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DK024 CHAPTER 1 REACTION KINETICS

Total questions: 15

Worksheet time: 16mins

Name
Class
Date
1.

For the reaction:

4NH3(g) + 5O2(g) → 4 NO(g) + 6H2O(g)


the rate of disappearance of oxygen is 0.020 M/s. What is the rate of formation of H2O?

a)

0.03 Ms-1

b)

0.02 Ms-1

c)

0.017 Ms-1

d)

0.024 Ms-1

2.
State the order for the reaction.
a)
zero
b)
1st
c)
2nd
d)
3rd
3.
A reaction has the rate law: Rate = k [A][B].
What is the overall order of reaction?
a)
1st
b)
2nd
c)
3rd
d)
4th
4.
The rate law for the reaction 2NO(g) + O2(g) → 2NO2(g) is first order in O2 and third order overall. What is the rate law for the reaction?
a)
Rate = k [NO]2[O2]2
b)
Rate = k [NO]1[O2]2
c)
Rate = k [NO]2[O2]1
d)
Rate = k [2NO]2[O2]1
5.

The catalyst alters the rate of a chemical reaction by,

a)

providing an alternative pathway with a lower Ea

b)

changing the products formed in the direction of the reaction

c)

providing a surface on which the molecules react

d)

increasing the frequencies of collisions between molecules

6.

Which of the following is a unit of rate of reaction?

a)

s-1

b)

Ms-1

c)

M

d)

M-1s-1

7.
Under the collision theory, the particles must collide with  ____ and ____ for a reaction to occur.
a)
sufficient rate and sufficient energy
b)
sufficient surface area and correct orientation
c)
sufficient catalyst and sufficient energy
d)
sufficent energy and correct orientation
8.
More collisions correspond to a: 
a)
Faster reaction rate  
b)
Slower reaction rate
c)
Constant reaction rate 
d)
None of the above
9.

Given the following balanced equation :

2NO(g) + Cl2(g) → 2NOCl(g)

If the rate of disappearance of Cl2 is 4.84 x 10-2 Ms-1, what is the rate of disappearance of NO?

a)

1.45 x 10-2 Ms-1

b)

2.42 x 10-2 Ms-1

c)

3.67 x 10-2 Ms-1

d)

9.68 x 10-2 Ms-1

10.

The reaction A + 2B → products was found to have the rate law, k = k[A][B]2. Predict by what factor the rate of reaction will increase when the concentration of B is doubled and the concentration of A remained uncanged

a)

2

b)

4

c)

6

d)

8

11.
A possible rate law for a third overall order of a reaction is __________________
a)
Rate = k [A]2[B]2
b)
Rate = k [A][B]3
c)
Rate = k [A]3 [B]
d)
Rate = k [A]2[B]
12.

What is the unit for rate constant,K if rate law:

Rate = K [A]

a)

s-1

b)

M s-1

c)

M-1 s-1

d)

M-2 s-1

13.
Which one of the following is a first order, overall reaction
a)
k1= 1.000 M s-1
b)
k1= 5403.2 M½ s½
c)
k1= 1.23 x 10-6 M-1 s-1
d)
k1= 10.7 s-1
14.

The catalyst alters the rate of a chemical reaction by,

a)

providing an alternative pathway with a lower Ea

b)

changing the products formed in the direction of the reaction

c)

providing a surface on which the molecules react

d)

increasing the frequencies of collisions between molecules

15.

Decreasing concentration has which of the following effects on reaction rate?

a)

Increases reaction rate.

b)

Has no effect on reaction rate.

c)

Decreases reaction rate.