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Chem Energetics definitions

Total questions: 13

Worksheet time: 6mins

Name
Class
Date
1.

Standard enthalpy change of combustion is defined as the enthalpy change when

a)

1 mole of compound is burnt in oxygen.

b)

1 mole of compound is completely burnt in oxygen under standard conditions of 298K and 1 bar.

c)

1 mole of compound is burnt under oxygen at 293K and 1 bar.

d)

1 mole of oxygen is used to burn a compound under standard conditions of 298K and 1 bar.

2.

Standard enthalpy change of neutralisation is defined as the enthalpy change when

a)

1 mole of acid reacts with 1 mole of alkali to form 1 mole of water, under standard conditions of 298K and 1 bar.

b)

1 mole of water is formed in the neutralisation between an acid and an alkali, under standard conditions of 298K and 1 bar.

c)

1 mole of water is formed in the neutralisation between an acid and an alkali, the reaction being carried out in aqueous solution under standard conditions of 298K and 1 bar.

d)

1 mole of acid is neutralised by an alkali to form a salt and water, under standard conditions of 298K and 1 bar.

3.

Bond energy (of dissociation) (BE) is defined as 

a)

the enthalpy change when 1 mole of covalent bonds is broken.

b)

the energy required to break 1 mole of a covalent bond between two atoms in the gaseous state.

c)

the energy required to break covalent bonds between atoms in the gaseous state to form 1 mole of gaseous atoms.

d)

the energy released when 1 mole of covalent bond between two atoms in the gaseous state is formed.

4.

Bond energy (of dissociation) (BE) is

a)

always positive (endothermic)

b)

always negative (exothermic)

c)

sometimes positive and sometimes negative

d)

double the value of  ΔH atomisation\Delta H\ atomisation  for gaseous diatomic molecules

e)

equal to the value of  \Delta H\ atomisation  for gaseous diatomic molecules

5.

Standard enthalpy change of formation of a substance is defined as

a)

the enthalpy change when 1 mole of the substance is formed from its elements under standard conditions of 298K and 1 bar.

b)

the energy released when 1 mole of the substance is formed from its elements under standard conditions of 298K and 1 bar.

c)

the enthalpy change when 1 mole of elements is used to form a substance under standard conditions of 298K and 1 bar.

d)

the energy released when 1 mole of elements is used to form a substance under standard conditions of 298K and 1 bar.

6.

Standard enthalpy change of hydration

a)

of a substance is defined as the enthalpy change when 1 mole of the substance is dissolved in a large amount of water under standard conditions of 298 K and 1 bar.

b)

of a substance is defined as the enthalpy change when 1 mole of the substance is fully dissolved in water under standard conditions of 298 K and 1 bar.

c)

of an ion is defined as the enthalpy change when 1 mole of ions is dissolved in a large amount of water such that addition of more water produces no further heat change under standard conditions of 298 K and 1 bar.

d)

of an ion is defined as the enthalpy change when 1 mole of gaseous ions is dissolved in a large amount of water such that addition of more water produces no further heat change under standard conditions of 298 K and 1 bar.

7.

Standard enthalpy change of solution is defined as

a)

the enthalpy change when 1 mole of a substance is dissolved in a large amount of solvent under standard conditions of 298 K and 1 bar.

b)

the enthalpy change when 1 mole of an ionic compound is fully dissolved in solvent under standard conditions of 298 K and 1 bar.

c)

the enthalpy change when 1 mole of substance is dissolved in a large amount of solvent such that addition of more solvent produces no further heat change under standard conditions of 298 K and 1 bar. (ie. further dilution has no effect)

d)

the enthalpy change when 1 mole of aqueous ions is formed from the dissolution in a large amount of water such that addition of more water produces no further heat change under standard conditions of 298 K and 1 bar.

8.

Lattice energy of an ionic solid is defined as

a)

the energy change when 1 mole of the ionic solid is formed from its separate ions.

b)

the heat energy evolved when 1 mole of the ionic solid is formed from its separate gaseous ions.

c)

the energy required to break 1 mole of ionic bonds to form separate ions.

d)

the heat energy required to break 1 mole of ionic bonds to form separate gaseous ions.

9.

Standard enthalpy of atomisation is defined as the enthalpy change when

a)

1 mole of atoms is formed in a reaction under standard conditions of 298 K and 1 bar.

b)

1 mole of separate gaseous atoms of the element is formed from the element under standard conditions of 298 K and 1 bar.

c)

1 mole of an element is atomised to form separate gaseous atoms under standard conditions of 298 K and 1 bar.

d)

1 mole of a compound is broken down into its individual atoms under standard conditions of 298 K and 1 bar.

10.

First ionisation energy (IE) is defined as 

a)

the energy change when 1 mole of electrons is removed from 1 mole of atoms to form 1 mole of gaseous cations.

b)

the energy required to remove 1 mole of electrons from 1 mole of atoms to form 1 mole of gaseous cations.

c)

the energy required to remove 1 mole of electrons from 1 mole of separate gaseous atoms to form 1 mole of gaseous cations.

d)

the energy released when 1 mole of electrons is removed from 1 mole of separate gaseous atoms to form 1 mole of gaseous cations.

11.

Second ionisation energy (IE) is defined as 

a)

the energy change when 2 moles of electrons is removed from 1 mole of atoms to form 1 mole of gaseous X2+ cations.

b)

the energy released when the 2nd mole of electrons is removed from 1 mole of  gaseous atoms to form 1 mole of gaseous X2+ cations.

c)

the energy change when 1 mole of electrons is removed from 1 mole of gaseous X+ cations to form 1 mole of gaseous X2+ cations.

d)

the energy required to remove 1 mole of electrons from 1 mole of gaseous X+ cations to form 1 mole of gaseous X2+ cations.

12.

Electron affinity (EA) of an element is defined as 

a)

the energy change when 1 mole of electrons is added to 1 mole of atoms to form 1 mole of anions.

b)

the energy change when 1 mole of electrons is added to 1 mole of gaseous atoms to form 1 mole of gaseous anions.

c)

the energy released when 1 mole of electrons is added to 1 mole of gaseous atoms to form 1 mole of gaseous anions.

d)

the energy required when 1 mole of electrons is added to 1 mole of gaseous atoms to form 1 mole of gaseous anions.

13.

Hess' Law states that

a)

the enthalpy change of a chemical reaction depends only on the initial and final states of the system.

b)

the enthalpy change of a chemical reaction is independent of the reaction pathway taken. 

c)

the enthalpy change of a chemical reaction depends only on the initial and final states of the system, and is independent of the reaction pathway taken. 

d)

the enthalpy change of a chemical reaction via a direct route is equal to the enthalpy change via an indirect route.

e)

sum of clockwise arrows = sum of anticlockwise arrows