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Chemical Equilibrium

Total questions: 10

Worksheet time: 5mins

Name
Class
Date
1.

Consider the reaction:

4NH3 (aq) + 7O2 (G) => 4NO2 (g) + 6H20 (L)

the equilibrium constant,Kc for the reaction should be written as?

a)

[NO2}4

[NH3]4[O2]7

b)

[NO2][H2O]

c)

[NO2]4[H2O]6

d)

[NO2]4[H2O]7

2.

When the system H2(g)+Br2(g) is in equilibrium at 550 K at 1.0 atm pressure,the value of the equilibrium constant,KP is 10.What is the value of KP at a pressure of 2.0 atm at the same temperature

a)

10

b)

20

c)

30

d)

40

3.

Which of the following equilibrium equation would be shifted toward the right when the pressure is raised at constant temperature

a)

PCl5 => PCl3 + Cl2

b)

O2 + 4F2 => F4 + 2F2O

c)

NH4HS => NH3 + H2S

d)

3Fe + 4H2O=> F3O4 + 4h2

4.

An equilibrium is represented by the following equation:

2SO2 + O2 = 2SO3 H=-yKj mol-1


Which of the following changes would effect the value of equilibrium constant,Kp and the proportion of sulfur trioxide present at equilibrium?

a)

Reducing the temperature

b)

Adding the catalyst

c)

Increasing the pressure

d)

Increasing the mass of oxygen

5.

Which statement describe a system at equilibrium?

a)

Kforward = Kreverse

b)

Amount of reactant and product are equal

c)

When the reactant used up,the reaction stop.

d)

The rate of forward reaction equal the rate of reverse reaction

6.

For the reaction

2SO3 => 2SO2 + O2

If the partial pressure of SO3 and SO2 at equilibrium are

1/4 P and 1/8 P,respectively,what is the value of Kp?

a)

1/64 P

b)

10/64 P2

c)

1/32 P

d)

1/8 P

7.

Hydrazine is produced from it elements as follow:

N2 + 2H2 => N2H4 H=+ve kjmol-1

a)

Addition of catalyst

b)

Decrease in the pressure of the system

c)

Increase in the temperature of the system

d)

Increase in the value of the reaction vessel

8.

Sodium hydrogen carbonates decomposes at 1000C according to equation below:

2NaHCO3 => Na2CO3 + H2O + CO2

If the value of Kp is 0.231,calculate he total gas pressure (atm) at equilibrium.

a)

0.691

b)

0,434

c)

0.431

d)

0.132

9.

At 250C,Kp=7.13 atm-1 for the reaction:

2NO2 => N2O4\

At equilibrium the partial pressure of NO2 in a container is 0.15 atm. Calculate the partial pressure of N2H4 in the mixture.

a)

0.16 atm

b)

1 atm

c)

0.99 atm

d)

0.69 atm

10.

Calculate the value of Kp and Kc for the above reaction at 25oC,given that the vapour pressure of water at 250C is 23.8 torr

H2O=>H2O

a)

2.33 X 10-3

b)

2.99 X 10-4

c)

1.23 X10-3

d)

1.28 X 10-3