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Aldehydes,Ketones and Carboxylic acids

Total questions: 21

Worksheet time: 14mins

Name
Class
Date
1.

Which is a test for a C=O?

a)

Bromine water

b)

Fehling's solution

c)

Acidified potassium dichromate (VI)

d)

2,4-DNPH (Brady's reagent)

2.

Which of the following tests would give a positive result for propan-1-ol?

a)

The iodoform test (NaOH + I2)

b)

Tollen's reagent (silver mirror test)

c)

PCl5 (phosphorus pentachloride)

d)

2,4-DNPH (Brady's reagent)

3.

Name this molecule:

a)

Propanone

b)

Propanal

c)

Butanone

d)

Butanal

4.

Name this molecule and give its functional group.

a)

Carboxylic acid - propanoic acid

b)

Ester - methyl ethanoate

c)

Ester - ethyl methanoate

d)

Carboxylic acid - methyl ethanoic acid

5.

What will be formed if butanone is reacted with LiAlH4 in dry ether?

a)

Butanoic acid

b)

Butan-1-ol

c)

Butan-2-ol

d)

Butanal

6.

What is the name of the mechanism when KCN (in acidic conditions) reacts with propanal?

a)

Free radical substitution

b)

Nucleophilic substitution

c)

Nucleophilic addition

d)

Electrophilic addition

7.

Name this molecule:

a)

Pentanoic acid

b)

2-hydroxy-2-methylbutan3-one

c)

3-hydroxy-3-methylbutane-2-one

d)

2-oxo-3-methylbutan-3-ol

8.

Which of the following reagents will oxidise propan-1-ol to propanal (tick all that apply)?

a)

Acidified potassium dichromate (VI)

b)

2,4-DNPH (Brady's reagent)

c)

Fehling's solution

d)

PCl5 (phosphorus pentachloride)

9.
What observations would you expect to see in a positive Fehlings test for an aldehyde?
a)
blue solution to brick-red solution
b)
blue solid to brick-red solution
c)
blue solution to brick-red solid
d)
blue solid to brick-red solid
10.
Which of these compounds does not react with Brady's reagent?
a)
propanoic acid
b)
propanal
c)
propanol
d)
propanone
11.
What is the chemical name for Brady's reagent?
a)
2,4-dinitrophenyhydrazone
b)
2,4-diphenylhydrazine
c)
2,4-dinitrophenyhydrazine
d)
2,4-dinitrophenolhydrazine
12.
What is the correct formula of the reducing agent used to reduce aldehydes and ketones?
a)
LiAlH4
b)
LiAlH2
c)
Li2AlH4
d)
LiAlH
13.
Aldehyde reacts with Tollen's reagent forming:
a)
Yellow precipitate
b)
Brick-red precipitate
c)
Purple solution
d)
Silver mirror
14.
1. Iodoform test: Pale yellow ppt
2. Fehling's test: No observable change
3. 2,4-DNPH: yellow ppt
Which compound will have the above observations?
a)
CH3CH2CHO
b)
C6H5CHO
c)
CH3CH2COCH3
d)
CH3COOH
15.
HVZ reaction involves
a)
reduction reaction of carboxylic group
b)
cleavage of O − H bond of carboxylic acid
c)
cleavage of C − OH bond of carboxylic acid
d)
substitution reaction in hydrocarbon part of carboxylic acid
16.

What is the difference between aldehyde and ketones?

a)

position of C=O group

b)

position of C atoms

c)

the number of bonds carbon can form

d)

the number of oxygen atoms

17.

If propanal reacts with KCN in acidic conditions, which of the following is true?

a)

The product is not chiral

b)

A racemic mixture of the R and S enantiomers is formed

c)

Only the R enantiomer forms

d)

Only the S enantiomer forms

18.

Which of the following is the most acidic?

a)
b)
c)

CH3CH2OH

d)

(CF3)2CHOH

19.

Which of the following is the most acidic?

a)
b)
c)
d)
20.

What will be formed if butanone is reacted with LiAlH4 in dry ether?

a)

Butanoic acid

b)

Butan-1-ol

c)

Butan-2-ol

d)

Butanal

21.

Which of the following species can attack the carbon atom in the carbonyl group, C=O?

a)

Br2

b)

Cl

c)

CN-

d)

NO2+