WorksheetsUV Spectroscopy
Total questions: 15
Worksheet time: 8mins
If two double bonds of a cyclic diene are present in the same ring, it is called ……. diene.
Homoannular
Heteroannular
Homocylic
Heterocyclic
Trans- stilbene absorbs at longer wavelength than cis- stilbene because …..
steric hinderance in cis- stilbene
Planarity is disturbed in cis- stilbene
Mobility of electron is more in trans- stilbene than in cis- stilbene
All the above
Which one of the following has maximum value of lambda max
Acetone
Ethyl methyl ketone
Methyl vinyl ketone
Acetaldehyde
UV spectroscopy is not useful for distinguishing between ………
Conjugated dienes
Carbonyl compounds and enones
Functional isomers
Geometrical isomers ( Cis-Trans Isomers)
UV spectroscopy provides information about presence of ……..
Multiple bond
Extent of conjugation
Aromatic rings
All of the above
If a double bond is exocyclic to two rings, λ max increases by ………. nm
5
10
20
30
UV Spectroscopy is used to distinguish between cis and trans isomers
True
False
A compound having λ max 215nm indicates....
Presence of conjugation
Presence of carbonyl group
Aromatic Compound
Auxochrome
All of the above
Which of the following compound absorb at higher λ max....
Cis Azobenzene
Trans Azobenzene
Both Cis Azobenzene and Trans Azobenzene
None of these
Basic λ max value or parent value for heteroannular diene is
253 nm
256 nm
213 nm
215 nm
For one extra double bond extending conjugation, the λ max value increases by ...
15 nm
30 nm
60 nm
90 nm
Basic λ max value for homoannular diene is..
256 nm
253 nm
215 nm
202 nm
Basic λ max value for α, β unsaturated ester or acid is
210
215
193
202
Basic λ max value for five membered cyclic enone..
193 nm
202 nm
210 nm
215 nm
Basic λ max value for α, β unsaturated aldehyde...
193 nm
202 nm
210 nm
215 nm
