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Thermodynamics

Total questions: 16

Worksheet time: 8mins

Name
Class
Date
1.

---------------is an intensive property

a)

area

b)

entropy

c)

temperature

d)

volume

2.

------ is an extensive property.

a)

specific heat capacity

b)

heat capacity

c)

molar volume

d)

density

3.

Isolated system can exchange------- with its surroundings.

a)

only energy

b)

both matter and energy

c)

neither matter nor energy

d)

only matter

4.

Work and heat are ------function.

a)

state

b)

path

5.

If heat flows into the system from the surrounding, then heat is taken as ------

a)

positive

b)

negative

6.

If work is done by the system, the internal energy of the system decreases, then work done by the system is taken as--------

a)

negative

b)

positive

7.

The enthalpy of formation of O2 in its standard state is ------

a)

+0.1 kJ mol-1

b)

0

c)

-0.1 kJ mol-1

d)

+16 KJ mol-1

8.

C (diamond) \rightarrow   C ( graphite),

Δ\Delta H = -ve, this indicates that

a)

graphite has more energy than diamond

b)

graphite is thermodynamically more stable than diamond

c)

thermodynamic stability cannot be predicted

d)

Both graphite and diamond are energetically equal

9.

The potential energy diagram of a reaction is shown. Which statement below is correct relating to this reaction?

a)

#1 represents the enthalpy change for this exothermic reaction.

b)

#2 represents the enthalpy change for this endothermic reaction.

c)

#3 represents the enthalpy change for this endothermic reaction.

d)

#4 represents the enthalpy change for this exothermic reaction.

10.

The diagram represents two solids and the temperature of each. What occurs when the two solids are placed in contact with each other?

a)

Heat energy flows from solid A to solid B. Solid A decreases in temperature

b)

Heat energy flows from solid A to solid B. Solid A increases in temperature

c)

Heat energy flows from solid B to solid A. Solid B decreases in temperature.

d)

Heat energy flows from solid B to solid A. Solid B increases in temperature.

11.

Which law states that the change of enthalpy in a chemical reaction is the same regardless of whether the reaction takes place in one step or several steps, provided the initial and final states of the reactants and products are the same?

a)

Third Law of Thermodynamics

b)

Netwon's Law of Cooling

c)

Hess's Law

d)

Joule's Law of Heating

12.

----------------------------------------- of a compound is the change of enthalpy during the formation of 1 mole of the substance from its constituent elements, with all substances in their standard states.

a)

Heat of combustion

b)

Heat of formation

c)

Standard Heat of formation

d)

Standard heat of reaction

13.

First Law of Thermodynamics states that (keeping in mind the sign convention of IUPAC)

a)

ΔU = Q + W

b)

ΔU = Q - W

c)

ΔU = W-Q

d)

ΔU = -W -Q

14.

Enthalpy (H) is defined by the relation

a)

H = U + PV

b)

H = U - PV

c)

H = UV + P

d)

H = PV - U

15.

Heat change at constant volume is

a)

U

b)

ΔU

c)

H

d)

ΔH

16.

Heat change at constant pressure is

a)

U

b)

ΔU

c)

H

d)

ΔH