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Worksheets

MasterChempro

Total questions: 33

Worksheet time: 1hrs 9mins

Name
Class
Date
1.

FULL NAME

4 lines
2.

CLASS

4 lines
3.

PHONE NUMBER

4 lines
4.

Given the following balanced equation :

2NO(g) + Cl2(g) → 2NOCl(g)

If the rate of disappearance of Cl2 is 4.84 x 10-2 Ms-1, what is the rate of disappearance of NO?

a)

1.45 x 10-2 Ms-1

b)

2.42 x 10-2 Ms-1

c)

3.67 x 10-2 Ms-1

d)

9.68 x 10-2 Ms-1

5.

In the chemical reaction, the successful formation of products depends on the following factors EXCEPT:

a)

The collisions between reacting molecules must be effective

b)

The colliding molecules must approach each other in the right orientation

c)

The energy of colliding molecules must be equal to or more than activation energy

d)

A collision between molecules must have energy less than activation energy

6.

For second order reaction, the initial concentration of reactant A is 0.24 M. If the rate constant is 8.1 x 10-2 M-1 s-1, what is the concentration of A after 29 seconds?

a)

0.02 M

b)

0.15 M

c)

0.30 M

d)

0.45 M

7.

The reaction A + 2B → products was found to have the rate law, Rate = k[A][B]2. Predict by what factor the rate of reaction will increase when the concentration of B is doubled and the concentration of A remained unchanged

a)

2

b)

4

c)

6

d)

8

8.

The first order rate constant for the decomposition of 0.5 M compound A at 100oC is 0.03 min-1. Calculate the half-life of A.

a)

1.5 min

b)

8.3 min

c)

23.1 min

d)

66.7 min

9.

The enthalpy of formation is the enthalpy change

a)

when one mole of the pure compound is formed from its elements under standard conditions

b)

when 1 mole of pure substance is completely burned in excess oxygen, under the given temperature and pressure of the reaction

c)

when 1 mole of H+ (aq) ions from acid reacts with 1 mole of OH- (aq) ions from an alkali to form 1 mole of water under the stated condition of the experiment

d)

the magnitude of the enthalpy change of a chemical reaction depends only on the difference in the enthalpy content of the products and the reactants, and does not on how the reaction is completed

10.

Which of the following equations represents the enthalpy change of combustion?

a)

2C4H10(g) +13O2(g) → 8CO2 (g) + 10H2O(g)

b)

C4H10(g) +13/2O2(g) → 4CO2 (g) + 5H2O(g)

c)

C4H10 + 9/2O2 = 4CO (s)+ 5H2O

d)

C4H10 + 5/2O2 = 4C(s) + 5H2O(g)

11.

Calculate the enthalpy change represented by X

a)

+695kJ/mol

b)

-695kJ/mol

c)

-635kJ/mol

d)

-635kJ/mol

12.

If the specific heat of water is 4.18 J/g∙°C, how much heat is required to increase the temperature of 1.2 kg of water from 23 °C to 39 °C?

a)

-80,256 J

b)

80.256 J

c)

80,256 J

d)

-80.256 J

13.

4 NH3 (g) + 5 O2 (g) ⟶ 4 NO (g) + 6 H2O (g)

Using the following information, calculate ΔH for the reaction shown above:

N2 (g) + O2 (g) ⟶ 2 NO (g) ΔH = -180.5 kJ

N2 (g) + 3 H2 (g) ⟶ 2 NH3 (g) ΔH = -91.8 kJ

2 H2 (g) + O2 (g) ⟶ 2 H2O (g) ΔH = -483.6 kJ

a)

256.0 kJ

b)

-1628.2 kJ

c)

-6387 kJ

d)

+1628.2 kJ

14.

The standard reduction potential for several half-reactions at 298K are shown below. Which of the following species is the strongest oxidising agent?

a)

    

X⁻    

         

b)

Y³⁺

c)

Z

d)

X₂

15.

Given standard reduction potential for half reactions below. Based on above data, which of the following statements is/are correct?

         I.            Magnesium is the strongest reducing agent

       II.            The reaction 2Fe²⁺ + Br₂ → 2Fe³⁺ + 2Br⁻ can occur spontaneously.

     III.            The standard e.m.f for the cell Mg(s) | Mg²⁺(aq) || Ni²⁺(aq) | Ni(s) is +2.12V

a)

    I only

b)

I and II only

c)

  II and III only

d)

I, II and III only

16.

Consider a voltaic cell in which the reaction is

Zn(s) + 2H (aq) →   Zn²⁺ (aq) + H (g)

It is found that the cell voltage is + 0.560 when [Zn²⁺] = 1.0 M, P H = 1.0 atm. Determine the concentration of H? Given standard reduction potential for H⁺|H₂ = 0 and Zn²⁺|Zn = -0.762 V

a)

+0.762 M

b)

3.87 M

c)

3.87 x 10⁻⁴ M

d)

1.0 x 10⁻⁴ M

17.

Choose the correct statement about electrolysis of aqueous sodium sulphate, NaSO.

          I.            At cathode, water is preferentially discharged.

        II.            Hydrogen gas is produced at anode

      III.            SO₄⁻ ions are not selected to be oxidised due to S already in its highest oxidation state.

      IV.            Bubble gas of oxygen evolved at anode

a)

I and III only

b)

  I, III and IV

c)

II and III only

d)

II, III and IV

18.

Chromium metal can be electroplated from an aqueous solution of potassium dichromate. The reduction half reaction is

CrO ²⁻ (aq) + 14H (aq) + 12e ⟶ 2Cr (s) + 7H₂O (l)

How many grams of chromium will be plated by 1.00 x 10 C? [Ar Cr: 52.0]

a)

0.1036 g

b)

0.0173 g

c)

0.8980 g

d)

5.3872 g

19.

Which of the following is the most probably a cyclic alkane?

a)

C₄H₁₀

b)

C₅H₁₀

c)

C₆H₁₀

d)

C₆H₆

20.

A compound that is wrongly named 3,3,4-trimethylbutane. Identify the correct name for this compound.

a)

2-methylpentane

b)

3,3-dimethylpentane

c)

2-methylhexane

d)

Hexane

21.

Boiling point of alkanes are varies based on strength of intermolecular forces. Arrange these alkanes according to decreasing boiling point; pentane, 2,2-dimethylpropane, hexane, 2-methylbutane

a)

2,2-dimethylpropane > 2-methylbutane > pentane > hexane

b)

hexane > 2,2-dimethylpropane > 2-methylbutane > pentane

c)

hexane > pentane > 2-methylbutane > 2,2-dimethylpropane

d)

hexane > pentane > 2,2-dimethylpropane > 2-methylbutane

22.

Ethane undergoes bromination in presents of sunlight to produce alkyl halide. Identify incorrect statement about this reaction.

a)

Chemical equation: CH₃CH₃ + Br₂/CH₂Cl₂ + uv ⟶ CH₃CH₂Br + HBr

b)

The reddish brown colour of bromine turn colourless after the reaction has finished.

c)

Mechanism of free radical substitution (Termination step): CH₃CH₂. + CH₃CH₂. ⟶ CH₃CH₃CH₃CH₃

d)

Mechanism of free radical substitution (Propagation step): CH₃CH₃ + Cl. ⟶ CH₃CH₂. + HCl

23.

. The combustion reaction of propane is carried out under excess oxygen and then under limited oxygen. Which chemical equation is not related to this reactions/    

a)

CH₃CH₂CH₃ + 3O₂ ⟶ 3CO₂ + 4H₂

b)

CH₃CH₂CH₃ + 2O₂ ⟶ 3CO₂ + 4H₂O

c)

CH₃CH₂CH₃ + 7/2 O₂ ⟶ 3CO + 4H₂O

d)

CH₃CH₂CH₃ + 2O₂ ⟶ 3C + 4H₂O

24.

Name the compound

a)

cis-4-heptene

b)

trans-4-heptene

c)

cis-3-heptene

d)

trans-3-heptene

25.

Which rule states that....

"Elimination reaction will give an alkene with the most

highly substituted double bond as the major product"

a)

Hund's rule

b)

Saytzeff’s Rule

c)

Markovnikov's rule

d)

Huckel's rule

26.

What is the general formula for alkenes?

a)

CnH2n

b)

CnH2n+2

c)

CnH2n-2

d)

CnH2n-6

27.

Which chemical test can be used to differentiate

cyclohexene and cyclohexane?

a)

Chlorine test

b)

Baeyer's Test

c)

Fehling's Test

d)

Nitrous acid test

28.

What is the product formed when propene react with

cold dilute potassium permanganate solution?

a)

propanol, CH3CH2CH2OH

b)

propanoic acid, CH3CH2COOH

c)

propane, CH3CH2CH3

d)

propanediol, CH2(OH)CH(OH)CH3

29.

What is the type of reaction for benzene?

a)

Elimination reaction

b)

Electrophilic aromatic substitution reaction

c)

Electrophilic additon reaction

d)

Nucleophilic substitution reaction

30.

Name the compound

a)

2-methyl-1-hydroxybenzene

b)

1-methyl-2-hdroxybenzene

c)

1,2-hydroxytoluene

d)

2-methylphenol

31.

What is the product formed when

a)
b)
c)
d)
32.

What is the product formed when

a)
b)
c)
d)
33.

what is the function of Lewis Acid in benzene reaction?

a)

to Increase polarity of halogen molecules

b)

as a source of energy for cleavage to occurs

c)

to produce negative ions benzene to react

d)

to break the polar bonds between

C-X