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WorksheetsTransition Elements
Total questions: 77
Worksheet time: 6hrs 25mins
Ligand + central metal atom/ion will form
compound
complex
molecule
substance
Which of the followings is not a common shape for complexes?
trigonal planar
tetrahedral
square planar
octahedral
Which of the followings is not a monodentate?
water
ammonia
1,2-diaminoethane
hydroxide ion
What is the coordination no. of this complex?
2
4
6
8
What is the shape of this complex?
linear
tetrahedral
square planar
octahedral
What is the oxidation state of Co?
0
+1
+2
+3
How do define coordination number?
no of ligands around the central metal atom/ion
no of molecules around the central metal atom/ion
no of dative covalent bond around the central metal atom/ion
oxidation state of the central metal atom/ion
What is the shape of this complex ion?
Hexagonal
Octahedral
Square Planar
Tetrahedral
What is the name of this complex ion?
Iron Hexaaqua (II)
Hexaaquairon (II)
Hexaaquaferrate (II)
Aquairon (II)
What is the name of this complex ion?
Tetrachlorocobalt (II)
Chlorocobaltate (II)
Tetrachlorocobaltate
Tetrachlorocobaltate (II)
What shape is this complex ion?
Octahedral
Square Planar
Linear
Tetrahedral
What shape is this neutral complex ion?
Octahedral
Square Planar
Linear
Tetrahedral
What is the name of this neutral complex ion?
Hexaaquacobalt (II)
Hexahydroxocobalt (II)
Tetraaquadihydroxocobalt (II)
Tetraaquadihydroxocobaltate (II)
Which one of these transition metals typically forms linear complexes
Silver
Copper
Nickel
Iron
What is the name of this shape?
Tetrahedral
Octahedral
Square Planar
Hexagonal
What is the best name for this neutral complex / molecule?
Tetracarboxylnickel
Tetracarbonylnickel (II)
Carbonylnickel (II)
Nickel Tricarbonyl
What is the best name for this complex?
Hexacyanoiron (III)
Hexacyanidoferrate (III)
Hexacyanoferrate (III)
Tetracyanoferrate (III)
What is the formula of this complex?
[Co(H2O)6]2+
[Co(OH)2(H2O)4]2+
[Co(OH)2(H2O)4]
[Co(OH)6]3-
What is the oxidation number of the transition
metal in each of the complexes [Co(NH3)6]3+ ?
2
3
-2
-3
What is the elctronic configuration of Cu2+
[Ar] 3d10 4s1
[Ar] 3d9 4s2
[Ar] 3d9 4s0
[Ar] 3d8 4s1
A transition metal complex has
metal ion
Ligands
Counter ions
molecules
what will be the shape of a transition metal complex having coordination number 6
Octahedral
Tetrahedral
Square Planar
what will be the shape of a transition metal complex having coordination number 2
Octahedral
Linear
Tetrahedral
Square planar
what will be the shape of a transition metal complex having coordination number 4?
Tetrahedral
Octahedral
Square Planar
Linear
1. The donor sites of (EDTA)4- are ?
O atoms only
N atoms only
Two N and four O atoms
Three N and three O atoms
The compound having lowest oxdation state of iron is
K4[Fe(CN)6]
K2FeO4
[Fe(CO)5]
K3[Fe(CN)6]
Among the following ions which one has the highest paramagnetism ?
[Cr(H2O)6]+3
[Fe(H2O)6]+2
[Cu(H2O)6]+2
[Zn(H2O)6]+2
In K4[Fe(CN)6] the number of unpaired electrons in iron are
0
2
3
5
The value of 'spin only' magnetic moment for one of the following configurations is 2.84 BM. The correct one is:
d4 (in strong field ligand in octahedral complexes)
d4 (in weak field ligand in octahedral complexes)
d3 (in weak as well as strong field ligand in octahedral complexes)
d5 (in strong field ligand in octahedral complexes)
In K4[Fe(CN)6] the number of unpaired electrons in iron are
0
2
3
5
The IUPAC name of the compound [Cu (NH3)4](NO3)2 is :
Cuprammonium nitrate
Tetraammine copper (II) dinitrate
Tetraammine copper (II) nitrate
Tetraammine copper (III) dinitrate
EAN (Effective Atomic Number) of a metal carbonyl M(CO)x is 36. If atomic number of metal M is 26, what is the value of x ?
4
8
5
6
Co-ordination compounds have great importance in biological systems. In this context, which statement is incorrect ?
Carboxypeptidase A is an enzyme and contains zinc
Haemoglobin is the red pigment of blood and contains iron
Cyanocobalmin is B-12 and contains cobalt
Chlorophylls are green pigments in plants and contain calcium
The coordination compounds,[Co(NH3)6]3+, [Cr(CN)6]3- and [Cr(NH3)6]3+, [Co(CN)6]3- are examples of...
Linkage isomerism
Coordination isomerism
Ionization isomerism
Geometrical isomerism
The sum of coordination number and oxidation number of the metal M in the complex [M(en)2 C2O4] Cl are
6
7
8
9
What are typical oxidation state for Sc?
-3
+3
-1
+1
What are typical oxidation state for Mn?
+2
+4
+6
+7
What are typical oxidation state for Fe?
+1
+2
+3
+4
Electron configuration for Sc is [Ar]4s13d1
Right
Wrong
Electron configuration for Cu is [Ar]4s13d7?
Right
Wrong
Electron configuration for Sc is [Ar]4s13d10?
Right
Wrong
Diamagnetism is permanent form of magnetism.
Right
Wrong
Transition metals are good ligands.
Right
Wrong
What is the coordination number?
[Fe(H2O)6 ]Cl2
1
2
4
6
Diamagnetism is permanent form of magnetism.
Right
Wrong
Diamagnetism is shown when electrons are spin-paired
Right
Wrong
Would the elements in D be paramagnetic or diamagnetic?
Paramagnetic
Diamagnetic
Both paramagnetic and diamagnetic
Some are paramagnetic, some are diamagnetic
Cannot be determined from the information given
Which of the following elements would be expected to be paramagnetic?
Ca
Zn
He
Mn
Among the following paramagnetic species is
B2
C2
O2
CO
What is the electron configuration of S 2- using noble gas method
A.[Ne]3s1
B.[Ne]3s23p3
C.[Ne]3s23p6
D.[Ne]3s23p4
Is the sodium atom paramagnetic or diamagnetic?
A.paramagnetic
B.diamagnetic
