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Upper 6th Big Fat Organic Quiz

Total questions: 44

Worksheet time: 42mins

Name
Class
Date
1.

The repeating unit of a polymer is shown.


Which monomer or pair of monomers could be used to make this polymer?

a)

ClOC(CH2)4NH2 only

b)

ClOC(CH2)4COCl only

c)

ClOC(CH2)4COCl and H2N(CH2)6NH2

d)

ClOC(CH2)6COCl and H2N(CH2)4NH2

2.

Z-Retinal, shown in the diagram, is a component in vitamin A.


Which of the double bonds, labelled A, B, C or D, is responsible for the letter Z in the name?

a)

A

b)

B

c)

C

d)

D

3.

Which compound is the strongest base?

a)

Ammonia

b)

Ammoniumm chloride

c)

Methylamine

d)

Phenylamine

4.

Which correctly represents an incomplete combustion of pentane?

a)

C5H12 + 8O2 ⟶ 5CO2 + 6H2O

b)

C5H12 + 8O2 ⟶ 4CO + CO2 + 6H2O

c)

C5H12 + 6O2 ⟶ 4CO + CO2 + 6H2O

d)

C5H12 + 5O2 ⟶ 4CO + CO2 + 4H2O + 2H2

5.

Which compound forms a racemic mixture when reacted with KCN followed by dilute acid?

a)

HCHO

b)

CH3CHO

c)

CH3COCH3

d)

(CH3CH2)2CO

6.

Which catalyst is used in the catalytic cracking of alkanes?

a)

Concentrated phosphoric acid

b)

Iron

c)

Nickel

d)

Zeolite

7.

Which of the following mechanisms does not occur in reactions of bromoethane?

a)

Electrophilic addition

b)

Elimination

c)

Nucleophilic substitution

d)

Radical substitution

8.

What is the total number of structural isomers with the molecular formula C2HBrClF3?

a)

2

b)

3

c)

4

d)

5

9.

What is the empirical formula of 4-hydroxypent-2-ene?

a)

C5H12O

b)

C5H10O

c)

CH2O

d)

C5H9OH

10.

How many peaks does this compound have in its 13C spectrum?

a)

5

b)

6

c)

7

d)

8

11.

Which compound does not show stereoisomerism?

a)

1,2-dichloropropene

b)

1,2-dichloropropane

c)

1,3-dichloropropene

d)

1,3-dichloropropane

12.

Which alcohol could not be produced by the reduction of an aldehyde or a ketone?

a)

2,2-dimethylpropan-1-ol

b)

2-methylbutan-2-ol

c)

3-methylbutan-2-ol

d)

pentan-3-ol

13.

Which compound forms a molecular ion with a different precise molecular mass from the other three?

a)

butanone

b)

butanone

c)

dimethylpropane

d)

methylpropanal

14.

How many structural isomers with the molecular formula C5H10O react with Tollens’ reagent?

a)

3

b)

4

c)

5

d)

6

15.

Which alcohol can be oxidised by acidified potassium dichromate(VI) but cannot be dehydrated by heating with concentrated sulfuric acid?

a)

2,3-dimethylbutan-2-ol

b)

2,2-dimethylpropan-1-ol

c)

2-methylpropan-2-ol

d)

pentan-3-ol

16.

Which compound has the fastest rate of reaction with potassium cyanide to form pentanenitrile?

a)

1-bromobutane

b)

1-chlorobutane

c)

1-fluorobutane

d)

1-iodobutane

17.

Which compound is a structural isomer of Z-but-2-ene?

a)

butane

b)

E-but-2-ene

c)

cyclobutane

d)

methylbut-2-ene

18.

Aqueous solutions of ammonia, ethylamine and phenylamine are prepared.

Each solution has the same concentration.


Which is the correct order for the pH values of these solutions?

a)

ammonia > ethylamine > phenylamine

b)

ammonia > phenylamine > ethylamine

c)

ethylamine > ammonia > phenylamine

d)

ethylamine > phenylamine > ammonia

19.

The nitration of benzene uses a nitrating mixture of concentrated nitric acid and concentrated sulfuric acid.


HNO3 + 2H2SO4 → NO2+ + H3O+ + 2HSO4–

Which statement is correct?

a)

HNO3 acts as a base.

b)

HNO3 acts as a catalyst.

c)

HNO3 acts as an electrophile

d)

HNO3 acts as a reducing agent.

20.

The structure of part of a polyester chain is shown.


Which statement correctly explains why plastics made from this polyester only soften at high temperatures?

a)

Hydrogen bonds and van der Waals’ forces exist between polyester chains.

b)

Permanent dipole-dipole forces and van der Waals’ forces exist between polyester chains.

c)

The carbon-carbon bonds in the chain are strong.

d)

The carbon-oxygen bonds in the chain are strong

21.

Which statement is correct about the fractional distillation of crude oil?

a)

A zeolite catalyst is used

b)

Each fraction contains a mixture of hydrocarbons

c)

Gaseous fractions are formed by breaking covalent bonds.

d)

The fractionating column is hottest at the top.

22.

How many peaks are there in the 13C NMR spectrum of 1,4-dimethylbenzene?

a)

8

b)

4

c)

3

d)

2

23.

Which statement is correct about both 2-methylbutan-1-ol and 2-methylbutan-2-ol?

a)

They can be formed by alkaline hydrolysis of esters.

b)

They can be oxidised by reaction with acidified potassium dichromate(VI).

c)

They can be formed by hydration of 2-methylbut-2-ene.

d)

They have four peaks in their 13C NMR spectra.

24.

Which statement is correct about the molecule shown?

a)

It reacts with HBr in an electrophilic substitution reaction.

b)

It reacts with NaBH4 in a nucleophilic addition-elimination reaction.

c)

It reacts with ethanolic KOH in an elimination reaction.

d)

It reacts with KCN in a nucleophilic substitution reaction.

25.

Which equation represents a termination step?

a)
b)
c)
d)
26.

Which can be both an empirical and molecular formula of a stable compound?

a)

CH2O

b)

P4O10

c)

NH2

d)

CH3

27.

How many structural isomers with an unbranched carbon chain have the molecular formula C4H8Br2?

a)

4

b)

5

c)

6

d)

7

28.

Which of the following is an example of an initiation step?

a)
b)
c)
d)
29.

Which species could act as a nucleophile?

a)

BH3

b)

NH4+

c)

PH3

d)

SiH4

30.

Which statement is correct about poly(chloroethene)?

a)

It has the empirical formula CHCl

b)

It decolourises bromine water.

c)

Its brittleness is reduced by plasticisers.

d)

Its polymer chain contains alternate single and double bonds.

31.

Whats the largest desert in the world?

a)

Sahara

b)

Namib

c)

Gobi

d)

Sonoran

32.

In Star Wars how many Death star like objects have there been?

a)

1

b)

2

c)

3

d)

4

33.

What color is associated with Donald Trump

a)

Brown

b)

Orange

c)

Yellow

d)

Red

34.

What cartoon character is yellow with holes

a)

Spongepants

b)

You

c)

Spongebob

d)

Spongebob squarepants

35.

A baby ALLIGATOR is a...

a)

nymph

b)

hatchling

c)

juvenile

d)

neonate

36.

What is this strange animal of the sea?

a)

Floppy Face Fish

b)

Nugget Fish

c)

Blob Fish

d)

Strange Face Fish

37.

Elephants are

a)

the largest animals on land.

b)

the smallest animals on land.

c)

the largest animals in the ocean.

38.

How do elephants sleep?

a)

lying down

b)

standing

c)

walking

39.

Which ancient wonder does still exist?

a)

The Pyramid of Giza

b)

The Hanging Gardens of Babylon

c)

The Colossus of Rhodes

d)

The Temple of Artemis

40.

Where is this monument located?

a)

Washington

b)

North Dakota

c)

Wyoming

d)

South Dakota

41.

What is the name of this monument?

a)

The Colosseum

b)

The Aqueduct

c)

Leaning Tower of Pisa

d)

The Parthenon

42.

What is the name of this movie?

a)

Moana

b)

The sea

c)

My story

43.

Who is the main character in the movie Cars?

a)

Doc Hudson

b)

Sally

c)

Mate

d)

Lightning Mcqueen

44.

what is the name of this cat?

a)

Jessy

b)

Jess

c)

Lola

d)

Meg