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Hyperconjugation effect

Total questions: 15

Worksheet time: 8mins

Name
Class
Date
1.

Which of the following is known as Baker-Nathan effect?

a)

Mesomeric effect

b)

Inductive effect

c)

Hyperconjugation

d)

Electromeric effect

2.

Hyperconjugation involves the delocalisation of __________ bond orbital

a)

s

b)

σ

c)

π

d)

p

3.

Number of hyperconjugation structures in isopropyl radical is __________

a)

3

b)

6

c)

9

d)

12

4.

Larger the number of hyperconjugation structures, the stability of free radicals will __________

a)

Increase

b)

Decrease

c)

No relation

d)

It involves Baker-Nathan constant

5.

On increasing what hyperconjugation structures increase?

a)

Stability

b)

Temperature

c)

α carbon

d)

hydrogen attached to α carbon

6.

Ethene is devoid of any alpha hydrogen so hyperconjugation is not possible.

a)

True

b)

False

7.

Find the product of this reaction?

a)

o-isobutyl p-nitro toluene

b)

p-isobutyl o-nitro toluene

c)

p-isobutyl o-nitro phenol

d)

p-isobutyl m-nitro benzene

8.

Which of the following carbocation is most stable

a)
b)
c)
d)
9.

Find out the order of reactivity of the following compound towards electrophilic substitution reaction

a)

methyl benzene

b)

ethyl benzene

c)

iso propyl benzene

d)

tert butyl benzene

10.

No bond resonance is known as

a)

inductive effect

b)

mesomeric effect

c)

hyperconjugation

d)

electromeric effect

11.

Alkyl group are o and p directive because of

a)

inductive effect

b)

resonance

c)

hyperconjugation

d)

electromeric effect

12.

The compound that can be most readily sulphonated is __________

a)

Benzene

b)

Nitro benzene

c)

Toluene

d)

Chorobenzene

13.

In which of the following cases the effect is a special type of hyperconjugation effect?

(also known as the reverse hyperconjugation effect)

a)

3-chloropent-1-ene

b)

2-chlorocyclopentane

c)

2-bromobutane

d)

benzene

14.

Which of the following effect is responsible for shortening of C-C bond adjacent to -C≡N in acetonitrile and the C-C bond adjacent to the -C≡C in propyne?

a)

electromeric effect

b)

inductive effect

c)

mesomeric effect

d)

no bond resonance effect

15.

If R=CH3 then tell which of the following is most stable?

a)

RCH=CR2

b)

R2C=CHR

c)

R2C=CR2

d)

RHC=CRH