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MIDTERM EXAM

Total questions: 50

Worksheet time: 46mins

Name
Class
Date
1.
a)

a

b)

b

c)

c

d)

d

2.

The anode is where

a)

electrolyte concentrations are lowest.

b)

electrolyte concentrations are highest.

c)

anions are produced.

d)

oxidation occurs.

3.

All of the following statements concerning voltaic cells are true EXCEPT

a)

a salt bridge allows cations and anions to move between the half-cells.

b)

electrons flow from the cathode to the anode in the external circuit.

c)

oxidation occurs at the anode.

d)

a voltaic cell consists of two-half cells.

4.

The following reaction occurs spontaneously.

2 Fe(s) + 3 Cl2(aq) --> 2 Fe3+(aq) + 6 Cl(aq)

Write the balanced reduction half-reaction

a)

Fe(s) -> Fe3+(aq) + e

b)

Fe(s) + 3 e -> Fe3+(aq)

c)

Fe(s) + 3/2 Cl2(aq) -> FeCl3(aq)

d)

Cl2(aq) + 2 e -> 2 Cl(aq)

5.

The following reaction occurs spontaneously.

2Al(s) + 6H+(aq) -> 2Al3+(aq) + 3H2(g)

Write the balanced oxidation half-reaction

a)

Al(s) -> Al3+(aq) + 3e-

b)

Al3+(aq) + 3e- -> Al(s)

c)

H2(g) -> 2H+(aq) + 2e-

d)

2H+(aq) -> H2(g) + 2e-

6.

Given the following half-reactions,

Pb(s) + 2I-(aq) -> PbI2(s) + 2e-

I2(aq) + 2e- -> 2I-(aq)

write the balanced overall reaction.

a)

Pb(s) + I2(aq) + 2e- -> PbI (s) + I-(aq)

b)

Pb(s) + I2(aq) -> PbI2(s)

c)

Pb(s) + Cl2(aq) -> Pb2+(aq) + 2I-(aq)

d)

2Pb(s) + 4e- -> 2PbI(s) + I2(aq)

7.

Given the following half-reactions

2IO3-(aq) + 12H+(aq) + 10e- -> I2(s) + 6H2O(l)

Fe2+(aq) -> Fe3+(aq) + e-

write the balanced overall reaction.

a)

2IO3-(aq) + 10Fe2+(aq) -> I2(s) + 10Fe3+(aq)

b)

2IO3-(aq) + 12H+(aq) + Fe2+(aq) -> FeI2(s) + 6H2O(l)

c)

2IO3-(aq) + 12H+(aq) + Fe2+(aq) -> I2(s) + Fe3+(aq) + 6H2O(l)

d)

2IO3-(aq) + 12H+(aq) + 10Fe2+(aq) -> I2(s) + 10Fe3+(aq) + 6H2O(l)

8.

Write a balanced net ionic equation for the overall reaction represented by the cell notation below.

Ag | AgI | I || Fe2+, Fe3+ | Pt

a)

Fe3+(aq) + Ag(s) + I(aq) -> Fe2+(aq) + AgI(s)

b)

Fe2+(aq) + Ag(s) + I(aq) -> Fe3+(aq) + AgI(s)

c)

Fe3+(aq) + 2I(aq) -> Fe2+(aq) + I2(s)

d)

Fe2+(aq) + AgI(s) -> Fe3+(aq) + Ag(s) + I(aq)

9.

What is the correct cell notation for the reaction below?

Cd2+(aq) + Ni(s) -> Cd(s) + Ni2+(aq)

a)

Cd2+ | Cd || Ni | Ni2+

b)

Cd | Cd2+ || Ni2+ | Ni

c)

Ni | Ni2+ || Cd2+ | Cd

d)

Cd2+ | Cd || Ni | Ni2+

10.

Write the overall chemical reaction and calculate E° for the following reduction and oxidation half-reactions.

a)

Zn2+(aq) + H2(g) -> Zn(s) + 2H+(aq)        E° = +0.381 V

b)

Zn2+(aq) + H2(g) -> Zn(s) + 2H+(aq)        E° = -0.762 V

c)

Zn(s) + 2H+(aq) -> Zn2+(aq) + H2(g)        E° = +0.762 V

d)

Zn(s) + 2H+(aq) -> Zn2+(aq) + H2(g)        E° = -0.381 V

11.

Given the following two half-reactions, write the overall balanced reaction in the direction in which it is spontaneous and calculate the standard cell potential.

a)

2Ga3+(aq) + 3Sn2+(aq) -> 2Ga(s) + 3Sn4+(aq)        E° = +0.68 V

b)

3Ga3+(aq) + 2Sn2+(aq) -> 3Ga(s) + 2Sn4+(aq)        E° = –1.89 V

c)

2Ga(s) + 3Sn4+(aq) -> 2Ga3+(aq) + 3Sn2+(aq)        E° = +0.68 V

d)

2Ga(s) + 3Sn4+(aq) -> 2Ga3+(aq) + 3Sn2+(aq)        E° = +1.89 V

12.

cathode is the electrode where

a)

reduction takes place

b)

oxidation takes place

c)

either reduction or oxidation

d)

none of these

13.

in electrochemical cell anode is

a)

positive

b)

negative

c)

neutral

d)

none

14.
Oxidation happens at the
a)
Anode
b)
Cathode
c)
Salt bridge
d)
Voltmeter
15.
Which is the correct oxidation half reaction for the reaction:
Al(s) + Zn(NO3)2(aq) → Al(NO3)3(aq) + Zn(s)
a)
Al(s) + 3e- →Al3+ (aq)
b)
Zn(s) → Zn2+(aq) + 2e-
c)
Al(s) → Al3+(aq) + 3e-
d)
Zn2+(aq) +2e- →Zn(s)
16.

How is the alpha particle written in a nuclear equation?

a)

(1) 42He

b)

(2) 24He

c)

(3) 0-1e

d)

(4) 00γ

17.
Which type of nuclear radiation is being emitted here?
a)
Alpha
b)
beta
c)
gamma 
d)
none
18.
Solve this equation for alpha decay.
85209At = ___ + 24He
a)

(option 1)

83205Bi

b)

(option 2)

86209Rn

c)

(option3)

81207Tl

d)

(option 4)

85208At

19.
Solve this equation for beta decay.
614C = ___ + -10e
a)

(option 1)

410Be

b)

(option 2)

714N

c)

(option 3)

210He

d)

(option 4)

613C

20.
Has the highest penetrating power.  Can penetrate our body.  Even several cm thick of lead or several meters thick of concrete cannot stop all of it.
a)
Alpha
b)
Beta
c)
Gamma
21.

Has the lowest penetrating power.  Can only penetrate 0.05 mm into the body and can be stopped by the skin.

a)
Alpha
b)
Beta
c)
Gamma
d)

Electron capture

22.
Uranium-238  decays into  Thorium-234  by emitting .........
a)
an alpha particle
b)
a beta particle
c)
gamma rays
d)
visible light
23.
In a correctly written symbol what would be located in the "A" position?
a)
number of neutrons
b)
atomic number
c)
number of electrons 
d)
mass number
24.

What is the correct # of protons, electrons, and neutrons for Cobalt - 59?

a)

27 protons, 59 electrons, & 27 neutrons

b)

59 protons, 59 electrons, & 86 neutrons

c)

27 protons, 27 electrons, & 32 neutrons

d)

27 protons, 32 electrons, & 27 neutrons

25.

What is an isotope?

a)

Atoms of the same element with different masses.

b)

Atoms of the same element with different # of protons.

c)

Atoms of the same element with different atomic numbers.

d)

Atoms of the same element with the different # of electrons.

26.
Balance the following equation:
146C --> 0-1e + ________
a)

(option 1)

145B

b)

(option 2)

146C

c)

(option 3)

147N

d)

(option 4)

42He

27.

In the symbol 167N what the 7 stand for?

a)

Mass number

b)

Atomic number

c)

Atomic mass

d)

Number of neutrons

28.

If an atom of Americium-231 (Am) goes through alpha decay, what would you have at the end?

a)

Neptunium-227

b)

Neptunium-234

c)

Plutonium-231

d)

Curium-247

29.

If an atom of potassium-40 (K) goes through gamma decay, what would you have at the end?

a)

Potassium-40

b)

Calcium-40

c)

Argon-35

d)

Potassium-39

30.
Radioactive materials have unstable...
a)
electrons
b)
protons
c)
nuclei
d)
neutrons
31.

Complete the following nuclear decay reaction

a)

(option 1)

21786Rn

b)

(option 2)

21788Ra

c)

(option 3)

21792U

d)

(option 4)

22586Rn

32.

What nucleus decays by beta emission to produce antimony-121?

a)

(option 1)

12050Sn

b)

(option 2)

12251Sb

c)

(option 3)

12150Sn

d)

(option 4)

12553I

33.

What element is produced by the alpha decay of 21083Bi?

a)

(option 1)

21081Tl

b)

(option 2)

20879Au

c)

(option 3)

20681Tl

d)

(option 4)

20681Bi

34.
The name for protons and neutrons in nuclear chemistry is____
a)
beta particles
b)
positrons
c)
nucleons
d)
nuclides
35.
What is the equation for the positron emission by oxygen-16?
a)

(option 1)

168O + 0+1e --> 169F

b)

(option 2)

168O --> 42He + 126C

c)

(option 3)

168O --> 0-1e + 169F

d)

(option 4)

168O --> 0+1e + 167N

36.

What is Combustion?

a)

reaction between substance (fuel, wood, paper clothes etc) and oxygen that releases Carbon dioxide and Water, with lots of energy.

b)

reaction between substance (fuel, wood, paper clothes etc) and carbon dioxide that releases oxygen and Water, with lots of energy.

c)

reaction between substance (fuel, wood, paper clothes etc) and water that releases Carbon dioxide and oxygen with lots of energy.

d)

Carbon dioxide is what we breathe out

37.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. Calculate the total atom of Carbon

a)

2.52 mol

b)

2.25 mol

c)

5.22 mol

d)

2.15 mol

38.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. Find the total number of atoms of Hydrogen.

a)

6.50 mole

b)

6.40 moles

c)

6.05 mole

d)

5.04 mole

39.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. The amount of carbon dioxide produced is:

a)

2.250 moles

b)

2.520 moles

c)

2.025 moles

d)

2.205 moles

40.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. Calculate the amount of CO produced.

a)

2.52 mole

b)

0.252 mole

c)

0.522 mole

d)

0.225 mole

41.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. Find the amount of water produced.

a)

3.520 mole

b)

3.250 mole

c)

3.205 mole

d)

3.502 mole

42.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. Calculate the amount of O2 used by hydrocarbon.

a)

3.7625 mole

b)

3.2531 mole

c)

3.5213 mole

d)

3.2135 mole

43.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. What is the amount of theoretical O2 needed?

a)

3.758 mole

b)

3.578 mole

c)

3.785 mole

d)

3.875 mole

44.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. How much O2 entering the system?

a)

5.8125 mole

b)

5.2581 mole

c)

5.2185 mole

d)

5.5218 mole

45.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. How much N2 is entering the system?

a)

21.668 mole

b)

26.816 mole

c)

21.866 mole

d)

28.616 mole

46.

Natural gas containing 80% C2H6, 15% C3H8, 5% C4H10, is burnt with 50% excess air.  Assuming that 90% of the carbon in the hydrocarbons are converted to CO2 and the rest to CO. How much O2 is in the Flue gas?

a)

5.20 mole

b)

5.02 mole

c)

2.50 mole

d)

2.05 mole

47.

A material such as coal, gas, or oil that is burned to produce heat or power:

a)

Oxygen gas

b)

kerosene

c)

Flue Gas

d)

Fuel

48.

Which of these is NOT needed for a fire?

a)

Heat

b)

Fuel

c)

Oxygen

d)

Friction

49.

Which poisonous gas is formed as a result of incomplete combustion?

a)

Coal gas

b)

carbon monoxide

c)

carbon dioxide

d)

nitrogen oxide

50.

Which one of the following gases is used in combustion?

a)

CO

b)

Carbon dioxide

c)

Oxygen

d)

Nitrogen