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Worksheets

Carboxylic acids

Total questions: 30

Worksheet time: 18mins

Name
Class
Date
1.

The products of the reaction of a carboxylic acid and an alcohol would be

a)

Ketone and water

b)

Amide and water

c)

Acid chloride and water

d)

Ester and water

2.

Which is the correct IUPAC name of the following compound?

a)

A. 2-hydroxybutanoic acid

b)

B. 3-hydroxybutanoic acid

c)

C. 2-hydroxypropanoic acid

d)

D. 1-carboxypropan-2-ol

3.

Give the name for the below structure based on IUPAC nomenclature.

a)

A 2-methyl-4-butanoic acid

b)

B 2-methyl-4-pentanoic acid

c)

C 3-methylbutanoic acid

d)

D 3-methylpentanoic acid

4.

Which carboxylic acid is most acidic?

a)

CH3CH2CH2COOH

b)

CH3CH2CH(Cl)COOH

c)

CH3CH(Cl)CH2COOH

d)

ClCH2CH2CH2COOH

5.

Reaction of a carboxylic acid and a primary amine will produce:

a)

a substituted ammonium salt if heat is added

b)

a secondary amine

c)

a tertiary amine

d)

an amide if heat is added

6.

In the below sequence of reactions, A and B are which of the following?

a)

(CH3)2C(OH)CN, (CH3)2C(OH)COOH

b)

(CH3)2C(OH)CN, (CH3)2C(OH)2

c)

(CH3)2C(OH)CN, (CH3)2CHCOOH

d)

(CH3)2C(OH)CN, (CH3)2C=O

7.

Which of the following compounds known as m-nitrobenzoic acid?

a)
b)
c)
d)
8.

Which of the following carboxylic acids is expected to have the highest boiling point?

a)

CH3CH2COOH

b)

CH3CH(OH)COOH

c)

CH2(COOH)2

d)

CH3CH(Cl)COOH

9.

Which alkyl benzene cannot be oxidised by KMnO4 to produce carboxylic acid?

a)

Toluene

b)

2-iodotoluene

c)

benzene

d)

ethylbenzene

10.

Name this molecule:

a)

Pentanoic acid

b)

2-hydroxy-2-methylbutan3-one

c)

3-hydroxy-3-methylbutane-2-one

d)

2-oxo-3-methylbutan-3-ol

11.

Which of the following reagents will oxidise propan-1-ol to propanal (tick all that apply)?

a)

Acidified potassium dichromate (VI)

b)

2,4-DNPH (Brady's reagent)

c)

Fehling's solution

d)

PCl5 (phosphorus pentachloride)

12.
Which carboxylic acid and which alcohol came together to form the ester pictured here?
a)
Propanol and heptanoic acid
b)
Heptanol and propanoic acid
13.
Predict the product of the following reaction
a)
A
b)
B
c)
C
d)
D
14.

Choose the best reagent in the missing box for carrying out the following reaction

a)

PCC, CH2Cl2

b)

CH3MgBr in ether, then H3O+

c)

m-ClC6H4CO3H

d)

warm H2SO4/H2O

e)

NaOCH3, CH3OH

15.

What is the name of this ester?

a)

Methyl Propanoate

b)

Methyl Methanoate

c)

Ethyl Ethanoate

d)

Methyl Ethanoate

16.

What is the correct IUPAC name for the Carboxylic Acid shown?

a)

1,1,1-trimethylbutanoic acid

b)

1,1,1-trimethylpentanoic acid

c)

4,4-dimethylbutanoic acid

d)

4,4-dimethylpentanoic acid

17.

Ethanol reacts with ethanoic acid to form ethyl ethanoate.

C2H5OH + CH3COOH → CH3COOC2H5 + H2O

What is the formula of the ester formed when methanol reacts with butanoic acid, (C3H7COOH)?

a)

C2H5COOC2H5

b)

C3H7COOC2H5

c)

C3H7COOCH3

d)

CH3COOC3H7

18.

The correct order of acidic strength of carboxylic acids is

a)

Formic acid < benzoic acid < acetic acid

b)

Formic acid < acetic acid < benzoic acid

c)

Acetic acid < Formic acid < benzoic acid

d)

Acetic acid < benzoic acid < Formic acid

19.

What does miscible means?

a)

Can form hydrogen bonds with water.

b)

Mix with water in any proportion.

c)

Soluble in water and organic solvents.

d)

Dissolve in water to form hydrogen ions.

20.

Carboxylic acids are acids because... (select all correct answers)

a)

They will turn blue litmus paper red

b)

They will accept protons from water, forming OH-

c)

They will donate protons to water, forming H3O+

d)

React with equation R-COOH + H2O --> R-COO- + H3O+

21.

To prepare an acid chloride from a carboxylic acid, which are suitable reagents? (select all correct answers)

a)

ZnCl2

b)

PCl5

c)

SOCl2

d)

Cl2(aq)

22.

Which of the following reactions with an acid chloride is a substitution reaction?

a)

Acid chloride + water --> carboxylic acid + hydrochloric acid

b)

Acid chloride + ammonia --> amide

c)

Acid chloride + primary amine --> secondary amide + HCl

d)

Acid Chloride + alcohol --> Ester + HCl

23.

Which of the following reactions with an acid chloride is not a condensation reaction?

a)

Acid chloride + water --> carboxylic acid + HCl

b)

Acid chloride + ammonia --> 1o amide + HCl

c)

Acid chloride + primary amine --> secondary amide + HCl

d)

Acid Chloride + alcohol --> Ester + HCl

24.

1-hexanol reacts with PCC/CH2Cl2 produced

a)

hexene

b)

hexanoic acid

c)

hexanal

d)

hexane

25.

In the reaction, which answer represents the product X?

a)
b)
c)
d)
26.

What are esters used for (chose two)

a)

Perfumes

b)

Fuels

c)

Flavourings

d)

Oxidising agent

27.

Which reaction is not an electrophilic addition ?

a)

A

b)

B

c)

C

d)

D

28.

A reaction between chlorine and propane in UV light produces 2 isomeric monochloropropanes, C3H7Cl, as products. Which information about this reaction is correct ?

a)

A

b)

B

c)

C

d)

D

29.

The starting material A in this reaction sequence is called _____.

a)

a β-keto ester

b)

an α-carboethoxy ketone

c)

a malonic ester

d)

an acetoacetic ester

30.

Compound X, diethyl propanedioate, is more commonly known as _____.

a)

ethyl acetoacetate

b)

acetoacetic ester

c)

oxalic ester

d)

malonic ester