same

d)

None

10.

Orbitals with high energy in tetrahedral complexes

a)

eg

b)

t2g

c)

All orbitals energy same

d)

None

11.

Electronic configuration of the central metal atom in the following complex [Co(NH3)6]Cl3

a)

t2g3 eg4

b)

t2g6 eg0

c)

t2g6 eg2

d)

t2g3 eg2

12.

Which of the following affect the CFSE value

a)

Geometry

b)

Nature of ligand

c)

Charge on central metal ion

d)

Above all

13.

Which of the following complex has the highest CFSE value   

a)

[FeCl6]3\left[FeCl_6\right]_{ }^{3-}  

 

b)

[Fe(H2O)6]3+\left[Fe\left(H_2O\right)_6\right]^{3+}  

c)

  [Fe(NH3)6]3+\left[Fe\left(NH_3\right)_6\right]^{3+}  

d)

[Fe(CN)6]3[Fe(CN)_6]^{3-}