WorksheetsXII CHEMISTRY SOLID STATE
Total questions: 40
Worksheet time: 21mins
The number of atoms per unit cell in simple, fcc and bcc unit cells are
1, 4, 2
1, 2, 4
2, 1, 4
2, 4, 1
In 3D close packing the ABCABCABC.....pattern gives rise to which type of close packing?
Hexagonal Close Packing (hcp)
Cubic Close Packing (ccp)
Face Centred Cubic Packing (fcc)
Both ccp and fcc
The packing efficiency in simple, fcc, bcc unit cells will be respectively
74% 52.4% 68%
52.4% 68% 74%
68% 74% 52.4%
52.4% 74% 68%
The relationship between the atomic radius (r) and edge length (a) of a simple, fcc, bcc cubic unit cell will be respectively
2a 42a 43a
2a 43a 42a
42a 43a 2a
43a 2a 43a
The coordination number in simple, fcc, bcc close packing arrangement will be respectively
1, 4, 2
6, 12, 8
4, 6, 8
none of the above
The total number of tetrahedral voids and octahedral voids in a given cubic unit cell with N number of atoms will be respectively
2N and N
N and 2N
4N and N
N and 4N
What type of material is this one?
Crystal
Amorphous
Covalent Crystal
Ionic Crystal
What is the coordination number in the FCC structure?
24
12
8
4
In METAL EXCESS DEFECTS the sites where an electron gets trapped in the anionic vacancy disturbing the ratio of cation to anion is known as
E- CENTRE
F- CENTRE
G- CENTRE
I- CENTRE
Which of the following is not a characteristic of a crystalline solid?
Definite and characteristic heat of fusion.
Long range order or perfect arrangement of constituent particles
Isotropic in nature
clean cleavage or smooth edges on cutting with a knife
Which of the following is an amorphous solid?
Copper(Cu)
Quartz glass (SiO2)
Silicon carbide (SiC)
Sodium Chloride (NaCl)
Which of the following is a network solid or covalent crystalline solid?
Diamond (C)
H2O (Ice)
Calcium Fluoride (CaF2)
Iron Metal (Fe)
What is the smallest repetitive unit of the crystal / lattice structure known as?
Atom
Molecule
Lattice Point
Unit Cell
The total number of tetrahedral voids and octahedral voids per unit cell of face-centred cell (fcc) are
8, 4
4, 8
2, 4
4, 2
Which of the following is a network solid?
SO2(Solid)
I2(Solid)
Diamond
H2O(Ice)
which of the following point defects are shown by AgBr(s) Crystals?
Schottky and impurity
Frenkel and schottky
Frenkel and impurity
Non stoichiometric defect
The percentage of empty space in a face centre cubic arrangement is
74
52
68
26
A mixed oxide has ccp arrangement in which the cations 'X' occupy 1/3rd of octahedral voids and the cations 'Y' occupy 1/3rd of tetrahedral voids.The formula of oxide is:
X 2Y 3O 2
XY 3O
X 2YO 3
XY 2O 3
A solid is made up of 2 elements P and Q. Atoms Q are in ccp arrangement,while P atoms occupy all the tetrahedral sites.The formula of the compound is:
PQ 2
P 6Q 4
P 2Q
PQ
A compound is formed by two elements X and Y. Atoms of the element Y (as anions) make ccp and those of the element X (as cations) occupy all the octahedral voids. The formula of the compound is :
X 2Y
X 4Y
XY
XY 2
Atoms of element B form hcp lattice and those of the element A occupy 2/3rd of tetrahedral voids. The formula of the compound formed by the elements A and B is:
A 4B 3
A 2B
A 3B 4
AB
Name the defects noticed when a solid is heated.
Frenkel Defect
Interstitial Defect
Schottky Defect
Vacancy Defect
A crystalline solid:
changes abruptly from solid to liquid when heated.
has no definite melting point.
undergoes deformation of its geometry easily
has irregular 3-dimensional arrangements.
Copper crystalline in FCC with a unit cell length of 361pm. What is the radius of a copper atom?
127pm
123pm
181pm
167pm
Schottky defect in crystal is observed when
The ion leaves its normal position and occupies an interstitial location
unequal number of cation and anions are missing from the lattice
density of the crystal increases.
an equal number of cations and anions are missing from the lattice.
Each of the following solids show, the Frenkel defect except
ZnS
AgBr
AgI
KCl
in which pair most efficient packing is present
hcp and bcc
hcp and ccp
bcc and ccp
bcc and simple cubic cell
Crystal system characterized by a ≠ b≠ c and α = β = γ = 90o
Hexagonal
Ortho rhombic
Tetragonal
Triclinic
The molecules of hydrogen bonded molecular solids contain .................... covalent bonds between H and F, O or N atoms.
polar
non polar
coordinate
Which of the following is crystalline solid
Rock salt
Cane Sugar
Gold
All of them
Amorphous solids are known as:
true solids
crystalline solids
super cooled liquid
True or False:
Amorphous solids have only a short range order
True
False
Crystalline solids are
Anisotropic
Isotropic
In non-polar molecular solids, the binding force between the particles is
Stronger dipole-dipole interactions
Strong hydrogen bond
London dispersion forces
Covalent bond
NaCl is an example for
Ionic solids
metallic solids
molecular solids
non polar molecular solids
The important characteristics of a crystal lattice are:
Each point in a lattice is called lattice point or lattice site
Each point in a crystal lattice represents one constituent particle which may be an atom, a molecule
(group of atoms) or an ion.
Lattice points are joined by straight lines to bring out the geometry of the lattice.
all of the above
Which defect is commonly seen in AgBr crystal?
Schottky defect
frenkel defect
Metal excess defect
Metal deficiency defect
A crystalline solid:
changes abruptly from solid to liquid when heated
has no definite melting point
does not undergoes deformation of its geometry easily
has regular 3-dimensional arrangements.
Crystal in which a=b=c and
α = β = γ =90Tetragonal
Rhombohedral
Cubic
Triclinic
The number of basic crystal systems are
7
5
3
