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Energetics2

Total questions: 30

Worksheet time: 12mins

Name
Class
Date
1.

In which one of the following reactions is the standard enthalpy change equal to the standard enthalpy of formation of lithium fluoride?

a)

Li(g) + F(g) → LiF(s)

b)

Li+(g) + F−(g) → LiF(s)

c)

Li+(aq) + F−(g) → LiF(s)

d)

Li(s) + 0.5F2(g) → LiF(s)

2.

What is the temperature rise, in K, when 504 J of heat energy are absorbed by 0.110 kg of solid iron?


Specific heat capacity of iron = 0.448 J K−1 g−1

a)

9.78 × 10−2

b)

1.02 × 101

c)

2.83 × 102

d)

1.02 × 104

3.

The table shows the standard enthalpy of formation, ΔfHθ, for some of the substances in the reaction


C2H6(g) + 6F2(g) ⟶ C2F6(g) + 6HF(g) ΔHθ = −2898 kJ mol−1


What is the standard enthalpy of formation, in kJ mol−1, for HF(g)?

a)

−1638

b)

−273

c)

+273

d)

+1638

4.

Using the information given, answer this question.

Fe2O3(s) + 3H2(g) → 2Fe(s) + 3H2O(g)

ΔH⦵= +96 kJ mol−1, ΔS⦵ = +138 J K−1 mol−1


The standard enthalpy of formation of steam is

a)

+286 kJ mol−1

b)

+242 kJ mol−1

c)

−242 KJ mol−1

d)

−286 kJ mol−1

5.
Which has a highest specific heat?
a)
water 
b)
sand
c)
concrete
d)
glass
6.
For the formula:
 Q= m c ∆T
The  units for specific heat are:
a)
g /J C
b)
°C/g J
c)
kJ/g
d)
J/g°C
7.

Copper, Stainless Steel, Carbon Steel, and Zinc were all heated using 10,000 JOULES of thermal energy. Based on the chart, which material would have the SMALLEST change in temperature?

a)

Copper

b)

Carbon Steel

c)

Zinc

d)

Stainless Steel

8.

In the lab, you mix two solutions (each originally at the same temperature) and the temperature of the resulting solution decreases. What is true?

a)

This chemical reaction is releasing energy and is exothermic.

b)

This chemical reaction is absorbing energy and is exothermic.

c)

This chemical reaction is releasing energy and is endothermic.

d)

This chemical reaction is absorbing energy and is endothermic.

e)

None of these are true.

9.

The standard enthalpy changes of formation of iron(II) oxide, FeO(s), and aluminium oxide, Al2O3(s), are –266 kJ mol–1 and –1676 kJ mol–1 respectively.

What is the enthalpy change under standard conditions for the following reaction?

3FeO(s) + 2Al (s) → 3Fe(s) + Al2O3(s)

a)

+878kJ

b)

–878kJ

c)

–1942kJ

d)

–2474kJ

10.

The enthalpies of combustion of C(s), H2(g) and C4H9OH(l) (in kJmol-1) are as follows

C(s) + O2(g) → CO2(g) ∆H=a

H2(g) + ½O2(g) → H2O(l) ∆H=b

C4H9OH(l) + 6O2(g) → 4CO2(g) + 5H2O(l) ∆H=c

What is the enthalpy change for the reaction shown below?

4C(s) + 5H2(l) + ½O2(g) -> C4H9OH(l)

a)

c – 4a – 5b

b)

2a + 10b - c

c)

4a + 5b - c

d)

2a + 5b + c

11.
Use the chart to answer the following question.
Which is correct about energy changes during bond breaking and bond formation? 
a)
A
b)
B
c)
C
d)
D
12.
C2H4(g) + H2(g)   ->   C2H6(g)  ∆H°=-137 kJ mol-1
Which statement about this information is correct?
a)
The total energy of the bonds broken in the reactants is greater 
than the total energy of the bonds 
formed in the product 
b)
The bonds broken and the bonds made are of the same strength 
c)
The total energy of the bonds broken in the reactants is less than the total energy of the bonds formed in the product 
d)
No conclusion can be made about the sums of the bond enthalpies in the product compared with the reactants 
13.

Enthalpy (H)

a)

The heat content of a system at constant pressure.

b)

A chemical equation that includes the amount of heat released or absorbed during the reaction.

c)

The heat released or absorbed during a chemical reaction.

d)

The heat released after burning 1 mole of a substance.

14.

Which equation represents the standard enthalpy of atomisation?(HL)

a)

1/8 S 8 (s) -> S (g)

b)

Na (s) -> Na (l)

c)

Cl2 (g) -> 2Cl (g)

d)

CH4 (g) -> C (g) + 2H2 (g)

15.

Which of the following equation shows ∆Hθsolution ?(HL)

a)

Na+ (g) → Na+ (aq)

b)

NH3 (g) → NH3 (aq)

c)

NaOH (aq) → Na+ (aq) + OH- (aq)

d)

NaCl (s) → Na+ (aq) + Cl- (aq)

16.

Which of the following equation shows lattice energy ?(HL)

a)

Na+ (g) → Na+ (s)

b)

2Na+ (g) + O2- (g) → Na2O (s)

c)

Na+ (g) + OH- (g) → NaOH (aq)

d)

NaCl (s) → Na+ (g) + Cl- (g)

17.

Which of the following represents ∆Hθatom of CH3CH2CH3?

a)

8 B.E. (C-H) + 3 B.E (C-C)

b)

8 B.E. (C-H) + 2 B.E (C-C)

c)

– 8 B.E. (C-H) – 3 B.E (C-C)

d)

– 8 B.E. (C-H) – 2 B.E (C-C)

18.

Calculate the enthalpy change represented by X(HL)

a)

+695kJ/mol

b)

-695kJ/mol

c)

-635kJ/mol

d)

-635kJ/mol

19.

which of the following results in decrease in enthropy(HL)

a)
b)
c)
d)
20.

For a chemical reaction to be feasible, the total entropy change must be zero. (∆Ssystem + ∆Ssurroundings = 0)(HL)

a)

True

b)

False

21.

Which represents a -ΔS?(HL)

a)

ice melting

b)

salt dissolving

c)

water heating up

d)

none of these

22.

Spontaneous reactions are driven by(HL)

a)

increasing enthalpy and increasing entropy.

b)

decreasing enthalpy and decreasing entropy.

c)

increasing enthalpy and decreasing entropy.

d)

decreasing enthalpy and increasing entropy.

23.

The reaction

A + 2 B2 + C --> CAB4

has an enthalpy change of -104 kJ and a change in entropy of -60.8 J/K at 30 °C. What is the free energy and spontaneity of the reaction? (HL)

a)

-85.6 kJ, spontaneous

b)

-18.3 kJ, not spontaneous

c)

+18.3 kJ, spontaneous

d)

+85.6 kJ, not spontaneous

24.

What are standard conditions for energy change?

a)

Pressure of 100 kPa and temperature of 298 K

b)

All solutions are 1 mol/dm3

c)

All substances are in the solid state

d)

All substances are in the gaseous state

25.

Diagram below shows(HL)

a)

Standard lattice enthalpy

b)

Standard enthalpy of precipitation

c)

Standard enthalpy of formation

d)

Standard enthalpy of hydration

26.

Identify the enthalpy change represented by letter f.(HL)

a)

enthalpy of formation

b)

enthalpy of lattice formation

c)

electro affinity of bromine

d)

enthalpy of atomization of zinc

27.
Consider the following energy profile diagram for a reaction represented by the equation X+Y→Z
Which one of the following provides the correct values of the activation energy (in kJ mol-1) and the ΔH (in kJ mol-1) for the reaction
a)
Activation Energy = +75; ΔH = +100 
b)
Activation Energy = +100; ΔH = +175
c)
Activation Energy = +175; ΔH = +100
d)
Activation Energy = +200; ΔH = -125
28.

1. Calculate the standard entropy change for the following reaction(HL)

Cu(s) +1/2 O2(g) =>CUO (s)

Given that

a)

195.66 J/K.mol

b)

93.09 J/K.mol

c)

-93.09 J/K.mol

d)

+195.66 J/K.mol

29.
What is the relationship between enthalpies p, q, r and s?  
S(s) + H2(g)   ->  H2S(g)                                  
∆H=p 
H2(g) + ½O2(g)  ->  H2O(l)                            ∆H=q 
S(s) + O2(g)  ->  SO2(g)                                    ∆H=r 
H2S(g) + 1½O2(g)   -> H2O(l) + SO2(g)    ∆H=s
a)
p = q + r – s
b)
p = s – q – r
c)
p = q – r – s
d)
p = s + r – q
30.

Which statements about exothermic reactions are correct?

I. They have negative ΔH values.

II. The products have a lower enthalpy than the reactants.

III. The products are more energetically stable than the reactants.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III