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WorksheetsMICROWAVE SPECTROSCOPY
Total questions: 20
Worksheet time: 4mins
CONDITION FOR THE MOLECULE TO BE MICROWAVE ACTIVE
CHANGE IN DIPOLEMOMENT
CHANGE IN POLARSIBILITY
PERMANENT DIPOLE MOMENT
ALL
Which of the following type of electromagnetic radiation has the most energy
infrared
ultraviolet
microwaves
radiowaves
Which of the following molecules show microwave activity?
H2
CO2
SF6
CH3Cl
The rotational energy of a diatomic molecule in terms of wave number is
EJ = 8π2IChJ(J+1)
EJ = 8π2ICh2J(J+1)
EJ =8π2Ih2 J(J+2)
The wave number difference between successive rotational levels of a rigid diatomic molecule is
2B J
BJ(J+1)
2BJ(J+1)
2BJ(J-1)
The various energy level of a rotational spectrum is given by
2B,6B,12B,_ _ _
2B,4B,6B,8B,….
0,2B,6B,12B,_ _ _
0,2B,4B,6B,8B,….
The different types of energies associated with a molecule are __________
Vibrational energy
electronic energy
Rotational energy
All of these
Molecules which are having _______ are microwave active.
Dipole moment
High pressure Detector
Principle axis
Acidity
The correct order of different types of energies is __________
Eel >> Evib >> Erot
Eel >> Erot >> Evib
Evib >> Eel >> E rot
None of these
The arrangement of various type of Electromagnetic radiation in the order of their
wavelength,frequency
Energy,velocity
Speed,Rate
None
Joules can be converted to cm-1
Multiply by h
Multiply by hc
Divide by h
Divide by hc
Rotational spectrum is useful to determine the
(a)
Intensity of spectral lines depends on
energy of the energy level
population of the energy level
J value
B Value
Plot of NJ/N0against J gives
Boltzmann curve
Gaussian curve
Parabola curve
Morse curve
The molecule which is microwave active
H2
O2
HCl
co2
The wavelength range of rotational spectrum is
10-2 to 10cm
1 to 10cm
10 to 100 cm
1 to 1000cm
As J value increases, the energy of the energy level
Increases
Decreases
Remains same
Remains constant
Selection rule of rotational spectrum
,Dn=±1
DS=0
,DJ=±1
,DJ=0
The rotational spectrum consits of a series of lines at
2B
B
4B
6B
Bond length can be determined using
Moment of inertia
Energy
Angular momentum
Plancks constant
