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UV Spectroscopy

Total questions: 15

Worksheet time: 8mins

Name
Class
Date
1.

If two double bonds of a cyclic diene are present in the same ring, it is called ……. diene.

a)

Homoannular

b)

Heteroannular

c)

Homocylic

d)

Heterocyclic

2.

Trans- stilbene absorbs at longer wavelength than cis- stilbene because …..

a)

steric hinderance in cis- stilbene

b)

Planarity is disturbed in cis- stilbene

c)

Mobility of electron is more in trans- stilbene than in cis- stilbene

d)

All the above

3.

Which one of the following has maximum value of lambda max

a)

Acetone

b)

Ethyl methyl ketone

c)

Methyl vinyl ketone

d)

Acetaldehyde

4.

UV spectroscopy is not useful for distinguishing between ………

a)

Conjugated dienes

b)

Carbonyl compounds and enones

c)

Functional isomers

d)

Geometrical isomers ( Cis-Trans Isomers)

5.

UV spectroscopy provides information about presence of ……..

a)

Multiple bond

b)

Extent of conjugation

c)

Aromatic rings

d)

All of the above

6.

If a double bond is exocyclic to two rings,  λ\lambda max increases by ………. nm

a)

5

b)

10

c)

20

d)

30

7.

UV Spectroscopy is used to distinguish between cis and trans isomers

a)

True

b)

False

8.

A compound having  λ\lambda max 215nm indicates....

a)

Presence of conjugation

b)

Presence of carbonyl group

c)

Aromatic Compound

d)

Auxochrome

e)

All of the above

9.

Which of the following compound absorb at higher  λ\lambda     max....

a)

Cis Azobenzene

b)

Trans Azobenzene 

c)

Both Cis Azobenzene and Trans Azobenzene 

d)

None of these

10.

Basic  λ\lambda  max value or parent value for heteroannular diene is

a)

253 nm

b)

256 nm

c)

213 nm

d)

215 nm

11.

For one extra double bond extending conjugation, the  λ\lambda  max value increases by ...

a)

15 nm 

b)

30 nm

c)

60 nm

d)

90 nm

12.

Basic  λ\lambda  max value for homoannular diene is..

a)

256 nm

b)

253 nm

c)

215 nm 

d)

202 nm 

13.

Basic  λ\lambda  max value for  α, β\alpha,\ \beta  unsaturated ester or acid is

a)

210

b)

215

c)

193

d)

202

14.

Basic λ max value for five membered cyclic enone..

a)

193 nm

b)

202 nm

c)

210 nm

d)

215 nm

15.

Basic λ max value for α, β unsaturated aldehyde...

a)

193 nm

b)

202 nm

c)

210 nm

d)

215 nm