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AP Chem Unit 4

Total questions: 25

Worksheet time: 56mins

Name
Class
Date
1.

Which of the following reactions could be modeled using the following representation?

a)

AgCl --> Ag+ + Cl-

b)

AgNO3 + NaCl --> AgCl + NaNO3

c)

AgCl + K --> Ag + KCl

d)

Ag+ + e- --> Ag

2.

Which of the following statements BEST describes the difference between the two equations shown below?

Equation 1: H2O (l) --> H2O(g)

Equation 2: 2H2O (l) --> 2H2(g) + O2(g)

a)

Equation 1 represents a physical change because intermolecular forces are broken during the process, whereas Equation 2 represents a chemical change because intramolecular forces are broken

b)

Equation 1 represents a physical change because intramolecular forces are broken during the process, whereas Equation 2 represents a chemical change because intermolecular forces are broken

c)

Equation 1 represents a chemical change because intermolecular forces are broken during the process, whereas Equation 2 represents a physical change because intramolecular forces are broken

d)

Equation 1 represents a chemical change because intramolecular forces are broken during the process, whereas Equation 2 represents a physical change because intermolecular forces are broken

3.

You mixed two aqueous solutions together, expecting to see a precipitate form. Instead, after several minutes, you do not SEE any changes.


Which of the following are other observations that could be recorded?

a)

gas bubbling

b)

heat evolving

c)

color change

d)

there are no other changes to look for because no reaction has occurred

4.

Use the diagram below to help you.

Which of the following BEST describes what happens to C2H4 when a 5.00 g sample of C4H6 is mixed with a 10.00 g sample of C6H6 at -10.0°C?

a)

A chemical change occurs, and the C4H6 forms nonpolar covalent bonds with the C6H6

b)

A physical change occurs, and the C4H6 forms a thin, liquid layer above the liquid C6H6

c)

A chemical change occurs, as the C4H6 bonds are broken, and the individual C and H atoms are added to the C6H6 molecule to form C10H12

d)

A physical change occurs as the C4H6 forms London dispersion forces with the C6H6 to create a mixture.

5.

Solutions of sodium carbonate and hydrochloric acid are mixed. Which of the following represents the balanced, net ionic reaction for this mixture?

a)

Na2CO3 (aq) + 2HCl (aq) --> 2NaCl(aq) + H2CO3(aq)

b)

CO32-(aq) + 2H+(aq) --> H2CO3(aq)

c)

CO32-(aq) + 2H+(aq) --> H2O(l) + CO2(g)

d)

2Na+ (aq) + CO32-(aq) + 2H+(aq) + 2Cl-(aq) --> 2Na+ (aq) + 2Cl-(aq) + H2O(l) + CO2(g)

6.

Reactions occurring in aqueous solution can be represented by three types of reaction equations: (1) a molecular equation, (2) a complete ionic equation, and (3) a net ionic equation. Sometimes, two of more of these wind up looking exactly the same.

Consider the reaction below:

Mg(OH)2(aq) + H2SO4(aq)--> MgSO4(s) + 2H2O(l)

Which of the following statements is TRUE concerning the molecular equation (shown above), the complete ionic equation and the net ionic equation for this reaction?

a)

All three equation types are the same

b)

All three equation types are different

c)

The molecular and complete ionic equations are the same, but the net ionic equation is different.

d)

The molecular equation is different from the other two, but the complete ionic and net ionic equations are the same.

7.

Consider the decomposition reaction represented in the picture. Which of the following reaction equations would fit this decomposition?

a)

KClO3 --> KCl + 3O2

b)

Mg(ClO3)2 --> MgCl2 + 3O2

c)

Mg(ClO3)2 --> MgO2 + 3Cl2

d)

Pb(CO3)2 --> PbO2 + 3CO2

8.

Consider the reaction:

2ZnS + 3O2 --> 2ZnO + 2SO2

This reaction has an 80.0% yield.

What mass of ZnO is produced when 50.0 g of ZnS is heated in an open vessel until no further weight loss is observed?

a)

33.4 g

b)

40.4 g

c)

43.4 g

d)

3240 g

9.

Calcium reacts with water according to the following reaction:

Ca + 2H2O --> Ca(OH)2 + H2

What volume of hydrogen gas, at 2.00 atm and 0.00°C, is produced from 20.0 g calcium and 20.0 g water?

a)

0.559 L

b)

5.46 L

c)

109 L

d)

219 L

10.

For a titration using 12.00 mL of 0.50 M HCl and NaOH, which of the following is TRUE about the equivalence point?

a)

1.5 mL of 2.0 M NaOH has been added

b)

24.00 mL of 1.0 M NaOH has been added

c)

12.00 mL of 1.0 M NaOH has been added

d)

6.00 mL of 1.0 M NaOH has been added

11.

There are two 25.0 mL unmarked samples. One is HCl and the other is HF. Given 0.200 M KOH, you titrate each sample separately to determine the equivalence point.

Which of the following would assist in identifying the samples?

a)

The equivalence point for HCl would be found at pH<7, while the equivalence point for HF would be found at pH=7

b)

The equivalence point for HCl would be found at pH>7, while the equivalence point for HF would be found at pH<7

c)

The equivalence point for HCl would be found at pH=7, while the equivalence point for HF would be found at pH<7

d)

The equivalence point for HCl would be found at pH=7, while the equivalence point for HF would be found at pH>7

12.

Which of the following is an accurate description of the equivalence point for any strong acid-strong base titration?

a)

The moles of acid is equal to half the amount of base

b)

The acid has been oxidized and the base has been reduced

c)

The acid has been completely reacted, and the pH of the solution is equal to 7

d)

The pH of the final solution is greater than 11 since the strong base is being used to neutralize a strong acid

13.

A sample of 25.0 mL of 0.120 M Ba(OH)2 is titrated with 0.150 M HBr.

What volume of hydrobromic acid is needed to completely neutralize the barium hydroxide?

a)

20.0 mL

b)

40.0 mL

c)

60.0 mL

d)

80.0 mL

14.

A student added 2 mL of 0.1 M CaCl2 to 2 mL of 0.1 M Na2CO3 in a test tube. He observed a white precipitate form. Which of the following is the identity of the precipitate?

a)

CaCl2

b)

Na2CO3

c)

NaCl

d)

CaCO3

15.

In which of the following substances does manganese have the highest oxidation number?

a)

LiMnO4

b)

K2MnO4

c)

MnO2

d)

Mn(NO3)2

16.

Which of the following is an oxidation-reduction reaction?

a)

CuCl2(aq) + Fe(s) --> FeCl2(aq) + Cu(s)

b)

Pb(NO3)2(aq) + 2NaI(aq) --> PbI2(s) + 2NaNO3(aq)

c)

HCl(aq) + NaOH(aq) --> NaCl(aq) + H2O(l)

d)

NH4Cl --> NH3 + HCl

17.

Which of the following represents the oxidation half-reaction for the unbalanced redox equation?

Cu + HNO3 --> Cu(NO3)2 + NO2

a)

Cu2+ + 2e- --> Cu

b)

Cu --> Cu2++2e-

c)

NO3- --> NO2 + e-

d)

2H+ + NO3- + e- --> NO2 + H2O

18.

A student performs a gravimetric analysis of an unknown alkali metal bromide solution by mixing the unknown with excess silver nitrate solution. The student collects the resulting silver bromide precipitate through filtration, dries it, and records the mass of the precipitate.

During the course of the experiment, which of the following happens to the nitrate ions?

a)

The nitrate ions react with the unknown metal ions and are decomposed

b)

The nitrate ions are oxidized by the bromide ions

c)

The nitrate ions react with the unknown metal ions, creating a solid product

d)

The nitrate ions remain dissolved in the filtrate

19.

10.0 mL of a 0.10 M sodium chloride solution is mixed with 10.0 mL of 0.25 M silver nitrate solution.

What mass of silver chloride should form from this reaction?

a)

0.014 g

b)

0.14 g

c)

0.24 g

d)

0.32 g

20.

Which of the following is the conjugate acid of HPO4-2?

a)

H2PO4-

b)

PO4-3

c)

H3PO4

d)

H3O+

21.

H2O is considered an amphoteric substance. Which of the following other substances can also be considered amphoteric?

a)

H2SO4

b)

HSO4-

c)

SO42-

d)

CO32-

22.

Which of the following is the conjugate base in this reaction?

H2S(g) + H2O(l) <->H3O+(aq) + HS-(aq)

a)

H2S

b)

H2O

c)

H3O+

d)

HS-

23.

Which of the following is the correct half-reaction for the reduction of hydrogen when a piece of Al wire is added to a solution of HCl?

a)

2H+(aq)+ 2e- --> H2(g)

b)

6H+(aq) + 6e- --> 3H2(g)

c)

2H+(aq) --> 2H+2 + e-

d)

2H2(g) --> 6H+(aq) + 6e-

24.

The two unbalanced half-reactions below represent the oxidation-reduction reaction that occurs when solid Cu is added to Ag ion solution.

Which of the following accurately describes the number of electrons transferred during the reaction?

Cu--> Cu2+

Ag+ --> Ag

a)

1 electron. The charge on the Ag+ is +1 so the silver ion is reduced by gaining an electron

b)

2 electrons. When the balanced equation is written, there are two Ag+ to balance the charge with the Cu2+

c)

3 electrons. Since the charge on the Cu2+ is +2 and the charge on the Ag+ is +1, the total charge is +3

d)

1 mole of electrons. During a redox reaction, there is always a mole of electrons transferred.

25.

A 15.0 g sample of lithium is reacted with 15.0 g of flourine to form lithium flouride:

2Li + F2 --> 2LiF

After the reaction is complete, which of the following will be present?

a)

2.16 moles LiF only

b)

0.789 moles LiF only

c)

2.16 moles LiF and 0.395 moles F2

d)

0.789 moles LiF and 1.37 moles Li