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Chem II/AP Unit 6 Review

Total questions: 23

Worksheet time: 56mins

Name
Class
Date
1.

Which of the following statements is held true about the common-ion effect on the equilibrium of solubility of salt ?

(you may choose more than one answer)

a)

Adding common-ion to the solution containing dissolved salt cause the solubility equilibrium shifts to the formation of undissolved salt

b)

Adding common-ion to the solution containing dissolved salt cause the numerical value of Ksp of corresponding salt changes

c)

Solubility of salt in solution containing common-ion is greater than that of pure water.

2.

Consider a beaker containing 100 ml of water, with solid AgCl on the bottom.


Which of the following statements is held true if NaCl is added to the solution?


(you may choose more than one answer)

a)

The amount of AgCl solid at the bottom of the beaker increases

b)

The amount of AgCl solid at the bottom of the beaker decreases

c)

The concentration of dissolved Ag+ ion in the solution stays the same

d)

The concentration of dissolved Ag+ ion in the solution changes

3.

Which of the following effect increase the solubility of Ca(OH)2 ?


Ca(OH)2(s) ↔ Ca2+(aq) + 2OH-(aq)


(you may choose more than one answer)

a)

Adding solid NaOH

b)

Adding an acid solution

c)

The pH of solution is adjusted to be below 7

d)

Adding solid CaCl2

4.

At which solution will AgBr have the lowest molar solubility ?

(Ksp AgBr =5 x 10-13)


AgBr(s) ↔ Ag+(aq) + Br-(aq)

a)

0.5 M AgNO3 solution

b)

0.5 M NaBr solution

c)

0.5 M AgClO4 solution

d)

0.5 M MgBr2 solution

5.

At which solution will Al(OH)3 have the highest molar solubility ?

(Ksp Al(OH)3 =1.3 x 10-33)


Al(OH)3(s) ↔ Al3+(aq) + 3OH-(aq)

a)

buffered solution of pH 9

b)

0.01 M NaOH solution

c)

0.01 M Sr(OH)2 solution

d)

0.01 M AlCl3 solution

6.

At which solution will Zn(OH)2 have the lowest molar solubility ?

(Ksp Zn(OH)2 =1.2 x 10-27)


Al(OH)3(s) ↔ Al3+(aq) + 3OH-(aq)

a)

buffered solution of pH 12

b)

10-3 M KOH solution

c)

10-3 M ZnCl2 solution

d)

10-2 M ZnSO4 solution

7.
Which of the following shows the correct dissolution reaction for BaCl2?
a)
Ba 2+(aq) + Cl2-(aq) -> BaCl2(s)
b)
BaCl2(aq) -> Ba 2+(aq) + 2Cl-(aq)
c)
 BaCl2(s) -> Ba 2+(aq) + 2Cl-(aq)
d)
Ba 2+(aq) + 2Cl-(aq) -> BaCl2(s)
8.
The correct mathematical expression for finding the molar solubility (s) of Sn(OH)2 is:
a)
2s2 = Ksp
b)
2s3 = Ksp
c)
4s3 = Ksp
d)
8s3 = Ksp
9.
Silver chromate, Ag2CrO4, has a Ksp of 8.96 x 10-12. Calculate the solubility in mol/L of silver chromate.
a)
1.31 x 10-4M
b)
1.65 x 10-4M
c)
2.25 x 10-12M
d)
2.08 x 10-4M
10.
a)

A

b)

B

c)

C

d)

D

e)

E

11.
a)

A

b)

B

c)

C

d)

D

12.

Ascorbic acid, H2C6H6O6(s), is a diprotic acid with K1 = 7.9 × 10–5 and K2 = 1.6 × 10–12. In a 0.005 M aqueous solution of ascorbic acid, which of the following species is present in the lowest concentration?

a)

H3O+(aq)

b)

H2C6H6O6(aq)

c)

HC6H6O6-(aq)

d)

C6H6O62-(aq)

13.

Which point on the titration curve corresponds to the point at which the moles of the added strong base are equal to the moles of the weak acid initially present?

a)

Q

b)

R

c)

S

d)

T

14.

At point P in the titration, which of the following species has the highest concentration?

a)

HA

b)

A

c)

H3O+

d)

OH

15.

What part of the curve corresponds to the optimum buffer action for the acetic acid/acetate ion pair?

a)

Point V

b)

Point Z

c)

Along all of section WY

d)

Along all of section YZ

16.

What is the pH at the equivalence point.

a)

The pH is approximately 5

b)

The pH is approximately 6

c)

The pH is approximately 8

d)

The pH is approximately 9

17.
Which type of titration is shown by this titration curve?
a)
Titration of a strong acid by a strong base 
b)
Titration of a weak acid by a strong base 
c)
Titration of a strong base by a strong acid 
d)
Titration of a weak base by a strong acid
18.
Which acid base pair will produce a pH jump from 2.7 to 11.3 at equivalent point?
a)
HCI and NH3
b)
HCI and NaOH
c)
CH3COOH and NH3
d)
CH3COOH and NaOH
19.
What is the volume of weak base 0.1M NH4OH needed to neutralize 25 ml 0.1M weak acid?
a)
12.5 ml
b)
25 ml
c)
50 ml 
d)
more than 25 ml
20.
Base is titrated with an acid. Which pair have the highest pH at the equivalence point?
a)
NaOH and CH3COOH
b)
NaOH and HNO3
c)
NH3 and HNO3
d)
NH3 and CH3COOH
21.

Which of the following statements ARE TRUE about buffer solution?


(you may choose more than one answer)

a)

pH of buffer solution will never change despite addition of small amount of base or acid

b)

Buffer can be made by mixing weak acid and salt of its conjugate base or by mixing weak base with salt of its conjugate acid

c)

Buffer has acid and base components that can work specifically to resist pH change

d)

the closer the concentration of weak acid to the concentration of it is conjugate base, the less effective the buffer to resist pH change

22.

What is the role of an indicator in a reaction?

a)

To help reactants react successfully.

b)

To bind to the analyte to form a products.

c)

To show when the reaction has reached or past the equivalence point.

d)

To provide a surface for the reaction to occur.

23.

Equal moles of the indicated acids are dissolved in the amounts of water shown in the beakers below. In which solution will the percent ionization of the acid be the lowest?

a)

Beaker 1

b)

Beaker 2

c)

Beaker 3

d)

Beaker 4