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Solubility Equilibrium_2

Total questions: 15

Worksheet time: 15mins

Name
Class
Date
1.

Which of the following statements is held true about the common-ion effect on the equilibrium of solubility of salt ?

(you may choose more than one answer)

a)

Adding common-ion to the solution containing dissolved salt cause the solubility equilibrium shifts to the formation of undissolved salt

b)

Adding common-ion to the solution containing dissolved salt cause the numerical value of Ksp of corresponding salt changes

c)

Solubility of salt in solution containing common-ion is greater than that of pure water.

2.

Consider a beaker containing 100 ml of water, with solid AgCl on the bottom.


Which of the following statements is held true if NaCl is added to the solution?


(you may choose more than one answer)

a)

The amount of AgCl solid at the bottom of the beaker increases

b)

The amount of AgCl solid at the bottom of the beaker decreases

c)

The concentration of dissolved Ag+ ion in the solution stays the same

d)

The concentration of dissolved Ag+ ion in the solution changes

3.

Which of the following effect increase the solubility of Ca(OH)2 ?


Ca(OH)2(s) ↔ Ca2+(aq) + 2OH-(aq)


(you may choose more than one answer)

a)

Adding solid NaOH

b)

Adding an acid solution

c)

The pH of solution is adjusted to be below 7

d)

Adding solid CaCl2

4.
An unknown salt, M2Z, has a Ksp of 3.3 x 10-9. Calculate the solubility in mol/L of M2Z.
a)
2.9 x 10-5 M
b)
5.7 x 10-5 M
c)
9.4 x 10-5 M
d)
3.7 x 10-5 M
5.

What will happen if some solid AgNO3 is added to a saturated solution of AgCl ?

a)

The AgNO3 will not dissolve

b)

More solid AgCl will dissolve

c)

More solid AgCl will produced

d)

There will be no effect on AgCl equilibrium

6.

Which of the following effect increase the solubility of Ca(OH)2 ?


Ca(OH)2(s) ↔ Ca2+(aq) + 2OH-(aq)


(you may choose more than one answer)

a)

Adding solid NaOH

b)

Adding an acid solution

c)

Adding solid CaCl2

7.

The Ksp expression for a saturated solution of Ca3(PO4)2 is

a)

Ksp = [Ca2+][PO43-]

b)

Ksp = [3Ca2+][2PO43-]

c)

Ksp = [Ca2+]3[PO43-]2

d)

Ksp = [3Ca2+]3[2PO43-]2

8.

What will happen if some solid AgNO3 is added to a saturated solution of AgCl ?

a)

The AgNO3 will not dissolve

b)

More solid AgCl will dissolve

c)

More solid AgCl will produced

d)

There will be no effect on AgCl equilibrium

9.

How could you change a saturated solution to an unsaturated solution?

a)

Add solvent

b)

Add solute

10.

The solubility of HgS is 5.5 x 10-27 mol/L. What is Ksp for HgS?

a)

4.0 x 10-3

b)

8.2 x 10-4

c)

1.3 x 10-13

d)

3.0 x 10-53

11.

For BaSO4, Ksp = 1.1 x 10-10. If you mix 200. mL of 1.0 x 10-4 M Ba(NO3)2 and 500. mL of 8.0 x 10-2 M H2SO4, what will be observed?

a)

A precipitate forms because Qsp > Ksp

b)

A precipitate forms because Qsp < Ksp

c)

No precipitate forms because Qsp < Ksp

d)

No precipitate forms because Qsp > Ksp

12.
If K < Q, which part of the reaction will speed up?
a)
forward
b)
reverse
c)
none
13.
A weak acid, HF, is in solution with dissolved sodium fluoride, NaF. If HCl is added, which ion will react with the extra hydrogen ions from the HCl to keep the pH from changing?
a)
OH-
b)
Na+
c)
F-
d)
Na-
14.

Which one of the following is the solubility product constant for Mn(OH)2?

a)

Ksp = [Mn2+][OH-]2

b)

Ksp = [Mn2+][2 OH-]2

c)

Ksp = [Mn2+]2[OH-]2

d)

Ksp = [Mn2+]2[OH-]

15.

A saturated solution of Ca(OH)2, has a pH of 12.40. What is the Ksp for Ca(OH)2?

a)

2.5 x 10-2

b)

1.3 x 10-2

c)

8.0 x 10-6

d)

2.0 x 10-6