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CHEM 122 Test 2

Total questions: 15

Worksheet time: 35mins

Name
Class
Date
1.

The rate law cannot be predicted from the stoichiometry of a reaction.

a)

True

b)

False

2.

The units of the rate depend on the order of the reaction.

a)

True

b)

False

3.

The half-life of a second-order reaction does not depend on the initial concentration of reactant

a)

True

b)

False

4.

The greater the energy of activation, Ea, the faster the reaction will be

a)

True

b)

False

5.

The rate of a reaction is determined by the rate of the fastest step in the mechanism.

a)

True

b)

False

6.

When a reaction system reaches equilibrium, the concentrations of reactants and products no longer change

a)

True

b)

False

7.

If Q>K, more products need to be formed as the reaction proceeds to equilibrium

a)

True

b)

False

8.

Consider the reaction:

2NH3(g) --> N2(g) + 3H2(g)

If the rate for the appearance of H2 is 0.030 mol/Ls, then what is the rate of decrease of NH3?

a)

-0.045 mol/Ls

b)

-0.030 mol/Ls

c)

-0.020 mol/Ls

d)

-0.010 mol/Ls

9.

Which of the following sets of units could be appropriate for a zero-order rate constant?

a)

s-1

b)

L/mol s

c)

L2/mol2 s

d)

mol/Ls

10.

A reaction is second-order with respect tot he reactant R. Which of the following plots will produce a straight line?

a)

[R] vs. 1/time

b)

1/[R] vs time

c)

[R]2 vs. time

d)

ln[R] vs. time

11.

The rate constant for the reaction 3A --> 4B is 6.00 x 10-3 L/mol min. How long will it take the concentration of A to drop from 0.75 M to 0.25 M?

a)

2.2 x 10-3 min

b)

5.5 x 10-3 min

c)

180 min

d)

440 min

12.

Which of the following affects the activation energy of a reaction?

a)

temperature of reactants

b)

concentration of reactants

c)

presence of a catalyst

d)

surface area of reactants

13.

The equilibrium constant, Kc, for the decomposition of COBr2 is 0.190.

COBr2 ↔ CO + Br2

What is the Kc for the following reaction?

2CO + 2Br2 ↔ 2COBr2

a)

0.0361

b)

2.63

c)

5.62

d)

27.7

14.

A mixture of 0.500 mol of carbon monoxide and 0.400 mol of bromine was placed into a rigid 1.00 L container and the system was allowed to come to equilibrium. The equlibrium concentration of COBr2 was 0.223 M. What is the value of Kc for this reaction?

CO (g) + Br2 (g) ↔ COBr2 (g)

a)

5.23

b)

1.22

c)

1.165

d)

0.858

15.

At 25 oC, the equilibrium constant, Kc , for the reaction: B(g) + C(g) ↔ 2A(g) is 28.57. A mixture of 8.00 mol of B and 12.00 mol of C in a 20.0 L container is allowed to come to equilibirum. What is the equilibrium concentration of A?

a)

<0.100M

b)

0.339 M

c)

0.678 M

d)

6.78 M