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Thermodynamics

Total questions: 14

Worksheet time: 10mins

Name
Class
Date
1.

A piston–cylinder device contains a liquid–vapor mixture of water at 300 K. During a constant-pressure process, 750 kJ of heat is transferred to the water. As a result, part of the liquid in the cylinder vaporizes. Determine the entropy change of the water during this process.

a)

2.5 kJ/K

b)

25 kJ/K

c)

0.4 K/kJ

d)

40 K/kJ

2.

A heat source at 800 K loses 2000 kJ of heat to a sink at (a) 500 K and (b) 750 K. Determine which heat transfer process is more irreversible.

a)

a

b)

b

3.

Entropy is a measure of the number of ways in which energy is distributed.

a)

True

b)

False

4.

Entropy of a system increases when it gains energy.

a)

True

b)

False

5.

Entropy of a system increases when a reaction increases the number of particles.

a)

True

b)

False

6.

In a spontaneous process, the entropy of the universe decreases.

a)

True

b)

False

7.

We can reverse a spontaneous process by intervening (eg applying heat, using distillation to separate mixtures).

a)

True

b)

False

8.

What information do we need to perform a calculation of Gibbs Free Energy?

a)

Enthalpy of the reaction.

b)

Entropy of the reaction.

c)

The temperature of the reaction in Kelvin.

d)

All of the above are needed.

9.
A reaction has a positive ΔH and a positive ΔS. Which of the following is true?
a)
It will be spontaneous at all temperatures.
b)
It will be nonspontaneous at all temperatures.
c)
It will be spontaneous at low temperatures.
d)
It will be spontaneous at high temperatures.
10.
True/False: The rate of a chemical reaction is unrelated to the spontaneity of the reaction.
a)
True
b)
False
11.

Which of the following situations demonstrates high entropy?

a)

water freezing

b)

water vaporizing

c)

steam condensing to water

12.
ΔH value in an endothermic reaction is a positive number.
a)
True
b)
False
13.
The equation that relates enthalpy, temperature and entropy is
a)
Hess's Law
b)
Second Law of Thermodynamics
c)
Gibbs Free Energy
d)
Calorimetry
14.

Which of the following would have the highest entropy?

a)

A cold solid

b)

A hot liquid

c)

A hot gas

d)

A cold gas