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Equilibrium

Total questions: 40

Worksheet time: 38mins

Name
Class
Date
1.
What are the two factors to look for when determining if the reaction is at equilibrium?
a)
Forward reaction rate is faster than the reverse and concentrations are equal
b)
Forward and reverse reaction rates are equal and concentration is conctant
c)
Forward and revers reaction rates are equal and concentration is equal
d)
Forward reaction rate is faster than the reverse and concentration is equal
2.

Identify the incorrect statement about achieving equilibrium.

a)

achieved when product and reactant concentrations are equal

b)

achieved when forward and reverse reaction rates are same

c)

achieved when concentration of reactants is stable/constant

d)

achieved when concentration ratio of reactants to products becomes stable, thus fixing the equilibrium constant (equilibrium position)

3.
This symbol indicates that a reaction is ____________
a)
reversible
b)
irreversible
4.
How does a catalyst change during a reaction?
a)
It is part of the products
b)
It combines with the reactants
c)
It precipitates
d)
It remains unchanged
5.

2SO2(g)+O2(g) ⇌ 2SO3(g)

H = -450kJ

Adding SO2(g) will

a)

shift equilibrium right

b)

shift equilibrium left

c)

increase rate of reaction

d)

have no change

6.

2SO2(g)+O2(g) ⇌ 2SO3(g)

H = -450kJ

Increasing the temperature will...

a)

shift equilibrium right

b)

shift equilibrium left

c)

increase pressure

d)

have no change

7.

2SO2(g) + O2(g) ⇌ 2SO3(g)

H = -450kJ

Removing O2(g) will

a)

shift equilibrium right

b)

shift equilibrium left

c)

increase pressure

d)

have no change

8.

2SO2(g) + O2(g) ⇌ 2SO3(g)

H = -450kJ


Adding SO3(g) will

a)

shift equilibrium right

b)

shift equilibrium left

c)

increase K

d)

have no change

9.

2SO2(g) + O2(g) ⇌ 2SO3(g)

H = -450kJ


Increasing the volume of the container will...

a)

shift equilibrium right

b)

shift equilibrium left

c)

slow rate of reaction

d)

have no change

10.

2SO2(g)+1O2(g) ⇌ 2SO3(g) + Heat


Increasing the pressure on the system will...

a)

shift equilibrium right

b)

shift equilibrium left

c)

slow rate of reaction

d)

have no change

11.

2SO2(g) + O2(g) ⇌ 2SO3(g)

H = -450kJ


Using a catalyst

a)

shift equilibrium right

b)

shift equilibrium left

c)

have no change

12.

CoCI42- +6H2O →Co(H2O)62+ + 4CI-.


What would happen when H2O is added?

a)

Position of equilibrium will shift to left (and become more blue)

b)

Position of equilibrium will shift to right (and become more pink)

c)

Keq will increase as H2O is added

d)

Position of equilibrium will shift to left to reduce the added H2O

13.

1N2 + 3H2 →2NH3


When the pressure on the system is increased, the equilibrium position shifts to the right. Why?

a)

To increase the amount of products

b)

To reduce the pressure, as the right side has fewer molecules of gas

c)

Keq will increase when it is shifted to the right

d)

To increase the pressure, as the right side has more molecules of gas

14.

CoCI42- +6H2O →Co(H2O)62+ + 4CI-


What will happen when CI- ions are added?

a)

Position of equilibrium will shift to left and become more pink

b)

Color of system will turn to all pink

c)

Concentration of reactants and products remain unchanged

d)

Position of equilibrium will shift to left to reduce the added CI- ions

15.

2CrO42- + 2H+ → Cr2O72- + H2O


What will happen when H+ ions are added to the system?

a)

Position of equilibrium will shift to left and become more yellow

b)

Color of system will turn all yellow

c)

Color of system will turn all orange

d)

Equilibrium will shift to right and become more orange

16.

2CrO42- + 2H+→Cr2O72- + H2O


What will happen when OH- ions are added to the system? HINT: They remove the H+ ions.

a)

Position of equilibrium will shift to right and become more orange

b)

Position of equilibrium will shift to left and become more yellow

c)

Position of equilibrium will shift to right and become more yellow

d)

OH- ions will not react, and thus no change is seen.

17.

CoCI42- +6H2O →Co(H2O)62+ + 4CI- + Heat


What will happen when the temperature is increased?

a)

Position of equilibrium will shift to left and become more blue

b)

Position of equilibrium will shift to right and become more pink

c)

No change in position of equilibrium

d)

Position of equilibrium will shift to left and become more pink

18.

2SO2(g)+O2(g)⇌2SO3(g)

Removing O2(g) will

a)

shift equilibrium right

b)

shift equilibrium left

c)

increase pressure

d)

have no change

19.
2SO2(g)+O2(g)⇌2SO3(g)
Increasing volume of container will
a)
shift equilibrium right
b)
shift equilibrium left
c)
slow rate of reaction
d)
have no change
20.
2SO2(g)+O2(g)⇌2SO3(g)
Decreasing volume of container will
a)
shift equilibrium right
b)
shift equilibrium left
c)
change K
d)
have no change
21.

What happens to the equilibrium if we add methane (CH4)?

a)

It shifts left, towards the reactants

b)

It shifts right, towards the products

c)

It does not shift

22.

What happens to the equilibrium if we remove water (H2O)?

a)

It shifts left, towards the reactants

b)

It shifts right, towards the products

c)

It does not shift

23.

What happens to the equilibrium if we remove heat?

a)

It shifts left, towards the reactants

b)

It shifts right, towards the products

c)

It does not shift

24.

What happens to the equilibrium if we add hydrogen (H2)?

a)

It shifts left, towards the reactants

b)

It shifts right, towards the products

c)

It does not shift

25.

What happens to the equilibrium if we remove carbon monoxide (CO)?

a)

It shifts left, towards the reactants

b)

It shifts right, towards the products

c)

It does not shift

26.

What happens when sodium ions (Na+) are added?

a)

The reaction shifts left, towards the reactants

b)

The reaction shifts right, towards the products

c)

There is no shift

27.

What happens when fluoride ions (Na+) are removed?

a)

The reaction shifts left, towards the reactants

b)

The reaction shifts right, towards the products

c)

There is no shift

28.

What happens when the system is cooled (heat is removed)?

a)

The reaction shifts left, towards the reactants

b)

The reaction shifts right, towards the products

c)

There is no shift

29.

What happens when sodium fluoride (NaF) is added?

a)

The reaction shifts left, towards the reactants

b)

The reaction shifts right, towards the products

c)

There is no shift

30.

What happens when sulfur dioxide (SO2) is added?

a)

The reaction shifts left, towards the reactants

b)

The reaction shifts right, towards the products

c)

The reaction does not shift

31.
What is the Kc expression for this reaction?
   2 NO(g)  +  O2(g) ⇌  2 NO2(g)
a)
K= [NO2]2 / [NO][O2]
b)
K=  [NO][O2] / [NO2]2
c)
K= [NO][O2] [NO2]2
d)
K= [NO2]2 / [NO]2 +  [O2]
32.
What are [A] and [B]?
a)
concentration of reactants
b)
concentration of products
c)
energy of reactants
d)
energy of products
33.
The following reaction :    
SO2 (g) +  NO2 (g) 
<=> SO3 (g) + NO (g)  
had reached a state of equilibrium, was found to contain  
0.40 mol L-1 SO3 , and 0.30 
mol L-1 NO,
0.15 
mol L-1NO2 , and 0.20 mol L-1 SO2.
Calculate the equilibrium constant
 for this reaction. 
a)
4
b)
.42
c)
.25
d)
1
34.
What is the equilibrium expression for:
Fe3O4(s) + 4H2(g) <=> 3Fe(s) + 4H2O(g)
Kc =
a)
[Fe][H2O]4  / [Fe3O4] [H2]4
b)
[Fe3O4] [H2]/  [Fe][H2O]4
c)
[H2O]4 / [H2]4
d)
[Fe] [H2O] / [Fe3O4] [H2]
35.
If the equilibrium constant is much greater than one (K >> 1) then
a)
Equilibrium is not established.
b)
Equilibrium lies to the right (products are favored)
c)
Equilibrium lies to the left (reactants are favored)
d)
Neither products or reactants are favored.
36.
If the equilibrium constant is much less than one (K << 1) then
a)
Equilibrium is not established.
b)
Equilibrium lies to the right (products are favored)
c)
Equilibrium lies to the left (reactants are favored)
d)
Neither products or reactants are favored.
37.
N2O4(g) ↔ 2 NO2(g)
What is the concentration equilibrium constant expression?
a)
K= [NO2]2/[N2O4]
b)
K= [N2O4]/[NO2]2
c)
K= [N2O4]2/[NO2]
d)
K= [NO2]/[N2O4]2
38.
What is the equilibrium-constant expression for 
CO2(g) + H2(g) ↔ CO(g) + H2O(l)
a)
Kc= [CO][H2O] / [CO2][H2]  
b)
Kc= [CO2][H2] / [CO]
c)
Kc= [CO2][H2] / [CO][H2O]
d)
Kc= [CO] / [CO2][H2]  
39.
Find the Kc for
2NOBr(g) + Cl2(g) ↔ 2NO(g) + 2BrCl(g)
 if 
2NOBr(g) ↔ 2NO(g) + Br2(g)
has a K= 0.014
Br2(g) + Cl2(g) ↔ 2BrCl(g)
has a K= 7.2
a)
0.10
b)
10
c)
1.0 x 10-3
d)
1.0 x 10-2
40.
Consider the following reaction. What would be the equilibrium constant expression?
4Br2(g) + CH4(g) ↔  4HBr(g) + CBr4(g)
a)
[Br2]4  [CH4]/ [HBr]4  [CBr4]
b)
[HBr]4 [CBr4]/ [Br2]4 [CH4]
c)
[HBr ]/ [Br2]4 [CH4]
d)
[HBr]4 [CBr4]/ [Br2]4 [CH]4