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Nucleophilic Substitution at Saturated Carbon - Quiz 1

Total questions: 20

Worksheet time: 10mins

Name
Class
Date
1.

Electrophile is a reagent which can

a)

a) Donate an electron pair in reaction

b)

b) Accept an electron pair in reaction

c)

c) Neither accept nor donate electron pair

d)

d) Both a and b

2.

Nucleophile is a reagent.....

a)

Which can accept electron pair in reaction

b)

Which can act as a Lewis base

c)

Which is nucleus loving species

d)

All of above

3.

In SN2 reaction bond fission is…

a)

Homolytic

b)

Heterolytic

c)

Both a and b

d)

None of these

4.

Which of the following are nucleophiles?

a)

AlCl3 ,BF3

b)

H2O ,NH3

c)

R3C+, NO2+

d)

All of these

5.

5) In SN2 mechanism

a)

a) Nucleophile attacks substrate in fast step

b)

b) Attack of nucleophile is from back side

c)

c) Leaving group departs and then nucleophile attacks

d)

d) There are two steps involved

6.

In SN2 reaction, product is obtained with ……..of configuration.

a)

a) Retention

b)

b) Inversion

c)

c) Racemization

d)

d) Both a and b

7.

7) In nucleophilic substitution reaction which type of bond is in the substrate.

a)

Non polar bond

b)

Polar bond

c)

Both Polar and Nonpolar

d)

None of these

8.

The reaction between methyl bromide and hydroxide ion is example of...

a)

SN2 Reaction

b)

SN1 Reaction

c)

Both SN2 and SN1

d)

SNi Reaction

9.

SN2 reaction is...

a)

Unimolecular reaction

b)

Bimolecular Reaction

c)

Unimolecular and Bimolecular

d)

None of these

10.

SN2 reaction follows...

a)

First order kinetics

b)

Second order kinetic

c)

Third order kinetic

d)

Forth order kinetics

11.

SN2 reaction occurs in...

a)

One step

b)

Two steps

c)

Three steps

d)

None of these

12.

The geometry of the Transition state...

a)

Trigonal Planner

b)

Trigonal Pyramidal

c)

Trigonal Bipyramidal

d)

Tetrahedral

13.

In SN2 Reaction

a)

bond breaking and bond formation takes place in two different steps

b)

bond breaking and bond formation takes place in only one step

c)

Both a and b

d)

None of these

14.

In SN2 reaction the slow step is...

a)

Formation of bond

b)

Braking of bond

c)

Both bond formation and bond breaking is slow step

d)

None of these

15.

In SN2 reaction the attack of Nucleophile is from Backside due to

a)

Steric repulsion

b)

Electrostatic repulsion

c)

Both steric and electrostatic repulsion

d)

None of these

16.

SN2 reaction is ..

a)

Stereospecific

b)

Stereoselective

c)

Both Stereospecific and Stereoselective

d)

None of these

17.

hydroxide is a good leaving group

a)

Yes

b)

No

18.

R- 1-phenyl-2-propanol and S- 1-phenyl-2-propanol are enantiomers of each other

a)

True

b)

False

19.

In SN2 reaction, Optically active compound gives optically active product.

a)

True

b)

False

20.

Carbon atom bearing four different groups is known as

a)

Chiral Carbon atom

b)

Asymmetric Carbon atom

c)

Stereocenter

d)

All of the above