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Coordination Compounds - Part 2

Total questions: 35

Worksheet time: 1hrs 10mins

Name
Class
Date
1.

The IUPAC name of the compound [Cu (NH3)4](NO3)2 is :

a)

Tetraammine copper (II) nitrate

b)

Tetraammine copper (III) nitrate

c)

Tetraammine copper (II) nitrate

d)

Cuprammonium nitrate

2.

Which type of isomerism does it have?

a)

Geometrical isomerism

b)

Functional Group isomerism

c)

Optical isomerism

d)

Structural isomerism

3.

What is the coordination number of this complex?

a)

2

b)

3

c)

4

d)

6

4.

What is the correct formula for the complex ion: Tetraaquadichlorochromium(III) chloride?

a)

[Cr(H2O)4Cl2]Cl

b)

[Cr(H2O)3Cl3]Cl

5.

Which of the following complexes can exhibit optical isomerism? (en = H2N–CH2–CH2–NH2 and is bidentate)

a)

cis–Co(NH3)4Cl2

b)

trans–Co(en)2Br2

c)

cis–Co(en)2Cl2

d)

Co(NH3)3Cl3

6.

The type of isomerism shown by the complex [CoCl2(en)2] is

a)

Geometrical isomerism

b)

Coordination isomerism

c)

Linkage isomerism

d)

Ionization isomerism

7.

Which of the following compounds shows optical isomerism?

a)

[Cu(NH3)4]2+

b)

[ZnCl4]2–

c)

[Cr(C2O4)3]3–

d)

[Co(CN)6]3–

8.

A molecule that cannot be superimposed on its mirror image is said to exhibit which of the following?

a)

geometrical isomerism

b)

optical isomerism

c)

linkage isomerism

d)

reactive isomerism

9.

Which of the following pairs represents linkage isomers?

a)

[Pd(P Ph3)2 (NCS)2] and [Pd(P Ph3)2(SCN)2]

b)

[Co (NH3)5 NO3]SO4 and [Co(NH3)5SO4] NO3

c)

[Pt Cl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2

d)

[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [CuCl4]

10.

The compound having lowest oxdation state of iron is

a)

K4[Fe(CN)6]

b)

K2FeO4

c)

[Fe(CO)5]

d)

K3[Fe(CN)6]

11.

Ligands and central metal ions are respectively

a)

lewis base and lewis acid

b)

lewis acid and lewis base

c)

both lewis acid

d)

bothlewis base

12.

In the coordination compound ,K4[Ni(CN)4], the oxidation state of nickel is

a)

0

b)

+1

c)

-1

d)

+2

13.

Coordination number of Ni in [Ni(C2O4)3]-4 is

a)

3

b)

4

c)

6

d)

5

14.

NH2(CH2)2NH2 is

a)

unidentate ligand

b)

bidentate ligand

c)

tridentate ligand

d)

ambidentate ligand

15.

The number of chloride ions given by the complex [Co(NH3)5Cl]Cl2

a)

2

b)

3

c)

1

d)

None

16.

-SCN- is an

a)

unidentate ligand

b)

bidentate ligand

c)

tridentate ligand

d)

ambidentate ligand

17.

A complex compound in which the oxidation number of a metal is zero is

a)

K4 [Fe (CN)6]

b)

K3 [Fe (CN)6]

c)

[Ni (CO)4]

d)

[Pl (NH3 )4]Cl2

18.

A ligand can also be regarded as

a)

Lewis acid

b)

Bronsted base

c)

Lewis base

d)

Bronsted acid

19.

Which of the following species is not expected to be a ligand

a)

NO

b)

NH4+

c)

NH2CH2CH2NH2

d)

CO

20.

The IUPAC name of K2 [Ni (CN)4] is

a)

Potassium tetracyanatonickelate (II)

b)

Potassium tetracyanonickelate (III)

c)

Potassium tetracyanonickel (III)

d)

Potassium tetracyanatonickel (II)

21.

The IUPAC name of the complex [Co (NH3)4 Cl2] Cl is

a)

dichloro tetraammine cobalt (III) chloride

b)

tetraammine dichloro cobalt (III) chloride

c)

tetraammine dichloro cobalt (II) chloride

d)

tetraammine dichloro cobalt (IV) chloride

22.

The oxidation state of Cr in [Cr(NH3)4Cl2]+ is

a)

+3

b)

+2

c)

+1

d)

0

23.

The central metal ion of K4[Fe(CN)6]

a)

Fe+

b)

Fe2+

c)

Fe3+

d)

Fe4+

24.

In the complex [Co(NH3)5Cl]Cl, the coordination number is

a)

3

b)

5

c)

6

d)

4

25.

Which one is a cationic complex?

a)

K3[Fe(CN)6]

b)

Na2[Ni(EDTA)]

c)

[Co(en)2Cl2]Cl

d)

K3[Fe(CN)5NO]

26.

Which one is a neutral ligand?

a)

H2O

b)

NH3

c)

CO

d)

All of these

27.

Write down the IUPAC name of the following complex:

[Pt(NH3)(H2O)Cl2]\left[Pt\left(NH_3\right)\left(H_2O\right)Cl_2\right]  



(a)  

28.

Write the IUPAC name of

[Cr(en)3]Cl3\left[Cr\left(en\right)_3\right]Cl_3  



(a)  

29.

Write down the IUPAC name of

K3[Fe(CN)6]K_3\left[Fe\left(CN\right)_6\right]  



(a)  

30.

Write the IUPAC name of

[Co(en)2Cl2]+\left[Co\left(en\right)_2Cl_2\right]^+  



(a)  

31.

Chiral carbons will produce _____________.

a)

structural isomers

b)

optical isomers

c)

polymers

d)

monomers

32.

What property can be assigned to a carbon atom that has four different atoms or structural groups attached to it?

a)

isomerity

b)

chirality

c)

chivalry

d)

geometry

33.

Compounds that are composed of the same number and type of atoms but have them arranged in different ways are ___________.

a)

isomers

b)

isotopes

c)

polymers

d)

alkanes

34.

In a stereoisomer, ________ means "on the same side" and ______ means "across from."

a)

cis; trans

b)

cis; L

c)

D; L

d)

trans; cis

35.
Geometric isomers shown below is called
a)
Cis/trans 1,2 dichloroethane
b)
Cis/trans 1,2 dichloroethene
c)
Cis/trans 1,2 chloroethane
d)
Cis/trans 1,2 chloroethene