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CHEMISTRY SK 026 PAPER 1 15/16

Total questions: 30

Worksheet time: 8hrs 30mins

Name
Class
Date
1.

The following factors influence the speed of reaction EXCEPT

a)

Particle size

b)

Catalyst

c)

Concentration of the products

d)

Temperature

2.

The enthalpy of solution of an ionic compound equal to

a)

Ionisation energy + Enthalpy of hydration

b)

Enthalpy of hydration - lattice energy

c)

Lattice energy - Enthalpy of hydration

d)

Lattice energy + enthalpy of hydration

3.

What mass of ethanol, C2H5OH must be burnt completely in oxygen in order to produce 82 kJ of heat?

Given ΔHoc = -1083 kJ mol-1.

a)

0.29 g

b)

0.57 g

c)

3.48 g

d)

6.96 g

4.

Which of the following is correct cell notation for the given cell at standard conditions?


2Au3+(aq) + 3Co(s) → 3Co2+(aq) + 2Au(s)

a)

Au(s) l Au3+(aq,1.0M) ll Co2+(aq, 1.0 M) l Co(s)

b)

Au3+(aq,1.0M) l Au(s) ll Co(s) l Co2+(aq, 1.0 M)

c)

Co(s) l Co2+(aq, 1.0 M) ll Au3+(aq,1.0M) l Au(s)

d)

Co2+(aq, 1.0 M) l Co(s) ll Au(s) l Au3+(aq,1.0M)

5.

Organic compounds ae classified into saturated and unsaturated compounds. Choose the CORRECT statement regarding the unsaturated organic compound.

a)

Open chain and cyclic hydrocarbon comprise only the σ bonds.

b)

Open chain or cyclic hydrocarbon comprise only the σ bonds.

c)

Open chain hydrocarbons comprise only the σ bonds.

d)

Open chain and cyclic hydrocarbons comprise only the σ bonds and at least one π bond.

6.

Which of the following neutral atoms has two covalent bonds and two lone pairs of electrons?

a)

carbon

b)

fluorine

c)

oxygen

d)

nitrogen

7.

All the following alkanes are named correctly EXCEPT

a)

3-ethyl-2,4-dimethylheptane

b)

4-ethyl-2,3-dimethylnonane

c)

5-ethyl-2-methylhexane

d)

3-ethyl-2-methyloctane

8.

Reaction of excess 2-methylbutane with bromine at 125oC gives FOUR monobromoalkane products. What is the major product for the reaction?

a)

CH3CH(CH3)CH2CH2Br

b)

BrCH2CH(CH3)CH2CH3

c)

CH3CH(CH3)CHBrCH3

d)

CH3CBr(CH3)CH2CH3

9.

What is the obeyed rule for the formation of the products when unsymmetrical alkenes reacted with hydrogen bromide in the presence of peroxide?

a)

Saytzeff's rule

b)

Anti-Saytzeff's rule

c)

Anti-Markovnikov's rule

d)

Markovnikov's rule

10.

Which of the following structural formula represent trans-2-methyl-3-hexene?

a)
b)
c)
d)
11.

2-methylpropene is reacted with hot,acidified solution of KMnO4. What is the product formed?

a)

(CH3)2CO + H2CO

b)

(CH3)2CO + CO + H2O

c)

(CH3)2CO + HCOOH

d)

(CH3)2CO + CO2 + H2O

12.

All the following statements about benzene are true EXCEPT

a)

Benzene is an aromatic hydrocarbon

b)

Benzene is an example of a planar organic molecule

c)

Benzene has localised pi electrons in these carbon-carbon double bonds which are arranged alternately with three single carbon-carbon bonds.

d)

The structure of benzene molecule can be represented by a resonance hybrid of two Kekule structures.

13.

Which of the following species is attacked by benzene in the electrophilic nitration reaction?

a)

NO2+

b)

H2NO+

c)

NO+

d)

H2NO3-

14.

Which of the following alkyl chlorides will undergo SN2 reaction?

a)

Chloromethylcyclopentane

b)

1-chloro-2-methylcyclopentane

c)

1-chloro-3-methylcyclopentane

d)

1-chloro-1-methylcyclopentane

15.

The alcohols below undergo dehydration upon heating with concentrated sulphuric acid in which the reaction mechanism involved carbocation rearrangement EXCEPT

a)

2-methyl-2-hexanol

b)

2-methyl-3-pentanol

c)

2-methyl-2-phenyl-1-propanol

d)

3,3-dimethyl-2-pentanol

16.

Compound E give positive results with iodoform test but does not react with Tollens' reagent. Compound E is

a)

CH3CH2COCH2CH3

b)

CH3CH2CH2COCH3

c)

CH3CHO

d)

CH3CH2CHO

17.

Why ethanoic acid is more acidic than ethanol?

a)

The presence of dimeric hydrogen bond in ethanoic acid

b)

pKa value of ethanoic acid is lower

c)

inductive effect contributed by carbonyl group in ethanoic acid.

d)

The formation of resonance stabilised ethanoate ion.

18.

What is the expected product for the reaction of butanoic acid with LiAlH4 followed by hydrolysis?

a)

CH3CH2CH2COOCH2CH2CH2CH3

b)

CH3CH2CH2CH2OH

c)

CH3CH2CH2CHO

d)

CH3CH2CH=CH2

19.

Choose the suitable reagent F in the conversion above:

a)

Br2, H2O

b)

H2, Pd

c)

Br2, NaOH

d)

LiAlH4, followed by H3O+

20.

What is the structure of lysine in a basic medium?

a)
b)
c)
d)
21.

Peptide bonds in dipeptide molecules consist of

a)

imide linkages

b)

amide linkages

c)

ester linkages

d)

anhydride linkages

22.

Ethene and polyethene have similar

a)

empirical formula

b)

molecular formula

c)

melting point

d)

relative molecular mass

23.

The components of a bomb calorimeter include

a)

water

b)

ignition wire

c)

strong steel container

24.

The following statements are true about an electrolytic cell EXCEPT

a)

The negative electrode is the anode

b)

It makes non-spontaneous reaction possible

c)

Electrical energy is converted into chemical energy

25.

Figure above the Maxwell-Boltzmann distribution of molecular energies at 100 K. Which of the area(s) represent(s) the number of reacted molecules to form product?

a)

I

b)

II

c)

III

26.

Which of the following molecule(s) is/are chiral?

a)

2-chlorobutane

b)

1-chlorohexane

c)

1,5-dichloropentane

27.

COmbustion of alkane in excess oxygen produces

a)

water

b)

carbon dioxide

c)

carbon monoxide

28.

Choose reaction(s) that obey(s) Markovnikov's rule.

a)
b)
c)
29.

Identify reagent G for the following reaction.

a)

SOCl2

b)

Cl2/H2O

c)

Cl2/hv

30.

Which of the following would produce an acid?

a)

Hydrolysis of a nitrile compound

b)

Oxidation of a primary alcohol

c)

Reaction of a Grignard reagent followed by hydrolysis