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Electrochemistry

Total questions: 12

Worksheet time: 11mins

Name
Class
Date
1.

On the electrolysis of dil. sulphuric acid using Platinum(Pt) electrode, the product obtained at anode will be

a)

O2 gas

b)

H2S gas

c)

SO2 gas

d)

H2 gas

2.

The number of Faradays(F) required to produced 20 g of calcium from molten CaCl2 is (Atomic mass of Ca = 40 g/mol)

a)

2

b)

3

c)

4

d)

1

3.

For the cell reaction :-

2Fe3+(aq) + 2I-(aq) → 2Fe2+(aq) + I2 E0cell = 0.24 V at 298K.

The standard Gibbs energy(ΔrG0) of the cell reaction is [F= 96500 C/mol]

a)

23.16 kJ/mol

b)

-46.32 kJ/mol

c)

-23.16 kJ/mol

d)

46.32 kJ/mol

4.

The molar conductivities are given as

λ0m(H2SO4) = x S cm2 mol-1

λ0m(K2SO4) = y S cm2 mol-1

λ0m(CH3COOK) = z S cm2 mol-1

Molar conductance of λ0m(CH3COOH) = ? S cm2 mol-1

a)

x - y + 2 z

b)

x + y - z

c)

x - y + z

d)

(x-y)/2 + z

5.

The standard electrode potential of E0 (Mn+/ M), values of Al3+/Al, Ag+/ Ag, K+/ K and Cr3+/Cr are -1.66V, 0.80V, -2.93V and -0.74V respectively. The correct decreasing order of reducing power of the metal is

a)

Ag > Cr > Al > K

b)

K > Al > Cr > Ag

c)

K > Al > Ag > Cr

d)

Al > K > Ag> Cr

6.

In the electrochemical cell :

Zn | ZnSO4(0.01M) || CuSO4(1.0M) |Cu. The emf of this Daniel cell is E1. when the concentration of ZnSO4 is changed to 1.0 M and that of CuSO4 changed to 0.01M, the emf of the cell changes to E2. From the followings, which one is the relationship between E1and E2 ? (RT/F = 0.059)

a)

E1 < E2

b)

E1 > E2

c)

E2 = 0 ≠ E1

d)

E1 = E2

7.

The molar conductivity of a 0.5 mol/dm3 solution of AgNO3 with specific conductance of 5.76 x 10-3 S cm-1 at 298 K is

a)

2.88 S cm2/ mol

b)

11.52 S cm2/ mol

c)

0.086 S cm2/ mol

d)

28.8 S cm2/ mol

8.

During electrolysis of molten NaCl, the time required to produce 0.10 mol of chloride gas using a current of 3 ampere is

a)

55 minutes

b)

110 minutes

c)

220 minutes

d)

330 minutes

9.

If the E0cell for a given reaction has a negative value, which of the following gives the correct relationship for the values of ΔG0 ?

a)

ΔG0 > 0

b)

ΔG0 < 0

c)

ΔG0 = 0

d)

ΔG0 > / < 0

10.

Zinc can be coated on iron to produce galvanized iron but the reverse is not possible. It is because

a)

Zinc is lighter than iron

b)

Zinc has lower melting point than iron

c)

Zinc has lower negative electrode potential than iron

d)

Zinc has higher negative electrode potential than iron

11.

The weight of silver(At.wt= 108) displaced by a quantity of electricity which displaces 5600 mL of O2 at STP will be

a)

5.4 g

b)

10.8 g

c)

54.0 g

d)

108.0 g

12.

At 250 C molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54 ohm-1cm2mol-1 and at infinite dilution its molar conductance is 238 ohm-1cm2mol-1. The degree of ionization of ammonium hydroxide at the same concentration and temperature is

a)

4.008 %

b)

40.800 %

c)

2.080 %

d)

20.800 %