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Solubility

Total questions: 14

Worksheet time: 21mins

Name
Class
Date
1.

Which compound is "insoluble" according to the solubility rules?

a)

Na2SO4

b)

NaCl

c)

Fe(NO3)2

d)

Ca3(PO4)2

2.

Write an equilibrium expression for the dissolution of Ca3(PO4)2

a)

Ksp = [Ca2+]3[PO43-]2

b)

Ksp = [Ca2+]2[PO43-]3

c)

Ksp = [Ca2+][PO43-]

d)

Ksp=[Ca2+]3[PO43−]2[Ca3(PO4)2]Ksp=\frac{[Ca^{2+}]^3[PO_4^{3-}]^2}{\left[Ca_3\left(PO_4\right)_2\right]}

3.

The Ksp of Pb3(AsO4)2 = 4.0 x 10-36. What is the molar solubility of this compound?

a)

3.7 x 10-38

b)

3.3 x 10-8

c)

4.0 x 10-36

d)

5.8 x 10-8

4.

The solubility of cobalt(III) sulfide, (Co2S3) is 7.52 x 10-26 M. What is the Ksp?

a)

7.52 x 10-26 M

b)

1.44 x 10-125 M

c)

2.6 x 10-124 M

d)

8.75 x 10-8 M

5.

The Ksp of silver phosphate, Ag3PO4 is 2.6 x 10-18. What is the molar solubility?

a)

9.53 x 10-7 M

b)

3.05 x 10-5 M

c)

1.76 x 10-5 M

d)

4.58 x 10-7 M

6.

The Ksp of magnesium carbonate, MgCO3 is 3.5 x 10-8. What is the molar solubility of this compound in a 0.237 L solution that already contains 0.173 mol of Mg2+?

a)

4.79 x 10-8 M

b)

8.30 x 10-9 M

c)

0.487 M

d)

1.48 x 10-7 M

7.

What's the net ionic equation for the dissolution of Ca3(PO4)2 in water?

a)

Ca3(PO4)2 (s) ↔ 3 Ca2+ (aq) + 2 PO43− (aq)Ca_3\left(PO_4\right)_2\ \left(s\right)\ \leftrightarrow\ 3\ Ca^{2+}\ \left(aq\right)\ +\ 2\ PO_4^{3-}\ \left(aq\right)

b)

Ca3(PO4)2 (s) + 6H2O (l) ↔ 3 Ca(OH)2 (aq) + 2 H3PO4 (aq)Ca_3\left(PO_4\right)_2\ \left(s\right)\ +\ 6H_2O\ \left(l\right)\ \leftrightarrow\ 3\ Ca\left(OH\right)_2\ \left(aq\right)\ +\ 2\ H_3PO_4^{ }\ \left(aq\right)

c)

Ca3(PO4)2 (s) ↔ 3 Ca (s) + 2 PO4 (l)Ca_3\left(PO_4\right)_2\ \left(s\right)\ \leftrightarrow\ 3\ Ca\ \left(s\right)\ +\ 2\ PO_4^{ }\ \left(l\right)

d)

Ca3(PO4)2 (s) + H2O (l) ↔ 3 Ca (aq) + 2 PO4 (aq)Ca_3\left(PO_4\right)_2\ \left(s\right)\ +\ H_2O\ \left(l\right)\ \leftrightarrow\ 3\ Ca\ \left(aq\right)\ +\ 2\ PO_4\ \left(aq\right)

8.

Landonium sorenside, L2So is a sparingly soluble solid with Ksp = 6.9. You prepare a solution with [L+] = 3.0 M and [So2-] = 1.0 M. Does a precipitate form? Why?

a)

No because Q > Ksp

b)

No because Q < Ksp

c)

Yes because Q > Ksp

d)

Yes because Q < Ksp

9.

An aqueous solution at room temperature is 0.5 M in both Pb2+ and Ca2+ ions. You want to separate these two ions by selective precipitation using chloride. What percentage of the first ion has been precipitated when the second ion begins precipitating? (PbCl2; Ksp = 1.6 x 10-5) and (CaCl2; Ksp = 3.2 x 10-11)

a)

100.%

b)

0.0002%

c)

99.96%

d)

0.04%

10.

Which compound has a higher molar solubility? PbCO3 (Ksp = 7.4 x 10-14) or BaCO3 (Ksp = 2.0 x 10-9).

a)

BaCO3

b)

PbCO3

c)

Can't say for sure

11.

Which compound has the highest molar solubility? AgCl (Ksp = 1.8 x 10-10) or LaF3 (Ksp = 2.0 x 10-9) or CaF2 (Ksp = 3.2 x 10-11).

a)

AgCl

b)

LaF3

c)

Can't say for sure

d)

CaF2

12.

What is the pH of a saturated solution of Al(OH)3 (Ksp = 1.8 x 10-5)?

a)

0.09

b)

1.07

c)

12.93

d)

13.10

13.

What concentration of Cu2+ is necessary to precipitate Cu(OH)2 (2.2 x 10-20) in a solution with a pH of 8.5?

a)

3.92 x 10-4 M

b)

2.58 x 10-5 M

c)

6.96 x 10-15 M

d)

2.2 x 10-9 M

14.

A 300. mL solution of 0.013 M Pb(NO3)2 and 400. mL solution of 0.56 M NaCl are combined to form a precipitate. What is the equilibrium concentration of chloride ion after the precipitate forms? (PbCl2; Ksp = 1.57 x 10-5)

a)

0.096

b)

0.0054 M

c)

0.31 M

d)

0.54 M