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MASTERCHEMPRO 4:HALOALKANES, HYDROXY, CARBONYL & CARBOXYLIC ACID

Total questions: 20

Worksheet time: 15mins

Name
Class
Date
1.

Which of the following is formed when 1-chloropropane reacts with ethanolic KOH

a)

1-propanol

b)

2-propanol

c)

propene

d)

propane

2.

What would you make if you reacted CH3CH2MgBr (Grignard reagent) with methanal?

a)

1-propanol

b)

1-butanol

c)

2-propanol

d)

2-butanol

3.

What is produced when propanone reacted with CH3CH2MgBr (Grignard reagent)?

a)

Primary alcohol

b)

Secondary alcohol

c)

Tertiary alcohol

d)

Quarternary alcohol

4.

Which of the following reagents will react with propanal?

I. Na2Cr2O7 / H+/ ∆

II. KCN / H+

III. NaBH4 in methanol

a)

I only

b)

I and II

c)

II and III

d)

I, II, and III

5.

Carbonyl compounds CANNOT be synthesized through

a)

ozonolysis of alkenes

b)

oxidation of 2° alcohol

c)

oxidation of 1° alcohol

d)

esterification

6.

The reaction of a carbonyl compound with H2O is this type of reaction...

a)

Electrophillic Addition

b)

Nucleophillic Substitution

c)

Elimination

d)

Nucleophillic Addition

7.

Which reagent is commonly used to convert carboxylic acids into acyl chlorides?

a)

HCl

b)

Cl2

c)

SOCl2

d)

CH3Cl

8.

2-butanol heated with acidified KMnO4 solution produced

a)

butanone

b)

butanoic acid

c)

butene

d)

butane

9.

2-propanol heated with conc. H2SO4 produced

a)

propanoic acid

b)

propene

c)

propane

d)

propanal

10.

2-methyl-1-propanol heated with acidified K2Cr2O7 solution produced

a)

alkene

b)

alcohol

c)

carboxylic acid

d)

ketone

11.

1-hexanol reacts with PCC/CH2Cl2 produced

a)

hexene

b)

hexanal

c)

hexanoic acid

d)

hexane

12.

Which of the following reaction is NOT shown by ketones?

a)

reaction with HCN

b)

reaction with 2,4-dinitrophenyl hydrazine

c)

reaction with NaHSO3

d)

reaction with Fehling's solution

13.

How do you produce a carboxylic acid?

a)

Reducing a secondary alcohol or ketone

b)

Oxidizing a primary alcohol or an aldehyde

c)

Reducing a primary alcohol or aldehyde

d)

Oxidizing a secondary alcohol or a ketone

14.

What happens when you add a strong base to a carboxylic acid?

a)

Carboxylic base

b)

Benzoic acid

c)

Carboxylic acid salt

d)

Strong acid

15.

Nitriles can be formed by reacting haloalkanes with......

a)

Amines

b)

Amides

c)

Sodium Cyanide or Potassium Cyanide

d)

Potassium Nitrile

16.

Compound T is an alcohol and optically active. Upon oxidation with acidified KMnO4 solution, a ketone, U is formed. Compound T is

a)

CH3CH2OH

b)

(CH3)2C(OH)CH3

c)

CH3CH(OH)CH2CH3

d)

CH3CH2CH(OH)CH2CH3

17.

Carbonyl compounds CANNOT be synthesized through

a)

ozonolysis of alkenes

b)

oxidation of 2° alcohol

c)

oxidation of 1° alcohol

d)

esterification

18.
Name the mechanism to form X
a)
Nucleophilic substitution
b)
Electrophilic addition
c)
Nucleophilic addition
d)
Electrophilic substitution
19.

cyclopentanol reacts with SOCl2 produced

a)

2-chlorocyclopentane

b)

chlorocyclopentanoic acid

c)

chlorocyclopentene

d)

chlorocyclopentane

20.

methanol reacts with PCl5 produced

a)

chloride

b)

chloro methane

c)

chlorox

d)

chlorine