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AP Periodicity

Total questions: 27

Worksheet time: 46mins

Name
Class
Date
1.

Neon lighting is one application using concepts from emission spectroscopy. Which of the following best describes how the emission process works in neon lighting?

a)

Ultraviolet light excites the neon gas to produce emitted white light.

b)

Energy excites the neon gas to an excited state. The relaxation to ground state causes light to be emitted.

c)

Neon gas reacts with oxygen in the air, which causes the emission of light.

d)

none of the above.

2.
Which of the following regions of the electromagnetic spectrum has the lowest frequency?
a)
ultraviolet
b)
infrared
c)
visible
d)
x-ray
3.
Which electron transition is an absorption of energy?
a)
n= 4 to n= 3
b)
n=2 to n=4
c)
n=3 to n=1
d)
n=3 to n=0
4.
What is the shorthand electron configuration for Sulfur atom?
a)
[Ar] 3p4
b)
[He] 3s23p4
c)
[Ne] 3s23p4
d)
[Na] 3s23p3
5.
Which of the following will have a larger radius than Zinc?
a)
Gallium
b)
Aluminum
c)
Magnesium
d)
Strontium
6.

Which of the following will have a higher electron affinity than arsenic (As)?

a)

Carbon (C)

b)

Neon (Ne)

c)

Antimony (Sb)

d)

Germanium (Ge)

7.
Which of the following will have a lower ionization energy than Scandium (Sc)?
a)
Helium (He)
b)
Titanium (Ti)
c)
Calcium (Ca)
d)
Magnesium (Mg)
8.

Which atom has the largest atomic radius?

a)

potassium

b)

rubidium

c)

neon

d)

cesium

9.

As you move down the periodic table atoms get bigger. This is because ____________.

a)

The atoms have more mass.

b)

The atoms have more protons.

c)

The atoms have more energy levels and the shielding effect

d)

The atoms have more neutrons

10.
Which statement correctly and completely identifies a trend?
a)
Atomic radius decreases across a period and increases down a group.
b)
Electronegativity decreases across a period and decreases down a group.
c)
Ionization energy increases across a period and increases down a group.
d)
Ionic radius increases across a period and increases down a group.
11.
What group of metals are extremely reactive because they only have one valence electron?
a)
Halogens
b)
Alkali
c)
Alkaline 
d)
Transition
12.
How many electrons can the d sublevel hold?
a)
14
b)
10
c)
2
d)
6
13.
What is incorrect about this orbital diagram?
a)
Both arrows in the 2p box should be pointing up
b)
There is nothing incorrect with this diagram
c)
In the there should only be 1 orbital in the first 2p box and one in the 2nd 2p box
d)
All the arrows should be pointing up.
14.
The concept of shielding happens because of
a)
attraction between nucleus and valence electrons
b)
attraction between nucleus and core electrons
c)
repulsion between valence electrons and other valence electrons
d)
repulsion between core electrons and valence electrons
15.
Shielding electrons are: 
a)
Electrons in the highest energy level
b)
Electrons in the lower energy levels
c)
Electrons that just come and go - they don't stay with the atom
d)
Electrons that are excited
16.
In moving from left to right across a period on the periodic table, the effective nuclear charge
a)
increases
b)
decreases
c)
stays the same
17.

The element represented by the PES chart would most likely be

a)

Na

b)

Mg

c)

K

d)

Ca

18.

APMCQ:

1s2 2s2 2p6 3s2 3p3

Atoms of an element, X, have the electronic con­figu­ration shown above. The compound most likely formed with magnesium, Mg, is

a)

MgX

b)

Mg2X

c)

MgX2

d)

MgX3

e)

Mg3X2

19.

APMCQ:

Consider atoms of the following elements. Assume that the atoms are in the ground state.

The atom that contains exactly two unpaired electrons

a)

S

b)

Ca

c)

Ga

d)

Sb

e)

Br

20.

APMCQ:

Which of the following best helps explain why the electronegativity of Cl is less than that of F?

a)

The mass of the Cl atom is greater than the mass of the F atom.

b)

The Cl nucleus contains more protons than the F nucleus contains.

c)

When Cl and F form bonds with other atoms, the Cl bonding electrons are more shielded from the positive Cl nucleus than the F bonding electrons are shielded from the positive F nucleus.

d)

Because Cl is larger than F, the repulsions among electrons in the valence shell of Cl are less than the repulsions among electrons in the valence shell of F.

21.

APMCQ:

Which of the following ground-state electron configurations represents the atom that has the lowest first-ionization energy?

a)

1s22s1

b)

1s22s22p2

c)

1s22s22p6

d)

1s22s22p63s1

22.

APMCQ:

The diagram above represents the photoelectric effect for a metal. When the metal surface is exposed to light with increasing frequency and energy of photons, electrons first begin to be ejected from the metal when the energy of the photons is 3.3×10−19J.


Which of the following is closest to the frequency of the light with photon energy of 3.3×10−19J.

a)

5.0×10−53 s−1

b)

5.0×10−16 s−1

c)

5.0×1014 s−1

d)

5.0×1052 s−1

23.

APMCQ:

The compound CCl4 is nonflammable and was once commonly used in fire extinguishers. On the basis of the periodic properties, which of the following compounds can most likely be used as a fire-resistant chemical?

a)

BCl3

b)

CH4

c)

CBr4

d)

PbCl2

24.

APMCQ:

A student uses visible spectrophotometry to determine the concentration of CoCl2(aq) in a sample solution. First the student prepares a set of CoCl2(aq) solutions of known concentration. Then the student uses a spectrophotometer to determine the absorbance of each of the standard solutions at a wavelength of 510nm and constructs a standard curve. Finally, the student determines the absorbance of the sample of unknown concentration.

A wavelength of 510nm corresponds to an approximate frequency of 6×1014 s−1. What is the approximate energy of one photon of this light?

a)

9×1047J

b)

3×1017J

c)

5×10-7J

d)

4×10-19J

25.

APMCQ:

The photoelectron spectra of the 1s electrons of two isoelectronic species, Ca2+ and Ar, are shown above. Which of the following correctly identifies the species associated with peak X and provides a valid justification?

a)

Ar, because it has completely filled energy levels

b)

Ar, because its radius is smaller than the radius of Ca2+

c)

Ca2+, because its nuclear mass is greater than that of Ar

d)

Ca2+, because its nucleus has two more protons than the nucleus of Ar has

26.

APMCQ:

The first five ionization energies of a second-period element are listed in the table above. Which of the following correctly identifies the element and best explains the data in the table?

a)

B, because it has five core electrons

b)

B, because it has three valence electrons

c)

N, because it has five valence electrons

d)

N, because it has three electrons in the p sublevel

27.

APMCQ:

Based on periodic trends and the data in the table above, which of the following are the most probable values of the atomic radius and the first ionization energy for potassium, respectively?

a)

242 pm, 633 kJ/mol

b)

242 pm, 419 kJ/mol

c)

120 pm, 633 kJ/mol

d)

120 pm, 419 kJ/mol