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Worksheets

Amines

Total questions: 25

Worksheet time: 25mins

Name
Class
Date
1.

Which of the following is not a primary amine?

a)

Diethylamine

b)

3-Hexylamine

c)

Cyclohexylamine

d)

1-Butylamine

2.

Which pairing of general formula and compound class is incorrect?

a)

RCONH2; amide

b)

R3CNH2; tertiary amine

c)

RNH2; amine

d)

(RCO)2NH; imide

3.

Which one is among the important property of Zwitter ion

a)

has a plus and minus charge in the structure

b)

Its a dipolar ion

c)

melting and Boiling point is lower

d)

amino acids exist as zwitter ions

4.

Which one among the following is a strongest base

a)

methyl amine

b)

Ammonia

c)

Aniline

d)

Benzylamine

5.

Which is the correct arrangement of compounds based on decreasing order of Kb value

a)

methyl amine > ammonia > phenyl amine

b)

Phenyl amine > ammonia > methyl amine

c)

Ammonia > phenyl amine > methyl amine

6.

Name the product for the following reaction :

CH3CH2CH2CONH2 + Br2 + NaOH -->

a)

A. CH3CH2CH2Br

b)

B. CH3CH2CH2NH2

c)

C. CH3CH2CH2COOH

d)

D. CH3CH2CH2CH2NH2

7.
a)

N,N-dimethylethylamine

b)

N,N-diethylethylamine

c)

N,N-dimethylpropylamine

d)

N,N-dimethylmethylamine

8.

State the reagent used to convert butanamine to butanol.

a)

Nitric acid

b)

Nitrous acid

c)

Water

d)

Sodium hydroxide

9.

The following methods can be used to prepare ethanamine except for

a)

ethanenitrile + LiAlH4

b)

ethanamide + LiAlH4

c)

1-bromoethane + NH3

d)

1-bromoethane + KCN + LiAlH4

10.

Amines can be prepared from the following reactions except ______

a)

reduction of nitriles

b)

reduction of amides

c)

reduction of nitro compounds

d)

reduction of carboxylic acids

11.

Give the IUPAC name for above compound

a)

N-butyl-N-ethyl-N-methylamine

b)

4-amino-N-methyl-hexane

c)

N-ethyl-N-methyl-1-butanamine

12.

Aromatic amines are ____ bases than ammonia, due to the ____ nature of the aryl group.

a)

Stronger, electron donating

b)

Weaker, electron donating

c)

Stronger, electron withdrawing

d)

Weaker, electron withdrawing

13.

Which is the incorrect statement in the following ?

a)

Methylamine is more basic than ammonia

b)

Amines from hydrogen bonds

c)

Ethylamine has higher boiling point than propane

d)

Dimethylamine is less basic than methylamine .

14.

The correct order of basic strengths is :

a)

CH3NH2 > (CH3)2 NH > (CH3)3N

b)

(CH3)3N > (CH3)2 NH > CH3NH2

c)

(CH3)2 NH > (CH3)NH2 > (CH3)3N

d)

(CH3)3N > CH3NH2 > (CH3)2NH

15.

Aniline react with bromine water to form

a)

Bromobenzene

b)

m-bromo aniline

c)

2,4,6-tribromoaniline

d)

o and p –bromoaniline

16.

Which of the following pairs will react to form benzenadiazonium chloride under suitable conditions?

a)

A. Methylbenzene and HNO3/HCI

b)

B. Nitrobenzene and SN/HCI

c)

C. Aniline and NaNO2/HCI

d)

D. Aniline and HNO3/HCI

17.

N-phenylethanamide , C6H5NHCOCH3 can be produced by reacting

a)

A. CH3COOH with C6H5COCH3

b)

B. CH3Br with C6H5CONH2

c)

C. C6H5CONH2 with C6H5NH2

d)

D. CH3COCI with C6H5NH2

18.

Aqueous solutions of ammonia, ethylamine and phenylamine are prepared. Each solution has the same concentration.


Which is the correct order for the pH values of these solutions?

a)

ammonia > ethylamine > phenylamine

b)

ammonia > phenylamine > ethylamine

c)

ethylamine > ammonia > phenylamine

d)

ethylamine > phenylamine > ammonia

19.

Hinsberg Reagent is

a)

Benzenesulphonyl trichloride

b)

Benzenesulphonyl fluoride

c)

Benzenesulphonyl diachloride

d)

Benzenesulphonyl chloride

20.

Aniline can be converted into phenyl iso cyanide by

a)

Hinsberg Reagent

b)

Carbylamine Reagent

c)

Iodoform

d)

CU/HCL

21.

Carbylamine reagent is

a)

CHCL3

b)

CHCL3 + Br2

c)

CHCl3 + KOH

d)

CHCL3 + KCL

22.

A reaction in which a primary amine is formed from primary amide is called

a)

Hoffmann bromamide reaction

b)

CARBYLAMINE

c)

AZO DYE TEST

d)

NITRATION

23.

Which class of amine can form intermolecular hydrogen bonds

a)

1o only

b)

2o only

c)

3o only

d)

1o and 2o

e)

2o and 3o

24.

In Hinsberg reaction, after the reaction with benzene sulphonyl chloride, primary amine will remain ... in base solution, & then ... in acid solution.

a)

Soluble, insoluble

b)

Insoluble, no change

c)

No change, Soluble

d)

Soluble, no change

25.

In Hinsberg reaction, after the reaction with benzene sulphonyl chloride, tertiary amine will remain ... in base solution, & then ... in acid solution.

a)

Soluble, insoluble

b)

Insoluble, no change

c)

Insoluble, Soluble

d)

Soluble, no change