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AP Chemistry Unit 2 Review

Total questions: 44

Worksheet time: 44mins

Name
Class
Date
1.

What type of alloy is made when the radii of the atoms are similar in size?

a)

interstitial

b)

substitutional

2.

Which atom has the negative dipole in this molecule?

a)

Hydrogen

b)

Fluorine

c)

Neither

3.

In this molecule, Carbon has a formal charge of ____ and Nitrogen has a formal charge of _____.

a)

0, 0

b)

1, 0

c)

0, -1

d)

-1, 0

4.

What type of alloy is this?

a)

Interstitial

b)

Substitutional

5.

What is the bond angle in BF3?

a)

90

b)

120

c)

109.5

d)

180

6.

What is the hybridization of carbon in CH4?

a)

sp3

b)

sp

c)

sp2

7.

Why are asymmetrical molecules polar?

a)

Their dipoles do not cancel

b)

Their dipoles cancel

8.

What is the hybridization for carbon in CO2

a)

sp3

b)

sp

c)

sp2

9.

As the electronegativity difference between 2 atoms increases, the polarity of the bond ____________________

a)

increases

b)

decreases

10.

Count the number of sigma and pi bonds in this molecule:

a)

13 sigma, 1 pi

b)

14 sigma, 2 pi

c)

1 sigma, 14 pi

d)

2 sigma, 13 pi

11.

What is the hybridization of carbon in C2H2?

a)

sp3

b)

sp

c)

sp2

12.

The Lewis structure of the CO32- ion is

a)
b)
c)
d)
e)
13.

The Lewis structure of N2H2 shows __________.

a)

a nitrogen-nitrogen triple bond

b)

a nitrogen-nitrogen single bond

c)

each nitrogen has one lone pair

d)

each nitrogen has two lone pairs

e)

each hydrogen has one lone pair

14.

Resonance structures differ by __________.

a)

number and placement of electrons

b)

number of electrons only

c)

placement of atoms only

d)

number of atoms only

e)

placement of electrons only

15.

As the number of covalent bonds between two atoms increases, the distance between the atoms ______ and the strength of the bond between them ______.

a)

increases, increases

b)

decreases, decreases

c)

increases, decreases

d)

decreases, increases

e)

is unpredictable

16.

The ability of an atom in a molecule to attract electrons is best quantified by the ______.

a)

electronegativity

b)

paramagnetism

c)

diamagnetism

d)

electron change-to-mass ratio

e)

first ionization energy

17.

The ion NO- has _____ valence electrons.

a)

10

b)

12

c)

14

d)

15

e)

16

18.

The formal charge on carbon in the molecule shown is _______.

a)

0

b)

+1

c)

+2

d)

+3

e)

-1

19.

Which of these bonds takes the most energy to break?

a)

single

b)

double

c)

triple

d)

quadruple

20.

Potassium iodide, KI,has the following bonding:

a)

ionic

b)

metallic

c)

nonpolar covalent

d)

polar covalent

21.
 A lone pair is defined as
a)
A pair of bonding electrons
b)
One non-bonding electron
c)
A pair of non-bonding electrons
d)
A pair of electrons on the central atom
22.
How are compounds with metallic bonds similar to ionic compounds? 
a)
Both tend to have double and triple bonds
b)
Both tend to have low boiling points 
c)
Both tend to have poor conductivity
d)
Both tend to have high melting points 
23.

The melting point of MgO is higher than that of NaF. Which of the following best explains this observation?

a)

O2- is more negatively charged than F-

b)

Mg2+ is more positively charged than Na+

c)

The O2- ion is smaller than the F- ion

d)

Mg2+ is more positively charged than Na+ and O2- is more negatively charged than F-

24.

The elements C and Se have the same electronegativity value, 2.55. Which of the following claims about the compound that forms from C and Se is most likely to be true?

a)

The carbon-to-selenium bond is unstable.

b)

The carbon-to-selenium bond is nonpolar covalent.

c)

The compound has the empirical formula CSe.

d)

A molecule of the compound will have a partial negative charge on the carbon atom.

25.

Which of the following correctly indicates whether the solid represented by the particulate model shown above conducts electricity and explains why or why not?

a)

It conducts electricity because it is made of positive and negative ions.

b)

It conducts electricity because it is made of particles of different sizes.

c)

It does not conduct electricity because its ions cannot move freely within the solid.

d)

It does not conduct electricity because there are small spaces between the particles.

26.

Which of the following Lewis diagrams best represents the bonding in the N2O molecule, considering formal charges?

a)
b)
c)
d)
27.

Which atom can accommodate an octet of electrons, but doesn't necessarily have to accommodate an octet?

a)

N

b)

C

c)

H

d)

O

e)

B

28.

Choose the correct shape for H2S

a)

Tetrahedral

b)

Trigonal pyramidal

c)

Bent

d)

Trigonal planar

29.
The following molecules all contain polar bonds however only one is a polar molecule.  Which one?
a)
CCl4
b)
CO2
c)
NH3
d)
CH4
30.
Determine the electron geometry (eg) and molecular geometry (mg) of XeF4 (Lewis structure is shown) .
a)
eg = tetrahedral, mg = tetrahedral
b)
eg = linear, mg = linear
c)
eg = octahedral, mg = square planar
d)
eg = trigonal bipyramidal, mg = tetrahedral
31.

How many sigma and pi bonds are there in C2H2? (the structure will be ordered HCCH)

a)

1 sigma and 1 pi

b)

3 sigma and 1 pi

c)

3 sigma and 2 pi

d)

2 sigma and 3 pi

32.
What is the VSPER shape of PCl5
a)
See-saw
b)
trigonal planar
c)
octahedral
d)
trigonal bipyramidal
33.

Which of the following best explains why copper conducts electricity?

a)

It can have two or three valence electrons

b)

It has delocalized electrons that can flow in a circuit

c)

It is a transition metal

d)

It has a low electronegativity

34.

Which of the following molecular shapes would have a bond angle of 180 Degrees?

a)

Bent

b)

Trigonal Planar

c)

Tetrahedral

d)

Linear

35.

Which one is polar?

a)

BF4BF_4^-

b)

H2COH_2CO

c)

PF5PF_5

d)

SeF6SeF_6

36.

What kind of an alloy is this?

a)

substitutional

b)

interstitial

c)

metallic

d)

nonpolar

37.
The interaction energy of two hydrogen atoms is shown on the graph above. Which of the answer choices displayed on the graph best represents the bond length of the H2 molecule?
a)
A
b)
B
c)
C
d)
D
38.

Which of these alloys is a substitutional alloy?

a)

Bronze

b)

Steel

39.

Why is the bond angle in NH3 molecule is smaller than that in CH4 molecule?

a)

Among the four electron pairs around the central atom N in NH3

molecule, there are two lone pairs which require more space than bonding pairs and tend to compress the angles between the bonding pairs.

b)

Among the four electron pairs around the central atom N in NH3

molecule, there is one lone pair which requires more space than a bonding pair and tends to compress the angles between the bonding pairs.

c)

Among the four electron pairs around the central atom N in NH3

molecule, there is one lone pair which requires less space than bonding pairs and tend to increase the angles between the bonding pairs.

d)

In reality, bond angle in NH3 molecule is larger than that in CH4 molecule.

40.

Choose the correct Electron Geometry and then Molecular Geometry of this molecule.

a)

Tetrahedral, Trigonal planar

b)

Tetrahedral, Trigonal pyramidal

c)

Tetrahedral, Tetrahedral

d)

Trigonal Bipyramidal, Bent

41.

Which structure consists of a giant lattice of cations and anions held together by strong electrostatic forces of attraction?

a)

ionic bonding

b)

metallic bonding

c)

covalent bonding

42.

Which color graph would be the plot for the molecule with the largest atomic radius

a)

purple graph

b)

blue graph

c)

red graph

43.

The acronym VSEPR stand for

a)

very strong electron pair repulsion.

b)

varied symmetry electrostatic proton reaction.

c)

venomous snakes enjoy pink ribbons.

d)

valence shell electron pair repulsion.

44.

Ionic Compounds are normally Solid at Room Temperature and known as Salts. The lattice energy of a salt is related to the energy required to separate the ions of solid ionic s. For which of the following pairs of ions is the energy that is required to separate the ions largest?

a)

K and F

b)

Fr and I

c)

Ga and O

d)

Al and O