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WorksheetsAchem
Total questions: 210
Worksheet time: 2hrs 53mins
What do you call a combination of two or more materials which retain their individual properties and can be separated by physical means
solvents
reactions
solutions
mixtures
A polar solute usually dissolves in a polar solvent and non polar solute usually dissolves in a non polar solvent. This is
Hunds rule
Solubility rule
Henrys Law
the like dissolves like rule
What is the molarity of a solution containing 72.9 grams of HCl is enough water to make 500 ml of solution
2.0 m/L
4.05 m/L
5.0 m/L
4.05 g/L
The determination of the equilibrium constant of a colored species can be done via which technique?
Conductance
Ion-exchange
Electrophoresis
Spectrophotometry
A solution has 3X10^-4 copper 2+ content. How much is the copper 2_+ content in ppm?
3 ppm
9 ppm
19 ppm
38 ppm
Solution of electrolytes and metals are
Insulators
Negative
Polar
Conductors
The recommended procedure for preparing a very dilute solution is not to weigh out a very small mass or measuring a very small volume of a stock solution. Instead it is done by a series of dilutions. A sample of 0.8214 g of KMnO4 (158.04) was dissolved in water and made up to the volume in a 500- ml volumetric flask. A 2.000-ml sample of this solution was transferred to a 1000-ml volumetric flask and diluted to the mark with water. Next, 10.00 ml of the diluted solution were transferred to a 250-ml flask and diluted to the mark with water. What is the concentration (in molarity) of the final solution?
0.1039 M
2.079 x 10^-5 M
8.316 X 10^-7 M
NONE OF THESE
How much of 2.0 M stock solution do you need to prepare 50 ml of 1.0 M solution
25 ml
75ml
30 ml
50 ml
A statement that sums up what you learned from an experiment and states if the hypothesis is proven and disproven is called
procedure
hypothesis
control group
conclusion
A prediction or a possible explanation to the question or problem which can be tested in an experiment is called
hypothesis
graph
procedure
data
The number of 2.34 x10^-7 is the scientific notation for
234000
23400000
23400
2340000
Express the number 0.051065 to four significant figures
0.051
0.05106
0.051
0.0511
The volume of a liquid is 20.5 mL. Which of the following sets of measurement represents the value with good accuracy?
19.2 mL, 19.3 mL, 18.8 mL, 18.6 mL
18.9 mL, 19.0 mL, 19.2 mL, 18.8 mL
18.6 mL, 17.8 mL, 19.6 mL, 17.2 mL
20.2 mL, 20.5 mL, 20.3 mL, 20.1 mL
What is the chemical formula of diphosphorus monobromide?
PBr2
P2Br2
PBr
P2Br
Which of the following is a chemical reaction?
an airconditioner cooling the air.
none of these choices
bleaching your clothes
melting of ice
Noble gases are inert because they have completed outer electron shells. Which of these elements isn't a noble gas?
Chlorine
Krypton
Helium
Argon
What is the most common isotope of hydrogen?
Hydrogen is the most common type of isotope
Tritum
Deutrium
Protium
As you move from top to bottom down the periodic table
change in atomic radius cannot be predicted
electronegativity decreases
ionization energy increases
atomic radius decreases
What do you call an atom that has more protons than electrons?
An anioN
Molecule
None of these
Cation
Which one of the following is a chemical equation
CO2
Ice + heat = water
C + O2 = CO2
iron + oxygen = rust
As you move from left to right across the periodic table
atomic radius Increases
electronegativity decreases
ionization energy decreases
atomic radius decreases
Balance the following equation:Ag + O2 → Ag2O
Put a 2 in front of Ag
Add a 4 in front of Ag and a 2 in front of Ag2O
Add a subscript 2 to the end of Ag2O
Add a 2 in front of Ag and a 1 in front of. Ag2O
hich is NOT an acceptable name for HgCl2
Mercury II chloride
Mercurous chloride
Mercury I Chloride
Dimercury Chloride
Under the Lewis concept of acids and bases, an acid is
An electron pair donor
a proton donor
a proton acceptor
an electron pair acceptor
Which of the following is NOT an acid?
milk of magnesia
milk
apple juice
gastric juice
Which of the following is NOT an acid-base conjugate pair?
NH3 and NH,*
H2O and OH
H2S and OH
HCN and CN
When NH.CI hydrolyzes, the resulting solution is
Acidic
Basic
Neutral
None of these
Aqua regla, the reagent that can be used to dissolve gold, is a 3:1 mixture of which acids?
hydrochloric and nitric acids
hydrofluoric and nitric acids
hydrochloric and sulfuric acids
hydrochloric and sulfuric acids
Which of the following conjugate acid/base pairs should be used to prepare a buffer with pH near 7.15?
Formic acid / sodium formate (pKa – 3.74)
Sodium dihydrogen phosphate/ sodium hydrogen phosphate (pKa2 = 7.20)
Succinic acid/sodium succinate (pKa = 5.64)
Glycylglycine / sodium glycylglycate (pKa = 8.35)
Predict the products of the following acid-base reaction: NH1(aq) + HNO3(aq)
no reaction takes place
NH2OH(aq) + HNO2(aq)
NH4OH(aq)
NH4NO3(aq)
What is the gas which behaves the most like an ideal gas?
Oxygen
Helium
Nitrogen
Hydrogen
What happens to the volume of a fully inflated balloon when it is taken outside on a cold day?
its volume decreases
volume increases
remains the same
volume becomes equal to zero
The standard pressure of the atmosphere at sea level is
760 mm Hg
760 torr
all of the choices
1atm
Each of these flask contains the same number of molecules. In which container is the pressure highest?
Flask 2
Flask 1
Flask 3
Flask 4
What is the molar mass of an unknown gas if 11.60 grams of the gas occupies volume of 2.24 at STP?
35.8 g/mol
16.0 g/mol
160 g/mol
81.0 g/mol
When chromium changes from an oxidation state of +3 to that +6 the Cr3 must.
gain 3 electrons
lose 3 electrons
lose 6 electron s
gain 3 electrons
In an electrolytic cell oxidation occurs
at the anode
between cathode and anode
either cathode and anode
at the cathode
For this reaction Mg + H2O = Mg0 + H2
H is the oxidizing agent
Mg is the oxidizing agent
Mg lost electrons
H gained electrons
Which procedure is recommended for reading the level of an aqueous solution in a buret or graduated cylinder?
Keep the eye level with the top of the meniscus and record that reading
Read both the bottom and top of the meniscus and average those readings
Keep the eye level with the bottom of the meniscus and record that reading
Look down at the meniscus at an angle to obtain the average reading directly
What is the Main ISO standard used by testing and calibration laboratories to gain accreditation and formal recognition of their competence to carry out tests and/or calibrations, including sampling?
ISO/IEC 17025
AOAC
EURACHEM
IS0 9000:2000
This detects contamination from reagents, sample handling, and the entire measurement process.
matched-matrix blank
solvent blank
method blank
calibration blank
There is a definite correlation between orderliness and level of safety in the laboratory. In addition, a disorderly laboratory can hinder or endanger emergency response personnel. Which of the following housekeeping rules should NOT be adhered to?
never obstruct access to exits and emergency equipment
properly label and store all chemicals
store chemical containers on the floor
clean work areas, including floors, regularly
In order to ensure an accurate weighing when using the balances, one should
leave the object on the balance for several minutes to ensure a stable reading
not lean on the balance bench, close the draft doors on the balance and zero the balance prior to weighing
turn the balance off to clear any previous weighings from its memory
turn the balance off to clear any previous weighings from its memory
Which of the following is NOT part of the technique for pouring in a laboratory?
Connect the pouring spout and receiving container using a stirring rod
Pour fast enough to avoid spills
Pour and allow the liquid to run along the stirring rod
Hold containers at arms length, with elbows slightly bent
The method that is widely used for the determination of the protein content of meat and animal food is the
Kjeldahl method
McBride method
Mohr method
Liebig method
What os the %w/w H2O in the cheese if the final mass was found to be 545.8 mg
35.23 %
30.6 %
31.45%
37.65%
An analytical chemist needs to transfer his/her precipitants from the beaker to the filter paper. Which of the following would be the best procedure to adopt in order to ensure a quantitative transfer of the precipitate?
None of the choices
Most of the liquid above the ppt is decanted first, then bulk of ppt is transferred to filter paper through a stirring rod, the beaker is washed with big volumes of wash solution.
Most of the liquid above the ppt is decanted frst, bulk of the ppt is transferred through a stirring fod, wash the beaker several times with small volumes of wash solution.
Solution is shaken, then immediately filtered; beaker is washed with relatively big volumes of wash solution.
A water sample is collected for analysis of oil and grease. The analysis will not be done Immediately. The sample should NOT be
collected in plastic bottle
refrigerated til analyzed
preserved with sulfuric acid
collected in all glass bottle
When two materials that have different densities, like oil and water, encounter one another, they will
separate according to their densities
exchange densities
mix uniformly
repel one another
Conductivity is defined as
The ability of a substance to conduct electric current, which is the same as resistivity
The ability of a substance to repel electric current
The ability of a substance to conduct variable resistance
The ability of a substance to conduct electric current, which is the reciprocal of resistivity
Even though all solid states of other materials are denser than the liquid states of materials, what is a unique property of water?
It is clear
It is tasteless
Solid water (ice) is less dense than liquid water (ice floats in water)
It can freeze
he following statements are true about electrical conductivity EXCEPT
a measure of a solution s capacity to conduct electricity
a measure of the total dissolved solids in a solution
increasing temperature has no effect on its value
is directly affected by temperature
The following statements are true about pH EXCEPT
the negative logarithm of hydrogen ions content in a solution
a measure of the acidity or alkalinity of a solution
a measure of the amount of hydrogen ions in solution
does not change when there are changes in temperature
In maintenance and storage of pH meters, which of the following procedure shall NOT be done?
Mild soap solution may be used in general cleaning of the electrodes
To keep the electrode bulb moist during storage, store the electrode in distilled water.
Blot the electrode dry after rinsing the pH electrodes.
Rinse pH electrodes in between measurements.
In operating a UV-Vis spectrophotometer, the following shall be done, EXCEPT for
Before turning on the power, check if the sample holder does not contain anything
After turning on, allow the spectrophotometer to initialize and stabilize according to its user manual.
If there are any spillage that gets onto the instrument, immediately wipe it away
Keep the sample compartment open during measurement.
In using fume hoods, the following shall be done, EXCEPT for
Items contaminated with odorous or hazardous materials should be removed from the hood only after decontamination or if placed in a closed outer container to avoid releasing contaminants into the laboratory air.
he hood shall be kept closed, except during apparatus set-up or when working within the hood.
The hood may be used as a permanent storage area for volatile chemicals when an appropriate storage cabinet is not available.
Ensure the exhaust is operating before using the hood.
In purifying a material by crystallization choose the solvent according to the following EXCEPT
solubility
reactivity
vapor pressure
polarity
The dynamic range in analytical measurement refers to the range where
the instrument reading is constant
the detection limit lies
the sensitivity of the instrument is highest
the instrument reading is linearly related to the input value
What is the law that states the linear relationship between absorbance and concentration of an absorbing species?
Boyles LAw
Charles Law
Beer Lamberts Law
Avogrados Law
Determine the actual volume contained in a 50.0 mL volumetric flask given the following data: Mass of water: 50.1227 g, Density of water at 25 C: 0.99707 g/mL
50.27 ml
50.17 ml
50.37 ml
50.45 ml
A lab analyst dissolved 4.021 g of NaOH in water and made up the solution to 1 litre with water. He then pipetted 10.00 mL of this solution into a flask and titrated it with 0.050 M HCl solution from a burette. A volume of 20.32 mL of acd had been used at the endpoint. Examining this result, the lab supervisor could deduce that
the NaOH absorbed H2O from the air after its mass was measured
the burette was rinsed with water instead of HCI
the analysis is as accurate as can be expected using this apparatus
the pipette was rinsed with water instead of NaOH
In which of the following titrations does pH = 7.0 occur at the equivalence point?
1.Strong acid/strong base
II. Weak acid/Strong acid
III. Strong acid/Weak Base
I only
II and III only
III only
II only
The following are good sampling practices EXCEPT
Collect the sample in a container made of material that will chemically react with the sample.
Sample frequently enough to allow for the identification of process cycles.
Take several increments and composite them to form the sample.
If possible, mix the material before getting the sample.
In liquid-liquid extraction, it is often necessary to determine which liquid is aqueous and which liquid is nonaqueous. To test the liquids, add a drop of water to the top layer. If the drop dissolves in the top layer, the top layer is
aqueous
miscible
denser
non aqueous
The process in which the sample is heated to the boiling point of the solvent and volatile analytes are concentrated in the vapour phase, condensed and collected.
distillation
evaporation
liquid - liquid extraction
oven drying
Glass container is NOT suitable for
oil and grease determination
all of the choices
microbiological analyses
inorganic trace analyses
The maximum holding time for acid preserved samples that will be subjected to determination of
48 hrs
6 months
3 months
1 week
The substance which does the dissolving and must be greater than 50% of the solution is called
solute
solvent
mixture
solution
Quantitative chemical analysis of weighing a sample, usually of a separated and dried precipitate
Gravimetric Analysis
Elemental Analysis
Volumetric Analysis
Titrimetric Analysis
Which of the following is a primary standard for use in standardizing bases?
Acetic Acid
Potassium Hydrogen Phthalate
Sulfuric Acid
Ammonium Hydroxide
How many grams of Sodium Persulfate (Na2S2O) are required to prepare a 1 L solution of Sodium Persulfate with concentration of 10% (w/v). This solution is widely used as oxidizing reagent for Total Organic Carbon analyzer (TOC).
100 g Sodium Persulfate
102 g of Sodium Persulfate
101 g of Sodium Persulfate
99 g of Sodium Persulfate
How many grams of sodium hydroxide is needed to prepare 500 mL of 0.5 N sodium hydroxide? (Sodium 22.99 g/mole, Oxygen- 16.00 g/mole, Hydrogen= 1.008 g/mole)
13.8115 g
9.9995 g
15.7470 g
10.2515 g
What is the light source used in the visible range to 340-1000 nm ?
Nerst Blower
Deutrium
Tungsten
Incandescent
Minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero refers to
Lower Warming Limit
Lower Control Limit
Method Detection Limit
Limit of Quantitation
Which of the following instruments uses a cuvette?
Gas Chromatography
ph meter
UV Vis Spectrometer
Flame AAS
The most appropriate technique to determine levels of the Pb2+ ion in blood is
Atomic Absorption Spectroscopy
Mass Spectrometry
Infrared Spectroscopy
High Performance Liquid Chromatography
Analytical methods or instruments' performance aim for
Low signal-to-noise ratio
Low dynamic range
High variability
High signal-to-noise ratio
A graphical representation of measuring signal as a function of quantity of analyte is called
Absorbance Chart
Calibration Curve
None of the choices
Quality Control Chart
For the reaction, Fe3(aq) + SCN ̈(aq) <=> FeSCN2+(aq)
reaction can best be determined by means of
lon-exchange
Spectrophotometry
Conductance
Chromatogrpahy
. A food scientist has a sample of a plantoil and wants to determine if the oil contains saturated or unsaturated fatty acids. Which of the following spectroscopic techniques would be most useful for this purpose?
mass spectroscopy
infrared spectroscopy
ultraviolet spectroscopy
visible spectroscopy
What is a graph showing the detectors response as a function of elution time: band's shapes, position, resolution?
monitor display
quality control chart
chromatogram
calibration curve
. A stable light source in AAS analysis, which is necessary to emit the sharp characteristic spectrum of the element to be determined is called
Tungsten lamp
deuterium lamp
hollow cathode lamp
Nerst blower
It is a hazardous waste characteristic which applies to wastes that have the potential to contaminate groundwater if improperly disposed of. These materials are regulated as hazardous waste due to their potential to leach out specific toxic substances in a landfill.
Reactivity
Toxicity
Corrosivity
Ognitability
In handling acid wastes, what type of protective gloves should be used?
Rubber Gloves
Disposal Gloves
Cloth Gloves
All of the choices
According to Revised DAO 04-36, the appropriate waste labels shall include
all of the choices
Volume Waste
Generator ID number
Container MAterial
he following acids and acid mixtures can be collected and placed in glass containers EXCEPT for
Sulfuric Acid
Aqua Regia
Hydrofluoric Acid
Hydrochloric Acid
When working with concentrated acids except hydrofluoric acid, which of the following statements are TRUE?
1. Acid-resistant gloves covering the whole arm or Nitrile gloves should be worn.
II. Half- or full-faced masks with gas- and/or vaporremoving respirators should be worn.
III. Wearing safety boots or foot covering is optional as long as the person is working under the hood. IV. Wearing of apron is optional as long as laboratory gown is worn.
I and II only
all of the choices
II and III only
I and IV only
The fire triangle consists of which of the following?
Oxygen, Heat, Material
Air, Fuel, Spark
Air, Heat, Fire
Oxygen, Heat, Fuel
In order to properly maintain chemical laboratory equipment one should perform the following EXCEPT
place the equipment in hot humid location
regular calibration of equipment
regular inspection of operational components
thorough cleaning with the proper materials
Which is TRUE about laboratory fume hoods?
all of the choices
Provides further protection by diluting low concentration of flammable gases below explosion limits.
It protect you from being exposed in chemical fume.
Must always be on.
What is the type of chemical that can cause an allergic reaction in the airways following inhalation of the chemical ?
Corrosive
Oxidizer
Respiratory Sensitizer
Carcinogen
Which of the following may be disposed in the sink?
0.1 M H2SO4
none of the choices
1 g/ml PC14
200g/ml PC14
Ammonia solution can be stored with the following chemicals EXCEPT for
cyclohexane solution
2-propanol solution
acetic acid solution
sodium hydroxide solution
Which of the following can cause ERRORS during the sample preparation stage?
I.Loss of sample during weighing or dissolution
II.Contamination by impurities in reagents and in the environment
III.Changes in mass due to varying humidity and temperature
IV.Obtaining inhomogeneous sample from the bulk
I and II only
I, II, III
I, III, IV
I, II, III, IV
What will you perform to know that the Atomic absorption spectrometer continues to work properly?
Calibration check
QC sample recoveries
Blank
sTANDARD aDDITION
Consider that you are working with Vitamin C tablet production, to which standard/s should your quality management should subscribe?
GMP
HACCP
ISO 9001:2008
ALL OF THE CHOICES
The test that decides whether a datum from a given set could be rejected or NOT is
T TEST
Q TEST
Z TEST
F TEST
Saying that the concentration of Total cyanide (CN) in drinking water is 0.05 mg/L, which is below the maximum allowable level of 0.07 mg/L as per DOH DAO No. 20070012 when it is actually
ACCURATE
PRECISE
FALSE NEGATIVE
FALSE POSITIVE
As per Lewis concept, what is base
accepts the electron
donates electron
proton accepts
donates protons
As per Lewis Concept, acid
donates electron
accept electron
proton accepts
proton donates
largest volume, lowest
(a)
oxidation state means, loss of (a)
Widely used known in Anal Chemistry, standardizing permanganate solution using sodium oxalate
(a)
SOLVENT EXTRACTION (TWO IMMISCIBLE PHASES)
LIQUID LIQUID EXTRACTION
SUBLIMATION
DISTILLATION
CRYSTALLIZATION
340 TO 1000 nm (continuous spectrum light
(a)
190 - 400 nm (high density)
(a)
190 to 1000 nm
(a)
minimum concentration of a substance with 99% confidence
(a)
lowest concentration amount of substance
(a)
control chart/ potential problems
(a)
Statistical theshold, a process of parameter
(a)
testing water samples for pollution
analyze metal ions and organic compounds
Liquid Chromatography
Gas Chromatography
Thin Layer Chromatography
pAPER cHROMATOGRAPHY
Detecting bombs, in airports, drugs, alcohols
used to analyze volatile gases
Liquid Chromatography
Gas Chromatography
Thin Layer Chromatography
Paper Chromatography
pesticides, insecticides
absorbent of material in flat glass
rapid method to check purity
Gas Chromatography
Thin Layer Chromatography
Paper Chromatography
Liquid Chromatography
Separating amino acids and anions RNA, fingerprinting anti biotics
most common type/stationary phase
pull the solutes up through the paper
Paper Chromatographty
Thin Layer Chromatography
Liquid Chromatography
Gas Chromatography
Activities connected with the collection and disposal of waste
(a)
For redox titrations
(a)
Its differentiate between water soluble, carbohydrate, and ketone
(a)
for the presence of carbohydrates
Molish Reagent
Tollens Reagent
Starch Solution
Millons Reagents
Silver mirror test
Iodine Reagent
Tollens Reagent
Grignard Reagents
Starch Solution
acid base titrations
Phenophthalein Solution
Starch Solution
Soluble Solution
Millons Solutions
Iodine Test
Iodine Reagents
Fehling Solution
Tollens Reagents
Starch Solution
Soluble proteins
Millons Reagents
Starch Solution
Grignard Solution
Molish Reagents
Alkyl and Alkenyl Halides
Fehling Solution
Starch Solution
Tollens Solution
Grignard Reagents
Measure the amount of light absorbed by a sample, concentrations of solutes in a solution.
(a)
Maybe solid or liquid cant be gas
Stationary Phase
Mobile Phase
maybe liquid or gas cant be solid
Mobile Phase
Stationary Phase
Aims to achieve and maintain clean air that meets the National Air Quality
(a)
Aims to protect water bodies from pollution
RA 8749
RA 9249
RA 9275
RA 6969
Aims to regulate restrict or prohibit the importation manufacture processing and sale distribution use of disposal of chemical substance and mixtures and present
RA 6969
RA 8249
RA 9275
RA 8749
Enacted and implemented in June 6, 1977 (Philippine Environment Code)
PD 1152
PD 1586
PD1189
PD1159
to facilitate the attainment and maintenance of rational and orderly balance between socio economic, establish of EIA (Environmental Impact Assessment)
PD 1152
PD 1586
PD 1578
PD 1670
Aim to adopt a systematic, comprehensive and ecological waste solid management program, proper segregation and disposal (Ecological Solid Waste Management Act of 2000)
RA 9003
RA 9512
RA 6979
RA 6969
Provides for the promotion of environmental awareness through environmental education which shall encompass (Environmental Awareness and Education Act 2008)
RA9215
RA 6969
RA 9003
RA 8742
Benzene and its derivatives undergo substitution reactions instead of addition reactions because
the integrity of the benzene ring and the stable pi-bonding pattern remains intact
the hydrogens of benzene are relatively loosely bound
the benzene ring is sterically crowded hence only substitution can occur
the benzene ring is electron rich
Electrophiles are
electron deficient species
electron rich species
electrically neutral species
positively charged ion
SN2 means
two step nucleophilic substitution mechanism involving both alkyl halide and nucleophile
one step nucleophilic substitution mechanism involving both alkyl halide and nucleophile
two step nucleophilic substitution mechanism involving only the alkyl halide
one step nucleophilic substitution mechanism involving only the nucleophile
In the decomposition and dissolution of solids during sample preparation, which of the followingis expensive and often the last resort?
Acid treatment using oxidation
Fusion technique
dissolution using ultrasound & appropriate solvent
Simple dissolution
It is important to discard containers that are scratched or abraded on their interior surfaces. The internal surface area of a container, whether used for sample preparation or storage, may cause loss of
matrix
analyte
weight
ash
Glass container is not suitable for
inorganic trace analyses
oil and grease determination
microbiological analyses
all of the above
Which of the following is a primary standard for use in standardizing bases?
Ammonium hydroxide
Sulfuric acid
Acetic acid
Potassium hydrogen phthalate
A solution has been prepared by transferring 60 mL from Ortho-phosphoric acid 85 % (v/v) H3PO4 and diluting it to 1.0 L, what is the concentration of the new solution.
10.10%
9.25%
12.2%
5.10%
A student has got three stock standard solutions of 3 different elements, zinc (Zn) 2000 ppm,
cadmium (Cd) 1500 ppm and lead (Pb) 1000 ppm. A student took 10 mL from each solution and
transfers it to 200 mL volumetric flask then completed to total volume with solvent. What is the
final concentration of each element in the diluted mix solution?
50 ppm Zinc, 32 ppm Cd, 25 ppm Pb
100 ppm Zinc, 75 ppm Cd, 50 ppm Pb
75 ppm Zinc, 75 ppm Cd, 50 ppm Pb
100 ppm Zinc, 25 ppm Cd, 25 ppm Pb
The HPLC column type in which molecules are separated according to size.
Ion exchange
size exclusion
normal phase
reverse phase
During ignition for ashing, muffle furnaces that go up to 1100oC are used primarily for this and________ is needed to contain the sample.
porcelain crucible
evaporating dish
beaker
all of the above
A graphical representation of measuring signal as a function of quantity of analyte.
Calibration curve
Quality Control Chart
Absorbance Chart
None of the above
In AAS method, If the sample concentration is too high to permit accurate analysis in linearity response range, there are alternatives that may help bring the absorbance into the optimum working range.
sample dilution
using an alternative wavelength having a lower absorptivity
reducing the path length by rotating the burner hand
All of the above
A student has to measure out 9.40 mL of a liquid and selects a 100 mL graduated cylinder. To improve the accuracy of the measurement, it would be most effective to:
take the average of multiple measurements using the graduated cylinder.
measure the liquid using a 25 mL graduated cylinder instead.
estimate the measurement obtained from the graduated cylinder to an additional significant figure.
measure the liquid using a 10 mL graduated pipette instead.
A buffer solution may be a mixture of
a weak acid and its salt
a weak base and its salt
an excess of a weak acid with a strong base
all of the above
Which statement is true?
The value of the equilibrium constant increases with the addition of a catalyst
A catalyst speeds up both the forward and reverse reaction rates
The greater the activation energy, the faster the rate of reaction.
A catalyst increases the rate of reaction by decreasing the number of collisions
What volume is occupied by 4.00 g of carbon dioxide, CO2 (44.0) gas at a pressure of 0.976 atm and a temperature of 25.00C?
0.191 L
19.1 L
2.28 L
22.8 L
Molecular oxygen is highly soluble in the blood because
the hemoglobin molecule can bind up to four oxygen molecules
the solubility of oxygen is increased by the higher temperature of the body
pressure is increased inside the body
pressure inside the body is different outside of it
When water is heated in a beaker, bubbles of air form on the side of the glass before the water boils. This shows that
the solubility of gases in water decreases with increasing temperature
the solubility of gases in water increases with increasing temperature
the solubility of gases in water decreases with decreasing temperature
the solubility of gases in water increases with decreasing temperature
The absorbance of different concentrations of potassium permanganate determined through UV- Vis Spectrophotometer is shown below.
The Quality Control Sample for this run gave an average absorbance reading of 0.486. The
theoretical concentration of the QC sample is 44.4 ppm. Calculate for the error of this QC run.
0.0524
0.0552
0.0465
0.00052
Method of passing the sample through a metal or plastic mesh of a uniform cross-sectional area to separate particles into uniform sizes.
sieving
pulverizing
macerating
milling
In handling acid wastes, what type of protective gloves should be used?
Cloth gloves
Surgical gloves
Rubber gloves
Disposal plastic gloves
What type of container must be used for acid or alkali wastes?
Polyethylene Drums
Metal drums
Fiber Drums
Cloth container
A solid waste management practice which refers to the controlled decomposition of organic matter by microorganisms, mainly bacteria and fungi, into a humus-like product.
Composting
Recycling
Bioremediation
Reducing
A series of reference standards solutions that have known and accurate pH values at different temperatures used for pH meter calibration.
Buffer Solutions
QC Solutions
pH solutions
None of the above.
Law that states the linear relationship between absorbance and concentration of an absorbing species
Beer-Lambert’s Law
Charles Law
Boyles Law
Avogadro’s Law
Type of quality-control sample used to evaluate the effects of sample matrices on the
performance of an analytical method
Matrix Duplicate
Matrix Spike
Method Blank
Reagent Blank
Component of error which, in the course of a number of analyses of the same measurand, remains constant or varies in a predictable way.
Random Error
Analyst’s Error
Systematic Error
Uncertainty
It is a pure dry solid substance of known chemical composition used in the direct standardization of solution.
primary standard
secondary standard
analytical standard
indicator
It is the closeness of the agreement between the result of a measured value and a true value.
Accuracy
Precision
Mean
Error
Sample preparation technique used prior to instrumental analysis of metals.
acid digestion
liquid-liquid extraction
sieving
clean-up
Which of the following chemicals may be used to neutralize waste containing caustic soda?
Potassium Hydroxide
Ammonia
Hydrochloric Acid
Buffer 10 Solution
Which of the following are possible routes of exposure of the hazardous effect of waste?
Inhalation
Dermal
Ingestion
all of the above
According to Revised DAO 04-36, the appropriate waste labels shall include:
Volume of Waste
Generator ID Number
Container Material
All of the above
Sampling type that eliminates questions of bias in selection
composite
stratified
systematic
random
Reliability of the results decreases with a decrease in the level or concentration of the:
matrix
analyte
reactant
product
Properties of nitric acid making it the preferred acid for digesting samples for the analysis of metals.
acts as a strong acid
as an oxidizing agent
does not form insoluble compounds with metals/nonmetals
All of the above
Locating the adulterated portion of the lot for sampling is an example of
random sampling
selective sampling
composite sampling
stratified sampling
Quantitative chemical analysis of weighing a sample, usually of a separated and dried precipitate.
Titrimetric analysis
Volumetric analysis
Gravimetric analysis
Elemental analysis
The substance which does the dissolving and must be greater than 50% of the solution.
solvent
solute
mixture
solution
Used for vacuum filtration using filter paper.
gooch crucible
Buchner funnel
rotary evaporator
rubber aspirator
In chromatography, ________ is carried out on glass plates or strips of plastic or metal coated on one side with a thin layer of adsorbent.
HPLC
GC
Paper Chromatography
Thin Layer Chromatography
Chromatography is used to
Separate two or more compounds based on their polarities.
Separate two or more compounds based on their masses.
Separate two or more compounds based on how strongly they interact with other compounds
all of the above
A technique for separating mixtures into their components in order to analyze, identify, purify, and/or quantify the mixture or components.
Spectroscopy
Chromatography
Gravimetry
Titrimetry
A graph showing the detectors response as a function of elution time : band’s shapes, position, resolution
monitor display
quality control chart
calibration curve
chromatogram
Under the Bronsted concept of acids and bases, a base is
a proton donor
a proton acceptor
a hydroxide donor
an electron pair donor
Which of the following is not a common method used for purification?
Sublimation
Crystallisation
Electrolysis
Chromatography
The solution of impure compound and solvent is concentrated to get ____________
Unsaturated solution
Undersaturated solution
Saturated solution
Oversaturated solution
Insoluble impurities from solution during crystallization are removed by ____________
Drying
Filtration
Heating
Cooling
Crystal phases can be interconverted by varying ____________
Temperature
Pressure
Size
Viscosity
Which of the following is not separated through distillation process?
Acetone and water
Aniline and chloroform
Impurities in seawater
Milk and water
Column chromatography is based on the principle of _______________ (this question appeared twice)
Ion-exchange
Exclusion principle
Differential Adsorption
Absorption
Select the correct statement from the following options.
The lesser the polarity of solute, more strongly it will be adsorbed on a polar surface
The greater the polarity of solute, more weakly it will be adsorbed on a polar surface
The greater the polarity of solute, more strongly it will be adsorbed on a polar surface
All of the mentioned option
The elution power of a solvent is determined by ____________
Its overall polarity
The polarity of the stationary phase
The nature of the sample components
All of the mentioned
The principle on which thin layer chromatography is based is that the ____________
Different compounds are absorbed on an absorbent to different degrees
Different compounds are absorbed on an absorbent to same degrees
Different compounds are adsorbed on an adsorbent to different degrees
Different compounds are absorbed on an absorbent to same degrees
Which type of chromatography is used for the structural analysis?
Column chromatography
Paper chromatography
Partition chromatography
Affinity chromatography
Affinity chromatography is used for the analysis and isolation of ____________
Insoluble starch substances
Enzyme tyrosinase
Antibodies bound with a covalently-attached antigen on cellulose column
All of the mentioned
Which of the following is not an application of high performance liquid chromatography?
Analysis of proteins, drugs and explosives
Separation of pharmaceutical drugs
Elimination of undesirable substances from blood
Separation of lipids, fatty acids and steroids
Which of the following is the application of ion exchange chromatography?
Ion exchange chromatography
Thin layer chromatography
Gas chromatography
Liquid chromatography
The temperature at which solid and liquid coexist in equilibrium is called ____________
Melting point of liquid
Freezing point of liquid
Freezing point of solid
All of the mentioned
The analysis of electromagnetic radiation scattered, absorbed or emitted by the molecule is called
Kaleidoscopy
Astronomy
Spectroscopy
Anatomy
Select the correct statement from the following option.
Spectroscopic methods require less time and more amount of sample than classical methods
Spectroscopic methods require more time and more amount of sample than classical methods
Spectroscopic methods require less time and less amount of sample than classical methods
Spectroscopic methods require more time and less amount of sample than classical methods
Which of the following is not in the infrared spectrum?
HCl
H2O
CO2
CH4
The components of the mixture in column chromatography are eluted in order of
increasing polarity and increasing distribution ratio.
increasing polarity and decreasing distribution ratio.
decreasing polarity and increasing distribution ratio.
decreasing polarity and decreasing distribution ratio.
An industrial source of alcohol.
Coal
Fats
Sugar
Ether
A 22/24 stopper is used in a volumetric flask. Which of the following is true? (Same concept as
this).
The diameter is 24 cm and the height is 22 cm.
The diameter is 22 cm and the height is 24 cm.
The diameter is 24 mm and the height is 22 mm.
The diameter is 22 mm and the height is 24 mm.
This type of glass is commonly used for laboratory glassware.
Amber
Quartz
Fused silica
Borosilicate
In the analysis of a mixture by gas chromatography, which of the following gives the best clue as to whether the components can be analyzed with any degree of accuracy? (Same concept)
Column length
Retention times
Column temperature
Flow rate of the carrier gas
Why is there a need to separate halogenated waste from non-halogenated waste?
Halogenated waste disposal is more costly.
Non-halogenated wastes are more toxic.
They are not compatible.
They will react.
In an ideal gas of volume V and temp T. What happens to T when volume is doubled under constant P?
Increases
Decreases
Remains Constant
Doubled
Water is a good solvent for benzoic acid recrystallization.what is the correct preparation of benzoic solution for recrystallization.
Add benzoic acid to minimum hot water with stirring
Add room temp water to benzoic while stirring until dissolved
Add maximum hot water to benzoic acid while stirring
Add small.portions of hot water to benzoic acid while stirring. Until dissolve
The gas-solid chromatography is ____________ chromatography as per basic principle involved
Exclusion
Ion exchange
Adsorption
Absorption
A compound is known to decompose at its boiling point, which of the following methods can be used to purify this substance
Simple distillation
vacuum distillation
liquid-liquid extraction
steam distillation
A solution is _______ if more solute can dissolve in it.
saturated
supersaturated
unsaturated
concentrated
Organic peroxides are dangerous when
Heated
Concentrated
Let ether, p-dioxane, THF, among others to vaporize
All of the above
This quality system standard is a general requirement for the competence of testing and
calibration laboratories.
GLP
GMP
ISO 9000
ISO/IEC 17025:2005
