Materials ;metals and non-metals

Materials ;metals and non-metals

Introduction

Everything around us is categorized into either metals or non-metals. Hence, it is important to know what non-metals and metals are and how to distinguish them. The class 8 science chapter 4 discusses the various physical and chemical properties of metals and non-metals. To help you with it, here we list a few physical and chemical properties of metals and non-metals.

Metals Metals are described as chemical elements that readily lose valence electrons to form positive ions (cations).Examples: Aluminium, copper, iron, tin, gold. Around 90 of the total 118 elements are metals.

Physical Properties Physical Properties of Nonmetals Occur as solids, liquids, and gases at room temperature Brittle Non-malleable Non-ductile Non-sonorous Bad conductors of heat and electricity

Exceptions in Physical Properties Alkali metals (Na, K, Li) can be cut using a knife. Mercury is a liquid metal. Lead and mercury are poor conductors of heat. Mercury expands significantly for the slightest change in temperature. Gallium and cesium have a very low melting point Iodine is non-metal but it has lustre. Graphite conducts electricity. Diamond conducts heat and has a very high melting point.

Physical Properties of Metals● Hard and have a high tensile strength

● Solids at room temperature, except mercury, which is liquid at room temperature.

● Sonorous

● Good conductors of heat and electricity

● Malleable, i.e., can be beaten into thin sheets

● Ductile, i.e., can be drawn into thin wires

● High melting and boiling points (except Cesium (Cs) and Gallium (Ga))

● Dense, (except alkali metals). Osmium – highest density and lithium – least density

● Lustrous

● Silver-grey in colour, (except gold and copper)

Non-MetalsNon-metals are those elements, which do not exhibit the properties of metals.

Examples: Carbon, Boron etc.

Chemical Properties of Metals● Alkali metals (Li, Na, K, etc) react vigorously with water and oxygen or air.

● Mg reacts with hot water.

● Al, Fe, and Zn react with steam.

● Cu, Ag, Pt, Au do not react with water or dilute acids.

Chemical PropertiesDisplacement ReactionsA more reactive element displaces a less reactive element from its compound or solution.

i) Zn(s)+CuSO4(aq)→ZnSO4(aq)+Cu(s)

ii) 2Al(s)+Fe2O3(molten)→Al2O3(s)+2Fe(molten)

Metals Reaction with Oxygen (Burnt in Air)Metal + Oxygen  →  Metal oxide (basic)

● Na and K are kept immersed in kerosene oil as they react vigorously with air and catch fire.

4K(s)+O2(g)→2K2O(s) (vigorous reaction)

● Mg, Al, Zn, Pb react slowly with air and form a protective layer that prevents corrosion.

2Mg(s)+O2(g)→2MgO(s) (Mg burns with a white dazzling light)

4Al(s)+3O2(g)→2Al2O3(s)

● Silver, platinum, and gold don’t burn or react with air.

Basic Oxides of MetalsSome metallic oxides get dissolved in water and form alkalis. Their aqueous solution turns red litmus blue.

 Na2O(s)+H2O(l)→2NaOH(aq)

 K2O(s)+H2O(l)→2KOH(aq)

Amphoteric Oxides of MetalsAmphoteric oxides are metal oxides which react with both acids as well as bases to form salt and water.

For example – Al2O3,ZnO,PbO,SnO

Al2O3(s)+6HCl(aq)→2AlCl3(aq)+3H2O(l)

Al2O3(s)+2NaOH(aq)→2NaAlO2(aq)+H2O(l)

ZnO(s)+2HCl(aq)→ZnCl2(aq)+H2O(l)

ZnO(s)+2NaOH(aq)→Na2ZnO2(aq)+H2O(l)

Reaction of Metals with Water/Steam Metal+Water→Metal hydroxide or Metal oxide+Hydrogen

 2Na+2H2O(cold)→2NaOH+H2+heat

 Ca+2H2O(cold)→Ca(OH)2+H2

 Mg+2H2O(hot)→Mg(OH)2+H2

 2Al+3H2O(steam)→Al2O3+3H2

 Zn+H2O(steam)→ZnO+H2

Reaction of Metals with AcidMetals, which are reactive than hydrogen displace hydrogen from its dilute acids and produce respective metal salts and hydrogen gas. Example: Metal+dilute acid→Salt+Hydrogen gas2Na(s)+2HCl(dilute)→2NaCl(aq)+H2(g)2K(s)+H2SO4(dilute)→K2SO4(aq)+H2(g) Metals, which are less reactive than hydrogen cannot displace hydrogen from its acids and hence no reaction takes place.

How Do Metals React with Solution of Other Metal SaltsHigh reactive metal displaces the low reactive metal from its salt solution.

  Metal A+Salt of metal B→Salt of metal A+Metal B

Fe(s)+CuSO4(aq)→FeSO4(aq)+Cu(s)

Reaction of Metals with BasesBase+metal→salt+hydrogen

2NaOH(aq)+Zn(s)→Na2ZnO2(aq)+H2(g), when zinc reacts with aqueous sodium hydroxide it gives sodium zincate and hydrogen gas.

How Do Metals and Non-metals ReactMetals lose valence electron(s) and form cations.

Non-metals gain those electrons in their valence shell and form anions.

The cation and the anion are attracted to each other by strong electrostatic force, thus forming an ionic bond.

For example: In Calcium chloride, the ionic bond is formed by oppositely charged calcium and chloride ions.

Calcium atom loses 2 electrons and attains the electronic configuration of the nearest noble gas (Ar). By doing so, it gains a net charge of +2.

The two Chlorine atoms take one electron each, thus gaining a charge of -1 (each) and attain the electronic configuration of the nearest noble gas (Ar).

Ionic CompoundsIonic compounds are chemical compounds in which oppositely charged ions are held together by electrostatic forces called ionic bonds. An ionic compound always contains an equal magnitude of positive and negative charges. For example: CaCl2, NaCl, K2SO4, etc

Properties of Ionic CompoundsAre usually crystalline solids (made of ions). Have high melting and boiling points. Conduct electricity when in aqueous solution or molten in water and when melted. Are mostly soluble in water and polar solvents.

Physical Properties of Ionic CompoundsIonic compounds are solids and are hard to break, due to the presence of the strong force of attraction between the positive and negative ions. They generally break into pieces when pressure is applied, hence are considered brittle.

Lattice Structure of Ionic CompoundsA lattice is a regular arrangement of particles, whether these are atoms, ions or molecules. Ionic solids usually exist in regular, well-defined crystal structures.

Electric Conduction of Ionic CompoundsIonic compounds conduct electricity in the molten or aqueous state when ions become free and act as charge carriers.

In solid form, ions are strongly held by electrostatic forces of attractions and not free to move; hence do not conduct electricity.

Melting and Boiling Points of Ionic CompoundsIn ionic compounds, the strong electrostatic forces between ions require a high amount of energy to break. Thus, the melting point and boiling point of an ionic compound are usually very high.

Solubility of Ionic CompoundIonic compounds are generally soluble in polar solvents such as water ,whereas the solubility tends to decrease in non-polar solvents such as chloroform, oil, etc.

Extraction of Metals and Non-MetalsApplications of Metals and Non-metalsZinc is used to protect the iron from rusting. Gold and silver are used for making jewellery. Oxygen is used by plants and animals. For the preparation of ammonia, nitric acid and fertilizers, nitrogen is used. For the purification of water, chlorine is used. Diamonds are used for cutting glass in different industries.

Occurrence of MetalsMost of the elements especially metals occur in nature in the combined state with other elements. All these compounds of metals are known as minerals. But out of them, only a few are viable sources of that metal. Such sources are called ores.

Au, Pt – exist in the native or free state.

RoastingRoasting:- Converts sulfide ores into metal oxides on heating strongly in the presence of excess air.

It also removes volatile impurities.

2ZnS(s)+3O2(g)+Heat→2ZnO(s)+2SO2(g)

CalcinationCalcination: Converts carbonate and hydrated ores into oxides on heating strongly in the presence of limited air. It also removes volatile impurities.

ZnCO3(s)+heat→ZnO(s)+CO2(g)

CaCO3(s)+heat→CaO(s)+CO2(g)

Extraction of Metals, Which Are Lower in the Reactivity SeriesThe metals like gold, silver, platinum, and copper are the least reactive and found in free state. Copper and silver are also found in the combined state as their sulphide or oxide ores. These metals usually occur as sulphide ores, which further undergo roasting.

Extraction of Metals, Which Are Mid-Way in the Reactivity SeriesThe metals such as Zn, Fe, Pb, etc are moderately reactive and usually present as oxides, sulphides or carbonates in nature. The carbonate and sulphide ores are subjected to calcination and roasting respectively, followed by reduction of metal oxides to obtain the metals.

Extraction of Metals, Which Are on the Top of the Reactivity SeriesNa, Ca, Mg, Al, etc., cannot be obtained by reducing with C due to high affinity for oxygen. These metals are obtained by electrolytic reduction or electrolysis of their oxides, hydroxides or chlorides in the molten state.

Enrichment of OresIt means removal of impurities or gangue from ore, through various physical and chemical processes. The technique used for a particular ore depends on the difference in the properties of the ore and the gangue.

Refining of MetalsRefining of metals – removing impurities or gangue from crude metal. It is the last step in metallurgy and is based on the difference between the properties of metal and the gangue.

Electrolytic RefiningThe process of purifying impure metal to obtain pure metal on the passage of electric current is called electrolytic refining. Metals like copper, zinc, nickel, silver, tin, gold etc., are refined electrolytically.Anode – impure or crude metalCathode – a thin strip of pure metalElectrolyte – aqueous solution of a metal salt From anode (oxidation) – metal ions are released into the solutionAt cathode (reduction) – equivalent amount of metal from solution is depositedImpurities deposit at the bottom of the anode.