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CLASS XII CHEMISTRY (ALCOHOLS, PHENOLS AND ETHERS)

Total questions: 20

Worksheet time: 11mins

Name
Class
Date
1.

What is the functional group of alcohols?

a)

–NH2

b)

–COOH

c)

–CHO

d)

–OH

e)

–NO2

2.
Name the following molecule:
a)
1,3-dimethyl-2-ethyl-1-butanol
b)
2,4-dimethyl-3-ethyl-1-pentanol
c)
2,4-dimethyl-3-ethyl-4-butanol
d)
3-ethyl-4-methyl-2-pentanol
3.

Which group has the following functional group?

a)

hydrocarbon

b)

alchohol

c)

ether

d)

ester

4.

Monochlorination of toluene in sunlight followed by hydrolysis with aq. NaOH yields__________

a)

o-Cresol

b)

p-Cresol

c)

2, 4-Dihydroxytoluene

d)

Benzyl alcohol

5.

The process of converting alkyl halides into alcohols involves_____________

a)

addition reaction

b)

substitution reaction

c)

dehydrohalogenation reaction

d)

rearrangement reaction

6.

Which of the following name reactions produces salicyldehyde?

a)

Kolbe's reaction

b)

Rosenmund reduction

c)

Williamson's synthesis

d)

Reimer Tiemann reaction

7.

Conversion of Salicylic acid to Aspirin is an example of ________

a)

Rearrangement reaction

b)

Esterification reaction

c)

Dehydration reaction

d)

Alkylation reaction

8.

Choose the correct order of acidic strength.

a)

o-nitrophenol < o-cresol < phenol

b)

o-cresol < o-nitrophenol< phenol

c)

o-cresol < phenol < o-nitrophenol

d)

o-nitrophenol< phenolo < cresol

9.

The order of ease of dehydration of primary,secondary and tertiary alcohols is_______________

a)

30 < 20 < 10

b)

20 < 10 < 30

c)

30 > 20 > 10

d)

20 < 30 < 10

10.

Which of the following set of reactants is appropriate for the preparation of t-butyl ethyl ether?

a)

t-butyl chloride and Sodium ethoxide.

b)

Sodium tertiary butoxide and Ethyl chloride

c)

Ethyl chloride and Butyl alcohol

d)

Butyl chloride and Ethyl alcohol

11.

Phenols are more acidic than alcohols because

a)

Phenoxide ion is stablised by resonance

b)

Phenols are more soluble in polar solvents

c)

Phenoxide ion does not exhibit resonance

d)

Alcohols do not lose H atoms at all

12.

Why alcohols have higher boiling point than alkanes?

a)

Alcohols have Van der Waal's forces between the molecules

b)

Alcohols have intermolecular Hydrogern bonding

c)

Alcohols exist as dimers.

d)

Alcohols have intramolecular Hydrogen bonding.

13.

Compound Z is an alcohol. When Z is reacted with conc HCl and ZnCl2, the cloudy solution appear immediately. But when compound Z reacts with acidified KMnO4 , no reaction occurs. What is the compound Z?

a)

Primary alcohol

b)

Secondary alcohol

c)

Tertiary alcohol

d)

Quaternary alcohol

14.

Dehydration of alcohol is an example of

a)

redox reaction

b)

elimination reaction

c)

substitution reaction

d)

addition reaction

15.

Williamson's synthesis gives best results when sodium alkoxide reacts with___________

a)

Primary alkyl halides

b)

Tertiary alkyl halide

c)

Primary alcohol

d)

Tertiary alcohol

16.

Phenol reacts with bromine in CS2 to give

a)

o-bromophenol

b)

m-bromophenol

c)

o-and p-bromophenol

d)

2,4,6-tribromophenol

17.

When phenol is treated with CHCl3 and NaOH the product formed is

a)

benzaldehyde

b)

salicylaldehyde

c)

benzoic acid

d)

salicylic acid

18.

Alkenes convert into alcohols by

(a) hydrolysis by dil. H2SO4

(b) hydration of alkene by alkaline KMnO4

(c) hydrolysis by water vapours and conc. HNO3

(d) hydration of alkene by aqueous KOH

a)

(a) hydrolysis by dil. H2SO4

b)

(b) hydration of alkene by alkaline KMnO4

c)

(c) hydrolysis by water vapours and conc. HNO3

d)

(d) hydration of alkene by aqueous KOH

19.

Which of the following reacts with NaOH to give an alcohol?

a)

(a) Propene

b)

(b) Butene

c)

(c) Ethanal

d)

(d) Methanal

20.

Williamson's synthesis gives best results when sodium alkoxide reacts with___________

a)

Primary alkyl halides

b)

Tertiary alkyl halide

c)

Primary alcohol

d)

Tertiary alcohol