Worksheetschemistry 2nd semester test
Total questions: 268
Worksheet time: 2hrs 14mins
A balanced chemical equation allows one to determine the
mole ratio of any two substances in the reaction
energy released in the reaction
electron configuration of all elements in the reaction
mechanism involved in the reaction
Actual yield must be determined by
experiments
calculations
theoretical yield
estimation
How many mole ratios can be correctly obtained from the chemical equation 2Al2O3 (l) ---> 4Al(s) + 3 O2(g)
3
4
6
8
In the equation 2Al2O3(l)-----> 4Al (s) + 3O2 (g), what is the mole ratio of aluminum to oxygen.
10:6
3:4
2:3
4:3
Fewer steps are required to solve stoichiometry problems when
the reactant is given in grams and the product is sought in grams
the reactant is given in moles and the product is sought in moles
the reactant is given in grams and the product is sought in liters
the reactant is given in liters and the product is sought in number of atoms
the participation of reactants in a chemical reaction is controlled by the
limiting reactant
limiting product
excess reactant
excess product
For a chemical reaction, percentage yield represents the
speed
individual steps
efficiency
rate
The limiting reactant of a reaction can be used to calculate the
actual yield
theoretical yield
experimental yield
both (a) and (c)
In most chemical reactions, the amount of product obtained is
equal to the theoretical yield
less than the theoretical yield
more than the theoretical yield
more than the percentage yield
knowing the mole ratio of a reactant and product in a chemical reaction would allow you to determine
the energy released in the reaction
the speed of the reaction
the mass of the product produced from a known mass of reactant
whether the reaction is reversible
If a chemist calculates the maximum amount of product that could be obtained in a chemical reaction, he or she is calculating the
theoretical yield
percentage yield
mole ratio
actual yield
The kinetic-molecular theory of gases assumes that the particles of an ideal gas are separated by great distances. This implies that the gas particles are considered to have no definite
mass
volume
density
energy
According to the equation for the kinetic energy of a moving object, which gas would have the lowest average velocity, assuming all gases are at the same temperature?
O2
H2
H2O
O3
Sublimation involves changing from a
solid to a gas
liquid to a gas
gas to a liquid
gas to a solid
Liquids and solids are much denser than gases because the particles of liquids and solids have a
greater mass
closer arrangement
greater volume
smaller volume
An increase in pressure exerted on a liquid does not compress the liquid as much as the same increase in pressure compresses a gas because
particles are more closely packed in liquids
liquids transmit pressure in all directions
intermolecular forces are stronger in liquids
particles in liquids are in constant movement
When there is a small decrease in temperature, the average kinetic energy of the particles of a liquid
decrease
becomes zero
is not changed
increases
The movements of particles in solids can best be describes as
from point to point
vibrational
not in motion
like a lattice
Amorphous solids behave like liquids at certain temperatures because of their
particle fluidity
incompressibility
high density
random arrangement
Which of the following is true for the melting and freezing points of a pure substance?
the melting point is higher than the freezing point
the melting point is lower than the freezing point
the melting point is the same as the freezing point
there is no relationship between the freezing point and the melting point
A phase diagram related the state of matter, pressure, and
temperature
volume
mass
weight
On a phase diagram, the point at which all equilibrium lines join is the
melting point
boiling point
critical point
triple point
According to the equation KE = 1/2 mv^2, if hydrogen molecules and oxygen molecules are at the same temperature, hydrogen molecules will have
less kinetic energy
more kinetic energy
higher average speeds
lower average speeds
As atmospheric pressure on the surface of a liquid decreases, its boiling point
decreases
increases
remains unchanged
shows no correlation
Which of the following is an assumption of the kinetic-molecular theory of gases?
collisions between gas particles are inelastic
gases consist of closely spaced particles
gas particles move around in an orderly manner
the temperature of a gas depends on the average kinetic energy of the gas particles
If a gas has the same temperature throughout, which gas molecule has the highest average velocity?
O2
H2O
H2
Xe
Rates of effusion of different gases are proportional to their
polarity
particle charge
particle velocities
compressibility
Which states of matter are fluid?
gases and liquids
liquids and solids
gases only
liquids only
A liquid can be described as a form of matter that
has a definite volume
has a definite shape
cannot diffuse
has low density
According to the kinetic-molecular theory, particles in a liquid
are bound together in fixed positions
are packed together in an orderly arrangement
move around randomly and constantly
vibrate only
Which of the following is not an example of an intermolecular force?
hydrogen bonding
dispersion forces
gravitational forces
dipole-dipole forces
Surface tension does not account for which of the following phenomena?
ability to diffuse
meniscus formation
capillary action
decreasing surface area
A liquid becomes a gas during
evaporation
condensation
sublimation
deposition
If energy as heat is removed, most liquids will eventually
freeze
burn
evaporate
diffuse
The three states of matter of a particular substance, in order of the strength of intermolecular forces from least to greatest, are
solid, liquid, gas
liquid, solid, gas
gas, liquid, solid
gas, solid, liquid
What is an example of an amorphous solid?
emerald
quarts
ice
glass
Which of the following is not a physical property of crystalline solids?
definite shape
definite melting point
low rate of diffusion
high compressibility
Which is an example of a polar covalent molecular crystal?
H2O
H2
NaCl
CCl4
The bonds that link water molecules together are said to be
dispersion forces
hydrogen bonds
dipole-dipole forces
don't exist
What is the reason for the relatively low density of ice?
empty spaces between molecules
the high number of hydrogen bonds
the small size of hydrogen and oxygen atoms
the low molar mass of water
Which of the following statements is true?
particles of a gas collide with each other in elastic collisions
particles of a gas collide with their container only
particles of a gas collide with each other in inelastic collisions
particles of a gas never collide
Which is NOT an assumption of the kinetic-molecular theory?
collisions between gas particles are elastic
all gases at a given temperature have the same average kinetic energy
all the gas particles in a sample have the same velocity
a gas particle is not significantly attracted or repelled by other gas particles
A sealed flask contains neon, argon, and krypton gas. If the total pressure in the flask is 3.782 atm, the partial pressure of Ne is 0.435 atm, and the partial pressure of Kr is 1.613 atm, what is the partial pressure of Ar?
1.318 atm
2.048 atm
1.556 atm
1.734 atm
The theory that describes the behavior of gases in terms of the motion of gas particles is ____________.
Dalton's Law of partial pressures
Graham's law of effusion
the kinetic molecular theory
the theory of intermolecular forces
Explain what would happen to the column of mercury in a barometer if the atmospheric pressure fell.
as the pressure falls, the column of mercury will drop lower
as the pressure falls, the density of the mercury will increase
as the pressure falls, the column of mercury will remain unchanged
as the pressure falls, the column of mercury will rise higher
Which of the following molecules can form hydrogen bonds?
CH3
BaH3
NH3
NaH3
In a polar molecule, which atoms will have the greatest partial negative charge?
the smallest atom
the largest atom
the least electronegative atom
the most electronegative atom
Which intermolecular force depends on the formation of a temporary dipole?
ionic bonding
hydrogen bonding
dispersion forces
dipole-dipole forces
The unit cell of a crystalline solid is _____.
determined by the temperature at which a solid forms
always cubic
the building block whose shape determines the shape of the crystal
held together by intramolecular forces
Dry ice is solid carbon dioxide. What combination of factors can change dry ice into a liquid?
increase both temperature and pressure
decrease both temperature and pressure
increase temperature and decrease pressure
decrease temperature and increase pressure
What would the phase of water at a temperature of 110 degrees Celsius and a pressure of 200 atmospheres?
liquid
solid
triple point
gas
In a container filled with one mole of helium and one mole of nitrogen, the pressure in the container is primarily
the pressure exerted by nitrogen
zero
the sum of the pressures exerted by nitrogen and helium
the pressure exerted by helium
Equal volumes of gases at the same temperature and pressure contain equal numbers of particles
Gay-Lussac's Law
Avogadro's principle
Boyle's law
Charles's law
one mole of any gas will occupy a volume of 22.4 L at STP
molar volume
ideal gas law
combined gas law
ideal gas constant
represents the relationship among pressure, volume, temperature, and number of moles of gas present
combined gas law
molar volume
ideal gas law
ideal gas constant
temperature, pressure, and volume are related for a fixed amount of gas
combined gas law
ideal gas law
Boyle's law
Charles's law
the physical behavior of an ideal gas can be expressed in term of the pressure, volume, temperature, and number of moles of gas present
Gay-Lussac's law
combined gas law
ideal gas law
Charles's law
the pressure of a given mass of gas varies directly with the kelvin temperature when the volume remains constant
Gay-Lussac's Law
ideal gas law
Charles's law
Boyle's law
the volume of a given amount of gas held at a constant temperature varies inversely with the pressure
Gay-Lussac's Law
Boyle's Law
Charles's law
Avogadro's principle
the volume of a given mass of gas is directly proportional to its kelvin temperature at constant pressure
combined gas law
Boyle's law
Gay-Lussac's Law
Charles's Law
Volume : increases
Pressure : stays the same
temperature : ______
increases
decreases
stays the same
volume : increases
pressure : ______
temperature : stays the same
increases
decreases
stays the same
volume : stays the same
pressure : increases
temperature : ________
increases
decreases
stays the same
volume : ______
pressure : increases
temperature : stays the same
increases
decreases
stays the same
volume : _______
pressure : stays the same
temperature : increases
increases
decreases
stays the same
volume : stays the same
pressure : ________
temperature : increases
increases
decreases
stays the same
volume : decreases
pressure : stays the same
temperature : ______
increases
decreases
stays the same
volume : decreases
pressure : _________
temperature : stays the same
increases
decreases
stays the same
which instrument measures atmospheric pressure?
barometer
manometer
vacuum pump
torrometer
according to avogadro's law, 1 L of H2(g) and 1 L of O2(g) at the same temperature and pressure
have the same mass
have unequal volumes
contain 1 mole of gas each
contain equal numbers of molecules
what is the percent by mass of NaCl in a solution that contains 17.5 g NaCl per 500.0 g of water?
3.38%
14.8%
3.50%
3.61%
Sucrose dissolves in water because _________
both water and sucrose are polar molecules
both water and sucrose have high melting points
both water and sucrose are molecular compounds
sucrose is an ionic compound
the decrease in solubility of a gas in a solution when the pressure is reduced is described by
the ideal gas law
charles's law
boyle's law
henry's law
H2SO4 is a
diprotic base
diprotic acid
monoprotic acid
monoprotic base
which of the following is a weak acid?
HF
HNO3
HCl
HClO4
Kw is the product of _____________
[H+] and [OH-]
[H20] and [H2O]
[H2O] and [H+]
[H2O] and [OH-]
Calculate the H+ ion and OH- ion concentrations in a 0.50M solution of HBr. Assume HBr is a strong acid.
[H+] = 0.50M and [OH-] = 2.0 x 10^-14
[H+] = 1.0x10^-7 and [OH-] = 1.0 x 10 ^-7
[H+] = 0.50M and [OH-] = 2.0M
[H+]=0.50M and [OH-]= 0.50M
pH is defined as __________
-log[OH-]
-log[H+]
log[H+]
log[OH-]
what is the net ionic equation for the neutralization reaction between HF and KOH?
H+ + KOH --> H2O + K+
K+ + F- --> KF
H+ + OH- ---> H2O
HF + OH- --> H20 + F-
Which of these reactions has the net ionic equation shown below?
H3O+(aq) + OH-(aq) ---> 2 H2O(l)
Ba(NO3)2 + Na2SO4 --> 2NaNO3(aq) + BaSO4(s)
2Na(s) + 2H2O(l) ---> H2(g) + 2NaOH(aq)
KCL(aq) + AhNO3(aq) ---> AgCl(s) + KNO3(aq)
HCL(aq) + NaOH(aq) ---> NaCl (aq) + H2O(l)
17.5 mL of 0.1000M NaOH was required to neutralize 25.0 mL of HCL. What was the molarity of the HCL?
0.0700M HCL
0.0300M HCL
14.3M HCL
3.00M HCL
Which of the properties listed below is not a characteristic of an acid?
a sour taste
a slippery feel
the ability to conduct an electric current
reactivity with metals
Bases taste
sweet
sour
bitter
have no taste at all
How many stages of ionization does phosphoric acid (H3PO4) go through?
one
two
three
four
In the following reaction, NaOH +HF --> NaF + H2O, the salt has ___________ properties.
acidic
basic
neutral
amphoteric
Which of the following compounds is not amphoteric?
H2SO4
H2O
NH3
H2PO4
the process in which an acid-base neutralization reaction is used to determine the concentration of a solution of unknown concentration
titrant
titration
end point
neutralization reaction
a reaction in which an acid and a base react in aqueous solution to produce a salt and water
neutralization reaction
titrant
titration
equivalence point
a chemical dye whose color is affected by acidic and basic solution
end point
titrant
acid-base indicator
titration
the point at which the moles of hydrogen ions from the acid equals moles of hydroxide ions from the base
end point
equivalence point
titration
titrant
a solution of known concentration used to titrate a solution of unknown concentration
titration
end point
titrant
acid-base indicator
the point at which the indicator that is used in a titration changes color
end point
equivalence point
acid-base indicator
titrant
The branch of chemistry that is devoted to the study of carbon compounds is ________
inorganic chemistry
organic chemistry
analytic chemistry
physical chemistry
Which of the following compounds is not organic?
C2H5
CH4
C12H22O11
CO2
What is the name given to a series of compounds that differ from one another by a repeating unit?
hydrocarbon series
homologous series
homogeneous series
heterogeneous series
What kind of organic compounds contain benzene rings as part of their structure?
aromatic compounds
adiabatic compounds
alkalinic compounds
aliphatic compounds
In a branched alkane, each branch attached to the main chain is called a(n) ___.
cycloalkane
substituent group
asymmetric carbon
acetylene group
All organic compounds contain the element nitrogen.
true
false
Butane, pentane, and hexane are members of one homologous series
true
false
a carcinogen is a substance that causes cancer
true
false
Compounds that exist in right and left forms have a property called chirality.
true
false
Isomers have the same molecular formula but different molecular structures.
true
false
a hydrocarbon that contains only single bonds
saturated hydrocarbon
unsaturated hydrocarbon
alkane
cyclic hydrocarbon
An unsaturated hydrocarbon, such as ethyne, with one or more triple bonds between carbon atoms in a chain
alkenes
alkanes
alkynes
cycloalkane
An unsaturated hydrocarbon, such as ethene, with one or more double covalent bonds between carbon atoms in a chain
alkanes
alkenes
cycloalkane
alkynes
Cyclic hydrocarbons that contain single bonds only and can have rings with three, four, five, six, or more carbon atoms
cycloalkane
alkane
cyclic hydrocarbon
saturated hydrocarbon
Nonaromatic hydrocarbons, such as alkanes, alkenes, and alkynes
saturated hydrocarbon
aliphatic compound
aromatic compound
unsaturated hydrocarbon
hydrocarbon that contains only single bonds between atoms
unsaturated hydrocarbons
saturated hydrocarbons
alkens
alkanes
organic compounds that contain one or more benzene rings as part of their molecular structure
aliphatic compounds
aromatic compounds
saturated hydrocarbons
unsaturated hydrocarbons
a hydrocarbon that contains at least one double or triple bond between carbon atoms
alkene
unsaturated hydrocarbon
alkyne
saturated hydrocarbon
an organic compound that contains a hydrocarbon ring
cyclic hydrocarbon
cycloalkane
saturated hydrocarbon
unsaturated hydrocarbon
What is the scientific law that states that matter is not created or destroyed, but only transformed in a chemical reaction?
law of conservation of mass
law of conservation of energy
law of conservation of momentum
law of gravity
What is the first step you must take to solve a stoichiometric problem?
write a balanced chemical equation
find the limiting reactant
find the excess reactant
convert given amounts of each substance to moles
Approximately how many grams of Fe2O3 are present in 0.82 mol Fe2O3?
130 g
160 g
80 g
195 g
In the balanced chemical reaction shown below, what is the molar ratio of O2 to CO2?
C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(g)
5 to 3
3 to 1
5 to 4
4 to 3
How many grams of O2 will be produced if 23.2 g of XeF2 reacts with excess water?
2.19 g
1.10 g
3.31 g
4.42 g
Which reactant in the following reaction is in excess when 9.8 grams of Ca(OH)2 is reacted with 9.8 grams of H3PO4?
Ca(OH)2
H3PO4
Ca3(PO4)2
H20
Which of these is NOT a reason for percent yield to be less than theoretical yield?
Reactants and products might adhere to containers.
Competing reactions might form other products.
Some product may transform completely into energy.
Some product may be lost in the purification process.
What do the coefficients in the following balanced chemical equation mean?
2H2+O2→2H2O
2 moles of hydrogen and 1 mole of oxygen in the reactants
2 moles of oxygen and 1 mole of hydrogen in the reactants
2 moles of oxygen and 1 mole of hydrogen in the products
)2 moles of hydrogen and 1 mole of oxygen in the products
When the following equation is correctly balanced with the smallest whole-number coefficients, what is the coefficient for H2O?
PBr3+H2O→H3PO3+HBr
3
1
2
4
In the balanced chemical equation for the reaction between iron(III) oxide and aluminum, what is the molar ratio of Fe to Al?
Fe2O3+2Al→2Fe+Al2O3
1 to 1
2 to 1
3 to 1
1 to 2
What is the scientific law that states that matter is not created or destroyed, but only transformed in a chemical reaction?
law of conservation of mass
law of conservation of energy
law of conservation of momentum
law of gravity
What is the first step you must take to solve a stoichiometric problem?
Write a balanced chemical equation.
Find the limiting reactant
find the excess reactant
convert given amounts of each substance to moles
Approximately how many grams of Fe2O3 are present in 0.82 mol Fe2O3?
130 g
160 g
80 g
195 g
In the balanced chemical reaction shown below, what is the molar ratio of O2 to CO2?
C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(g)
5 to 3
3 to 1
5 to 4
4 to 3
Based on the following equation, how many moles of hydrochloric acid are needed to react with 0.64 moles of potassium permanganate?
2KMnO4 + 8HCl → 3Cl2 + 2MnO2 + 4H2O + 2KCl
2.6 mol HCL
0.21 mol HCL
0.64 mol HCL
5.1 mol HCL
How many moles of CO2 would be produced from 56 moles of O2 according to the following balanced equation?
2C2H6 + 7O2 → 4CO2 + 6H2O
16 mol
32 mol
224 mol
48 mol
How many moles of HCl will just react with 0.424 g Ba(OH)2?
2HCl + Ba(OH)2 → BaCl2 + 2H2O
4.94 x 10-3 mol
9.90 x 10-3 mol
2.48 x 10-3 mol
1.24 x 10-3 mol
What mass of SrF2 can be prepared from a reaction of 10.0 g Sr(OH)2 with excess HF?
Sr(OH)2 + 2HF → SrF2 + 2H2O
9.67 g
9.82 g
10.0 g
10.3 g
Natural gas is mostly methane, CH4. When 128 grams of methane is burned in the chemical reaction shown below, how many grams of water vapor are produced?
CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)
8.00 g
144 g
18.0 g
288 g
In the chemical reaction below, 3.27 grams of Zn are reacted with 3.30 grams of HCl. Which component will limit the reaction?
Zn + 2HCl → ZnCl2 + H2
Zn
HCl
ZnCl2
H2
Which reactant in the following reaction is in excess when 9.8 grams of Ca(OH)2 is reacted with 9.8 grams of H3PO4?
3Ca(OH)2 + 2H3PO4 → Ca3(PO4)2 + 6H2O
Ca(OH)2
H3PO4
Ca3(PO4)2
H2O
What is the percent yield of CO2 if a reaction using 10.0 g CO with excess O2 produces 12.8 g CO2?
2CO + O2 → 2CO2
76.40%
78.10%
81.50%
84.40%
What is the percent yield for the reaction between 9.8 grams of Ca(OH)2 and 9.8 grams of H3PO4 when 2.5 grams of Ca3(PO4)2 are actually obtained?
3Ca(OH)2 + 2H3PO4 → Ca3(PO4)2 + 6H2O
18%
9.0%
27%
36%
Which of these is NOT a reason for percent yield to be less than theoretical yield?
Reactants and products might adhere to containers.
Competing reactions might form other products.
Some product may transform completely into energy.
Some product may be lost in the purification process.
Stoichiometry is based on the law of conservation of __.
mass
charge
reactants
volume
In a balanced chemical equation, the numbers of individual particles and the numbers of moles of particles are represented by the __.
chemical symbols
molar masses
coeffiecients
subscripts
Mole ratios for a reaction are obtained from the __.
balanced chemical equation
periodic table
molar masses
total mass of products
In the decomposition reaction of compound AB into substances A and B, what is the number of mole ratios that can be formed?
1
3
6
9
Calculating the mass of a reactant and product from the number of moles of another product or reactant in a chemical equation is an example of a __.
mass-to-mass conversion
mole-to-mass conversion
mass-to-mole conversion
mole-to-mole conversion
Limiting a reactant is often accomplished by __.
producing excess product
slowing down a chemical reaction
overcoming conservation of mass
using an excess of another reactant
In a reaction, substances A and B form substance C. If the actual mole ratio of substance B to substance A is less than the balanced equation mole ratio of substance B to substance A, substance B is the __.
actual yield
excess reactant
limiting reactant
product
Percent yield of a product is a measure of a reaction’s __.
efficiency
heat production
rate
spontaneity
The actual yield of a product is __.
a negative value
the same as its theoretical yield
independent of the reactants
measured experimentally
The most important industrial chemical in the world is __.
carbon dioxide
oxygen
petroleum
sulfuric acid
theoretical yield
the maximum amount of product that can be produced from a given amount of reactant in a chemical reaction
the amount of product produced when a chemical reaction is carried out
the ratio of actual yield (from an experiment) to theoretical yield (from stoichiometric calculations) expressed as a percent
actual yield
the maximum amount of product that can be produced from a given amount of reactant in a chemical reaction
the amount of product produced when a chemical reaction is carried out
the amount of product produced when a chemical reaction is carried out
percent yield
the maximum amount of product that can be produced from a given amount of reactant in a chemical reaction
the amount of product produced when a chemical reaction is carried out
the ratio of actual yield (from an experiment) to theoretical yield (from stoichiometric calculations) expressed as a percent
How many particles are present in one mole of particles?
6.02 × 1023
3.0 × 103
1
12
The sucrose molecule is a large and complex molecule built of carbon, hydrogen, and oxygen. How many sucrose molecules are in 0.5 moles of sucrose?
6.02 × 1023
1.20 × 1024
3.01 × 1023
1.20 × 1023
Copper wire consists of copper atoms connected through metallic bonds. Find the moles of copper in 1.87 × 1024 copper atoms.
3.1 moles
1 mole
3 moles
6.02 × 1023
How many moles of chlorine are in 100 g chlorine (Cl2)?
1.41
0.355
64.6
100
Radium is a radioactive element that decays into radon gas. Its atomic mass is 226. How many moles are in 500 grams of radium?
2.2 moles
7.26 moles
3 × 1026 moles
0.452
What is the molar mass of H2CrO4?
118 g/mol
52 g/mol
64 g/mol
148 g/mol
How many moles of C3H8 are present in 451 g C3H8?
10.2 mol
3.84 mol
0.879 mol
1.44 mol
What is the mass of 1.0 × 1012 molecules of O2?
1.9 × 1013 g
6.0 × 1011 g
2.7 × 10−11 g
5.3 × 10−11 g
Acetic acid has the molecular formula CH3COOH. How many atoms of oxygen are there in 60 grams of acetic acid?
6.0 × 1023 atoms of oxygen
1.0 × 1022 atoms of oxygen
3.6 × 1025 atoms of oxygen
1.2 × 1024 atoms of oxygen
How many moles of hydrogen atoms are present in 2.0 moles of ammonia NH3?
3.0 mol
6.0 mol
2.0 mol
What is the percent composition of carbon dioxide, CO2?
27% C and 73% O
73% C and 27% O
33% C and 66% O
50% C and 50% O
Methane (CH4) contains 75% carbon. What percentage of methane is hydrogen?
25%
4%
20%
33%
Analysis of a covalent compound showed that it contained 14.4% hydrogen and 85.6% carbon by mass. What is the empirical formula for this compound?
CH
CH2
CH3
CH4
A sample of a metal salt contains 36.1 % calcium and 63.9 % chlorine. What is the empirical formula?
CaCl
Ca2Cl2
Ca2Cl
CaCl2
The empirical formula for a sample of liquid is HO. The molecular weight is 34.0 grams/mole. What is the molecular formula?
H2O
HO
H2O2
HO2
A 25.0-g sample of an unknown hydrocarbon is composed of 12.16 g carbon, 2.027 g hydrogen, and 10.81 g oxygen. If its molar mass is 148 g/mol, what is the molecular formula for this compound?
C4H10O
C6H12O4
C3H6O2
C8H8O5
What is the correct chemical formula for barium hydroxide octahydrate?
Ba(OH)2 • 8H2O
BaOH • 8H2O
8Ba(OH)2 • H2O
8BaOH • H2O
How many moles of oxygen atoms do 1.5 moles of CO2 contain?
3.0 mol
1.0 mol
1.5 mol
2.0 mol
Which of the following compounds has the smallest molar mass?
CO
CO2
H2O
H2O2
One mole of silicon (Si) has a mass of 28.086 g, and one mole of carbon has a mass of 12.011 g. What is the mass of one mole of silicon carbide (SiC)?
2.340 g
16.075 g
40.097 g
3.3734 × 102 g
Carbon dioxide (CO2) contains 30% carbon. What percentage of carbon dioxide is oxygen?
50%
66%
70%
75%
Sodium bromide dihydrate is correctly written as __.
NaBrH2
(NaBr)2•H2O
NaBr•(HO)2
NaBr•2H2O
As a hydrated compound is heated, it decreases in __.
brightness
color
mass
temperature
The percent composition of carbon is equal to carbon’s atomic mass and has the units g/mol.
true
false
Benzene (C6H6) and acetylene (C2H2) have the same empirical formula but different molecular formulas.
true
false
Which of the following statements is true?
particles of a gas never collide
particles of a gas collide with their container only
particles of a gas collide with each other in elastic collisions
particles of a gas collide with each other in inelastic collisions
The measure of the average kinetic energy of the particles in a sample of matter is
temperature
speed
velocity
heat
Which is NOT an assumption of the kinetic-molecular theory?
Collisions between gas particles are elastic.
All the gas particles in a sample have the same velocity.
A gas particle is not significantly attracted or repelled by other gas particles.
All gases at a given temperature have the same average kinetic energy.
Which of the following gases will diffuse the fastest at room temperature?
Ne
CO2
N2
H2
What is the ratio of diffusion rates for nitric oxide (NO) and nitrogen tetroxide (N2O4)?
0.306
0.571
1.751
3.066
In a container filled with one mole of helium and one mole of nitrogen, the pressure in the container is primarily
the pressure exerted by nitrogen.
the pressure exerted by helium.
the sum of the pressures exerted by nitrogen and helium.
zero.
A sealed flask contains neon, argon, and krypton gas. If the total pressure in the flask is 3.782 atm, the partial pressure of Ne is 0.435 atm, and the partial pressure of Kr is 1.613 atm, what is the partial pressure of Ar?
2.048 atm
1.734 atm
1.556 atm
1.318 atm
The theory that describes the behavior of gases in terms of the motion of gas particles is __.
the theory of intermolecular forces
Graham's law of effusion
Dalton's law of partial pressures
the kinetic molecular theory
What happens to the density of the gas particles in the cylinder as the piston moves from position A to position B?
Density decreases because the gas particles occupy more volume per unit mass.
Density increases because the gas particles occupy less volume per unit mass.
Density remains the same.
There is not enough information to answer the question.
In water's hydrogen bonds, the attraction is between which atoms?
hydrogen atoms in different molecules
hydrogen atoms in one molecule and oxygen atoms in another molecule
hydrogen atoms in the same molecule
hydrogen atoms and oxygen atoms in the same molecule
The phase change that describes the direct conversion of a solid into a gas is __.
vaporization
sublimation
melting
deposition
The point on a phase diagram where the solid state, the liquid state, and the gas vapor state can coexist is __.
the pressure point
the absolute zero point
the critical point
the triple point
The boiling point of a liquid is the temperature at which __.
vapor pressure is greater than atmospheric pressure.
vapor pressure is equal to atmospheric pressure.
vapor pressure is less than atmospheric pressure.
vapor pressure is zero.
pressure
force per unit area
an instrument used to measure atmospheric pressure
measure of the average kinetic energy of the particles in a sample of matter
the movement of one material through another
barometer
the SI unit of pressure, equal to the force of one newton per square meter
a measure of the resistance of a liquid to flow
an instrument used to measure atmospheric pressure
a measure of the average kinetic energy of the particles in a sample of matter
elastic collisions
the SI unit of pressure, equal to the force of one newton per square meter
collisions between gas particles in which no kinetic energy is lost
a measure of the average kinetic energy of the particles in a sample of matter
the energy required to increase the surface area of a liquid by a given amount
pascal
the SI unit of pressure, equal to the force of one newton per square meter
a compound that lowers the surface tension of water
a measure of the resistance of a liquid to flow
a measure of the average kinetic energy of the particles in a sample of matter
viscosity
the movement of one material through another
a compound that lowers the surface tension of water
a measure of the resistance of a liquid to flow
the energy required to increase the surface area of a liquid by a given amount
surface tension
the SI unit of pressure, equal to the force of one newton per square meter
the energy required to increase the surface area of a liquid by a given amount
a measure of the average kinetic energy of the particles in a sample of matter
an instrument used to measure atmospheric pressure
surfactant
the movement of one material through another
a measure of the average kinetic energy of the particles in a sample of matter
a compound that lowers the surface tension of water
force per unit area
melting point
temperature at which a liquid becomes a crystalline solid
temperature at which the vapor pressure of a liquid equals the external or atmospheric pressure
the temperature at which a crystalline solid becomes a liquid
the point on a phase diagram where the solid state, the liquid state, and the gas vapor state can coexist
vapor pressure
a graph that shows in which phase a substance exists under different conditions of temperature and pressure
temperature at which the vapor pressure of a liquid equals the external or atmospheric pressure
the pressure exerted by a vapor over a liquid
the point on a phase diagram where the solid state, the liquid state, and the gas vapor state can coexist
boiling point
temperature at which a liquid becomes a crystalline solid
temperature at which the vapor pressure of a liquid equals the external or atmospheric pressure
the pressure exerted by a vapor over a liquid
the temperature at which a crystalline solid becomes a liquid
freezing point
temperature at which the vapor pressure of a liquid equals the external or atmospheric pressure
the temperature at which a crystalline solid becomes a liquid
a graph that shows in which phase a substance exists under different conditions of temperature and pressure
temperature at which a liquid becomes a crystalline solid
phase diagram
the point on a phase diagram where the solid state, the liquid state, and the gas vapor state can coexist
a graph that shows in which phase a substance exists under different conditions of temperature and pressure
temperature at which the vapor pressure of a liquid equals the external or atmospheric pressure
the temperature at which a crystalline solid becomes a liquid
triple point
the point on a phase diagram where the solid state, the liquid state, and the gas vapor state can coexist
temperature at which the vapor pressure of a liquid equals the external or atmospheric pressure
temperature at which a liquid becomes a crystalline solid
a graph that shows in which phase a substance exists under different conditions of temperature and pressure
The pressure of a sample of helium in a 1.0-L container is 0.857 atm. What is the new pressure if the sample is placed in a 0.5-L container? Assume the temperature is constant.
0.143 atm
0.429 atm
1.38 atm
1.71 atm
A sample of gas is held in a 10.0-L volume piston at 175 kPa. The temperature is kept constant while the volume is decreased until the pressure is 350 kPa. What is the new volume of the gas?
1.0 L
5.0 L
10.0 L
175 L
When will the molecules of all samples of ideal gases have the same average kinetic energies?
at constant volume
at constant temperature
at constant amount
at constant pressure
Which diagram shows the relationship between volume and pressure for a gas at constant temperature?
B
D
E
C
A gas occupies a volume of 1.0 L at 25°C. What volume will the gas occupy at 100°C?
1.0 L
1.3 L
0.80 L
4.0 L
A 0.5-L container of nitrogen gas at 18°C is heated under constant pressure to the boiling point of water. What is its new volume?
0.5 L
0.64 L
0.79 L
0.86 L
At constant volume, a container of gas at atmospheric pressure is heated from 27°C to 77°C. What is the final pressure?
0.35 atm
1.2 atm
0.86 atm
2.8 atm
A sample of gas starts at 1.00 atm, 0.00°C, and 30.0 mL. What is the volume if the temperature increases to 27.0°C and the pressure increases to 2.00 atm?
54.6 mL
65.9 mL
13.7 mL
16.5 mL
What volume will one mole of a gas occupy under standard temperature and pressure?
1 L
22.4 L
273 L
293 l
What is the molar mass of a gas if 0.104 g of the gas occupies 48.7 mL at STP?
28.2 g/mol
34.5 g/mol
40.0 g/mol
47.9 g/mol
What is the name given to a gas whose particles do not take up space, do not have intermolecular attractive forces, and follow the gas laws under all conditions of temperature and pressure?
noble gas
diatomic gas
ideal gas
real gas
Which of the following states that equal volumes of gases at the same temperature and pressure contain the same number of particles?
boyle's law
gay-lussac's law
charles's law
avogadro's principle
Use the Ideal Gas Law equation to find the molar mass of a 98.2 g sample of gas that fills a 50.0-liter container at STP.
1.48 g/mol
44.0 g/mol
32.0 g/mol
4.00 g/mol
Use the Ideal Gas Law equation to find the density of a gas at STP with a molar mass of 44.0 g/mol.
1.96 g/L
86.4 g/L
0.0446 g/L
23.9 g/L
In the Ideal Gas Law equation, the units of R will commonly change based on different units of __.
pressure
volume
temperature
moles
Which of the following gases will behave most like an ideal gas?
H2O
He
C4H10
NH3
Calculate the number of moles of gas contained in a 16.0-L vessel at 373 K with a pressure of 2.50 atm.
2.8 x 10-3 mol
1.31 x 10-1 mol
0.766 mol
1.31 mol
In the reaction below, what volume of methane is required to produce 10.0 L of water vapor at constant temperature and pressure?
CH4(g) + 2O2(g) --> CO2(g) + 2H2O(g)
20.0 L
5.00 L
4.45 L
6.23 L
What volume of oxygen gas is needed for the complete combustion of 40.0 liters of hydrogen gas at constant temperature and pressure?
20.0 L
40.0 L
80.0 L
2.00 L
What information is NOT given by the coefficients in a balanced chemical equation?
the mass ratios of reactants and products
the mole ratios of reactants and products
the ratios of number of molecules of reactants and products
the volume ratios of gaseous reactants and products
What variable is assumed to be constant in the combined gas law?
number of moles
pressure
temperature
volume
Boyle's Law
states that the volume of a fixed amount of gas held at a constant temperature varies inversely with the pressure
states that the volume of a given mass of gas is directly proportional to its kelvin temperature at constant pressure
states that the pressure of a fixed mass of gas varies directly with the kelvin temperature when the volume remains constant
describes the physical behavior of an ideal gas in terms of pressure, volume, temperature, and number of moles of gas
Charles's Law
states that the volume of a fixed amount of gas held at a constant temperature varies inversely with the pressure
states that the volume of a given mass of gas is directly proportional to its kelvin temperature at constant pressure
states that the pressure of a fixed mass of gas varies directly with the kelvin temperature when the volume remains constant
describes the physical behavior of an ideal gas in terms of pressure, volume, temperature, and number of moles of gas
Gay-Lussac's Law
states that the volume of a fixed amount of gas held at a constant temperature varies inversely with the pressure
states that the volume of a given mass of gas is directly proportional to its kelvin temperature at constant pressure
states that the pressure of a fixed mass of gas varies directly with the kelvin temperature when the volume remains constant
describes the physical behavior of an ideal gas in terms of pressure, volume, temperature, and number of moles of gas
combined gas law
states that the volume of a given mass of gas is directly proportional to its kelvin temperature at constant pressure
describes the physical behavior of an ideal gas in terms of pressure, volume, temperature, and number of moles of gas
states that the pressure of a fixed mass of gas varies directly with the kelvin temperature when the volume remains constant
a single law combining Boyle's, Charles's, and Gay-Lussac's laws that states the relationship among pressure, volume, and temperature of a fixed amount of gas
ideal gas law
a single law combining Boyle's, Charles's, and Gay-Lussac's laws that states the relationship among pressure, volume, and temperature of a fixed amount of gas
describes the physical behavior of an ideal gas in terms of pressure, volume, temperature, and number of moles of gas
states that the pressure of a fixed mass of gas varies directly with the kelvin temperature when the volume remains constant
states that the volume of a given mass of gas is directly proportional to its kelvin temperature at constant pressure
absolute zero
zero on the kelvin scale, which represents the lowest possible theoretical temperature; atoms are all in the lowest possible energy state
for a gas, the volume that one mole occupies at 0.00°C and 1.00 atm pressure
conditions of 0.00°C and 1.00 atm
an experimentally determined constant whose value in the ideal gas equation depends on the units that are used for pressure
molar volume
zero on the kelvin scale, which represents the lowest possible theoretical temperature; atoms are all in the lowest possible energy state
for a gas, the volume that one mole occupies at 0.00°C and 1.00 atm pressure
conditions of 0.00°C and 1.00 atm
an experimentally determined constant whose value in the ideal gas equation depends on the units that are used for pressure
standard temperature and pressure (STP)
zero on the kelvin scale, which represents the lowest possible theoretical temperature; atoms are all in the lowest possible energy state
for a gas, the volume that one mole occupies at 0.00°C and 1.00 atm pressure
conditions of 0.00°C and 1.00 atm
an experimentally determined constant whose value in the ideal gas equation depends on the units that are used for pressure
ideal gas constant (R)
zero on the kelvin scale, which represents the lowest possible theoretical temperature; atoms are all in the lowest possible energy state
for a gas, the volume that one mole occupies at 0.00°C and 1.00 atm pressure
conditions of 0.00°C and 1.00 atm
an experimentally determined constant whose value in the ideal gas equation depends on the units that are used for pressure
Match each factor with the statement that best explains why it increases solvation.
increases the kinetic energy of the particles in solution
increase in temperature
agitation
increase in surface area
Match each factor with the statement that best explains why it increases solvation.
moves solute particles away from contact surfaces more quickly
increase in temperature
agitation
increase in surface area
Match each factor with the statement that best explains why it increases solvation.
breaks the solute into smaller pieces
increase in temperature
agitation
increase in surface area
the scattering of light by dispersed colloid particles
Tyndall Effect
Brownian Motion
concentration
osmotic pressure
a mixture with particles that settle out if undisturbed
concentration
osmotic pressure
suspension
colloid
the erratic movement of colloid particles
heat of solution
solvation
tyndall effect
brownian motion
the amount of additional pressure caused by water molecules moving into a solution
osmotic pressure
solvation
heat of solution
suspension
a measure of how much solute is dissolved in a specific amount of solvent or solution
solvation
concentration
heat of solution
osmotic pressure
the overall energy change that occurs when a solution forms
suspension
heat of solution
solvation
osmotic pressure
a heterogeneous mixture of intermediate-sized particles
concentration
suspension
colloid
solvation
the process of surrounding solute particles with solvent particles to form a solution
heat of solution
osmotic pressure
henry's law
solvation
the statement that the solubility of a gas in a liquid is directly proportional to the pressure of the gas above the liquid
heat of solution
henry's law
solvation
concentration
When the rate of solvation equals the rate of crystallization, the solution is
unsaturated
supersaturated
saturated
crystallized
What term describes a solution in which the dissolved solute is in equilibrium with the undissolved solute?
saturated solution
dilute solution
supersaturated solution
unsaturated solution
Which of the following statements explains the solubility of ionic substances in water?
The molar mass of water is 18.02 g/mol.
An oxygen atom has six electrons in its outermost energy level.
water molecules are polar
Water is a covalent substance.
Identify a conjugate acid-base pair in the following reaction.
NH3 + H2O ↔ NH4+ + OH-
H2O and OH-
NH3 and H2O
NH3 and OH-
H2O and NH4+
Which one of the following could not be a Brønsted-Lowry acid?
H2O
H3O+
NH4+
BF3
In a weak acid, the conjugate base has a greater attraction for the H+ ion than does the base ________.
HY + H2O --> H3O+ +Y-
HY
H2O
H3O+
NH4+
Which of the following is the strongest base according to the Brønsted-Lowry theory?
Cl-
NO3-
F-
I-
How many times more concentrated is [H+] for soft drinks than for coffee?
100
10
2
0.6
What is the concentration of hydrogen ions in a solution that has a pH of 4.32?
4.8 x 10–5M
6.2 x 10–4M
5.1 x 10–4M
8.6 x 10–5M
What is the hydronium ion concentration of propanoic acid, which has a pH of 2.43?
1.4 × 10–5
2.43 × 100
3.72 × 10–3
7.3 × 104
Calculate the pH of a solution that has a [OH-] = 2.50 x 10-4M.
0.4
3.6
-3.6
10.4
What is the pH of a 0.40M solution of cyanoacetic acid, which has a Ka of 3.55 x 10-3?
2.06
1.22
2.45
1.44
Calculate Ka for a 0.05M solution of the weak acid HF. The pH of the solution is 2.274.
6.3 x 10–4
0.12
5.7 x 10–4
0.11
Arrhenius model
an acid produces hydrogen ions in aqueous solution; a base produces hydroxide ions in aqueous solution
an acid is a hydrogen-ion donor; a base in a hydrogen-ion acceptor
an acid is an electron-pair acceptor and a base is an electron-pair donor
Brønsted-Lowry model
an acid produces hydrogen ions in aqueous solution; a base produces hydroxide ions in aqueous solution
an acid is a hydrogen-ion donor; a base in a hydrogen-ion acceptor
an acid is an electron-pair acceptor and a base is an electron-pair donor
Lewis model
an acid produces hydrogen ions in aqueous solution; a base produces hydroxide ions in aqueous solution
an acid is a hydrogen-ion donor; a base in a hydrogen-ion acceptor
an acid is an electron-pair acceptor and a base is an electron-pair donor
strong acid
an acid that ionizes completely in aqueous solution
an acid that ionizes only partially in dilute aqueous solution
a base that dissociates entirely into metal ions and hydroxide ions in aqueous solution
a base that ionizes only partially in dilute aqueous solution
strong base
a base that ionizes only partially in dilute aqueous solution
an acid that ionizes only partially in dilute aqueous solution
a base that dissociates entirely into metal ions and hydroxide ions in aqueous solution
an acid that ionizes completely in aqueous solution
conjugate acid
the species produced when a base accepts a hydrogen ion from an acid
the species produced when an acid donates a hydrogen ion to a base
conjugate base
the species produced when an acid donates a hydrogen ion to a base
the species produced when a base accepts a hydrogen ion from an acid
weak acid
an acid that ionizes only partially in dilute aqueous solution
a base that ionizes only partially in dilute aqueous solution
an acid that ionizes completely in aqueous solution
a base that dissociates entirely into metal ions and hydroxide ions in aqueous solution
weak base
an acid that ionizes completely in aqueous solution
a base that dissociates entirely into metal ions and hydroxide ions in aqueous solution
an acid that ionizes only partially in dilute aqueous solution
a base that ionizes only partially in dilute aqueous solution
The process used to separate fractions from petroleum is ___________.
fractional distillation
isomerization
chirality
drilling
Which of the following statements is not true about 4-ethyl-3,5-dimethyloctane?
A methyl group branches from position 5.
An ethyl group branches from position 4.
There are eight carbon atoms in the longest chain.
An ethyl group branches from position 3.
An alkyl group is one type of ________.
homologous group
substituent group
heterogenous group
parent group
What term is used to describe isomers that have all the atoms bonded in the same order but arranged differently in space?
structural isomers
nonisomers
polymers
stereoisomers
Chiral carbons will produce _____.
structural isomers
optical isomers
polymers
monomers
