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AP Chemistry Unit 2 Review

Total questions: 40

Worksheet time: 45mins

Name
Class
Date
1.

The Lewis structure of the CO32- ion is

a)
b)
c)
d)
e)
2.

In the nitrite ion (NO2-), __________.

a)

both bonds are single bonds

b)

both bonds are double bonds

c)

both bonds are the same because of resonance

d)

there are 20 valence electrons

e)

there is one single and one double bond

3.

Of the possible bonds between carbon atoms (single, double, and triple), _____.

a)

a triple bond is longer than a single bond

b)

a double bond is stronger than a triple bond

c)

a single bond is stronger than a triple bond

d)

a double bond is longer than a triple bond

e)

a single bond is stronger than a double bond

4.

The formal charge on carbon in the molecule shown is _______.

a)

0

b)

+1

c)

+2

d)

+3

e)

-1

5.

In the Lewis structure of ClF, the formal charge on Cl is _______ and the formal charge on F is _______.

a)

0,0

b)

-1, -1

c)

0, -1

d)

-1, 0

e)

+1, -1

6.

In the resonance form of ozone shown, the formal charge on the central oxygen atom is _______.

a)

0

b)

+1

c)

-1

d)

+2

e)

-2

7.
The electronegativity of C is 2.5, F is 4.0.  predict the character of a C-F bond.
a)
polar covalent
b)
nonpolar covalent
c)
ionic
d)
metallic
8.

Choose the correct shape for H2S

a)

Tetrahedral

b)

Trigonal pyramidal

c)

Bent

d)

Trigonal planar

9.
The following molecules all contain polar bonds however only one is a polar molecule.  Which one?
a)
CCl4
b)
CO2
c)
NH3
d)
CH4
10.
 A lone pair is defined as
a)
A pair of bonding electrons
b)
One non-bonding electron
c)
A pair of non-bonding electrons
d)
A pair of electrons on the central atom
11.
Determine the electron geometry (eg) and molecular geometry (mg) of XeF4 (Lewis structure is shown) .
a)
eg = tetrahedral, mg = tetrahedral
b)
eg = linear, mg = linear
c)
eg = octahedral, mg = square planar
d)
eg = trigonal bipyramidal, mg = tetrahedral
12.
What is the VSPER shape of PCl5
a)
See-saw
b)
trigonal planar
c)
octahedral
d)
trigonal bipyramidal
13.
The interaction energy of two hydrogen atoms is shown on the graph above. Which of the answer choices displayed on the graph best represents the bond length of the H2 molecule?
a)
A
b)
B
c)
C
d)
D
14.
Consider the molecule below.  Determine the molecular geometry at each of the 2 labeled carbons.
a)
C1 = tetrahedral, C2 = linear
b)
C1 = trigonal planar, C2 = bent
c)
C1 = bent, C2 = trigonal planar
d)
C1 = trigonal planar, C2 = tetrahedral
15.

Draw the Lewis Dot structure for ICl2- and determine its predicted molecular geometry.

a)

see-saw

b)

trigonal bipyramidal

c)

linear

d)

bent

16.
Pi bonds are formed by 
a)
side to side overlap of s orbitals
b)
end to end overlap of s orbitals
c)
side to side overlap of p orbitals
d)
end to end overlap of p orbitals
17.
This structure is called...
a)
tetrahedral
b)
Trigonal pyramidal
c)
Seesaw
d)
Bent/Angular
18.

The carbon atom undergoes what type of hybridization?

a)

sp hybridization

b)

sp2 hybridization

c)

sp3 hybridization

d)

dsp3 hybridization

19.

The nitrogen atom undergoes what type of hybridization?

a)

sp hybridization

b)

sp2 hybridization

c)

sp3 hybridization

d)

dsp3 hybridization

20.

Which best describes the bonding in the cyanide ion (CN-)?

a)

3 (sigma) bonds

b)

2 (sigma) bonds and I (pi) bond

c)

1 (sigma) bond and 2 (pi) bonds

d)

3 (pi) bonds

21.

The molecule that uses sp3d hybrid orbital on the central atom is

a)

BCl3

b)

NCl3

c)

ICl3

d)

PCl3

22.

What is the molecular geometry of this molecular compound?

a)

Trigonal bypyramidal

b)

Tetrahedral

c)

Trigonal planar

d)

linear

23.

What is the bond angle for the central atom in this molecular compound? *Just type in the number!

(a)  

24.

Which of the following Lewis Structures for this molecule is most accurate? Explain your answer.

4 lines
25.

As two atoms covalently bond to become more stable, what happens to their bond energy?

(a)  

26.

Which of these alloys is a substitutional alloy?

a)

Bronze

b)

Steel

27.

The melting point of MgO is higher than that of NaF. Which of the following best explains this observation?

a)

O2- is more negatively charged than F-

b)

Mg2+ is more positively charged than Na+

c)

The O2- ion is smaller than the F- ion

d)

Mg2+ is more positively charged than Na+ and O2- is more negatively charged than F-

28.

The diagram above shows two resonance structures for a molecule of C6H6 . The phenomenon shown in the diagram best supports which of the following claims about the bonding in C6H6?

a)

In the C6H6 molecule, all the bonds between the carbon atoms have the same length.

b)

Because of variable bonding between its carbon atoms, C6H6 is a good conductor of electricity.

c)

The bonds between carbon atoms in C6H6 are unstable, and the compound decomposes quickly.

d)

The C6H6 molecule contains three single bonds between carbon atoms and three double bonds between carbon atoms.

29.

How would coulombic forces affect physical properties of a molecule such as boiling (BP) and melting point(MP)?

a)

Higher coulombic forces would lead to lower BP and MP

b)

Higher coulombic forces would lead to higher BP and MP

c)

Higher coulombic forces would lead to higher BP ,but a lower MP

d)

Lower coulombic forces would lead to higher BP and MP

30.
What is the measure of a tetrahedral bond angle?
a)
90 Degrees
b)
109.5 Degrees
c)
120 Degrees
d)
180 Degrees
31.

Which of the following molecular shapes would have a bond angle of 180 Degrees?

a)

Bent

b)

Trigonal Planar

c)

Tetrahedral

d)

Linear

32.

Steel is an alloy containing Fe atoms and C atoms. Which of the following diagrams best represents the particle-level structure of steel?

a)
b)
c)
d)
33.

Which of the following molecules has the shortest bond length?

a)

N2

b)

O2

c)

Cl2

d)

Br2

e)

I2

34.

What is the bond angle in H2S molecule?

a)

107

b)

104.5

c)

180

d)

120

35.

Why is the bond angle in NH3 molecule is smaller than that in CH4 molecule?

a)

Among the four electron pairs around the central atom N in NH3

molecule, there are two lone pairs which require more space than bonding pairs and tend to compress the angles between the bonding pairs.

b)

Among the four electron pairs around the central atom N in NH3

molecule, there is one lone pair which requires more space than a bonding pair and tends to compress the angles between the bonding pairs.

c)

Among the four electron pairs around the central atom N in NH3

molecule, there is one lone pair which requires less space than bonding pairs and tend to increase the angles between the bonding pairs.

d)

In reality, bond angle in NH3 molecule is larger than that in CH4 molecule.

36.

Breaking bonds is _________________. Forming bonds is ______________________

a)

endothermic, exothermic

b)

exothermic, endothermic

37.

Use bond energies to determine the energy change for the following reaction and use the information to determine if it is an endothermic or exothermic reaction:


HCN + H2 --> CH3N2

4 lines
38.

The average bond enthalpies for O-O and O=O are 146 and 496 kJ/mol respectively. What is the enthalpy change, in kJ, for the reaction below?

H2O2(g) → H2O(g) + ½O2(g)

a)

-102

b)

+102

c)

+350

d)

+394

39.

Which has the higher lattice energy: BeCl2 or LiCl?

a)

LiCl because lithium is smaller than beryllium

b)

LiCl because Li has a smaller ionic charge than Be

c)

BeCl2 because there are more chlorine atoms in the bond

d)

BeCl2 because Be has a stronger ionic charge than Li

40.

Choose the ionic compound with the greater magnitude of lattice energy.

a)

NaCl

b)

KCl