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9.0 REACTION KINETICS

Total questions: 10

Worksheet time: 7mins

Name
Class
Date
1.

Which of the following is a unit of rate of reaction?

a)

s-1

b)

Ms-1

c)

M

d)

M-1s-1

2.

For the reaction below, which of the following is the correct differential rate equation?


NH3(g) + O2(g) → NO(g) + H2O(g)

a)

rate = −d[NH3]dt=−d[O2]dt=d[NO]dt=d[H2O]dtrate\ =\ -\frac{\text{d}\left[NH_3\right]}{\text{d}t}=-\frac{\text{d}\left[O_2\right]}{\text{d}t}=\frac{\text{d}\left[NO\right]}{\text{d}t}=\frac{\text{d}\left[H_2O\right]}{\text{d}t}

b)

rate = −12d[NH3]dt=−13d[O2]dt=14d[NO]dt=12d[H2O]dtrate\ =\ -\frac{1}{2}\frac{\text{d}\left[NH_3\right]}{\text{d}t}=-\frac{1}{3}\frac{\text{d}\left[O_2\right]}{\text{d}t}=\frac{1}{4}\frac{\text{d}\left[NO\right]}{\text{d}t}=\frac{1}{2}\frac{\text{d}\left[H_2O\right]}{\text{d}t}

c)

rate = d[NH3]dt=d[O2]dt=−d[NO]dt=−d[H2O]dtrate\ =\ \frac{\text{d}\left[NH_3\right]}{\text{d}t}=\frac{\text{d}\left[O_2\right]}{\text{d}t}=-\frac{\text{d}\left[NO\right]}{\text{d}t}=-\frac{\text{d}\left[H_2O\right]}{\text{d}t}

d)

rate = −14d[NH3]dt=−15d[O2]dt=14d[NO]dt=16d[H2O]dtrate\ =\ -\frac{1}{4}\frac{\text{d}\left[NH_3\right]}{\text{d}t}=-\frac{1}{5}\frac{\text{d}\left[O_2\right]}{\text{d}t}=\frac{1}{4}\frac{\text{d}\left[NO\right]}{\text{d}t}=\frac{1}{6}\frac{\text{d}\left[H_2O\right]}{\text{d}t}

3.

Write a balanced chemical equation based on the given differential rate equation:

 rate = −d[C2H6]dt= −27d[O2]dt=12d[CO2]dt=13 d[H2O]dtrate\ =\ -\frac{\text{d}\left[C_2H_6\right]}{\text{d}t}=\ -\frac{2}{7}\frac{\text{d}\left[O_2\right]}{\text{d}t}=\frac{1}{2}\frac{\text{d}\left[CO_2\right]}{\text{d}t}=\frac{1}{3}\ \frac{\text{d}\left[H_2O\right]}{\text{d}t}  

a)

C2H6 +  27\frac{2}{7}  O2  \rightarrow   12\frac{1}{2}   CO2 +  13\frac{1}{3}   H2O

b)

  \frac{1}{2}   CO2 +  \frac{1}{3}   H2O  →\rightarrow  C2H6 +  \frac{2}{7}  O2

c)

C2H6 +  72\frac{7}{2}  O2  →\rightarrow  2 CO2 + 3 H2O

d)

C2H6 +3 O2  →\rightarrow  2 CO2 + 3 H2O

4.

For the reaction:

4NH3(g) + 5O2(g) → 4 NO(g) + 6H2O(g)


the rate of disappearance of oxygen is 0.020 M/s. What is the rate of formation of H2O?

a)

0.03 Ms-1

b)

0.02 Ms-1

c)

0.017 Ms-1

d)

0.024 Ms-1

5.
State the order for the reaction.
a)
zero
b)
1st
c)
2nd
d)
3rd
6.
A reaction has the rate law: Rate = k [A][B].
What is the overall order of reaction?
a)
1st
b)
2nd
c)
3rd
d)
4th
7.
The rate law for the reaction 2NO(g) + O2(g) → 2NO2(g) is first order in O2 and third order overall. What is the rate law for the reaction?
a)
Rate = k [NO]2[O2]2
b)
Rate = k [NO]1[O2]2
c)
Rate = k [NO]2[O2]1
d)
Rate = k [2NO]2[O2]1
8.
Determine the order of reaction with respect to concentration of A
a)
zero
b)
1st
c)
2nd
d)
3rd
9.

The catalyst alters the rate of a chemical reaction by,

a)

providing an alternative pathway with a lower Ea

b)

changing the products formed in the direction of the reaction

c)

providing a surface on which the molecules react

d)

increasing the frequencies of collisions between molecules

10.

Liz observes 2 reactions, A and B.


Reaction A is performed in a beaker placed on top of a hotplate.


Reaction B is is performed in a beaker placed within a container of ice.


Which of the following statements is true?

a)

Reaction A will react slower because the higher temperature will cause more collisions because the heat makes the molecules tired.

b)

Reaction A will react slower because the higher temperature will cause give the reactants higher speed and kinetic energy.

c)

Reaction B will react faster because the lower temperature causes the particles to move slower, allowing them to have more time to attach to one another.

d)

Reaction B will react slower because the lower temperature makes the particles move slower, resulting in less collisions.