WorksheetsChemical Equilibrium & Chemical Kinetics
Total questions: 50
Worksheet time: 50mins
The rate law for the reaction is rate = k[A] [B] . The order of reaction is
Zero
2/3
1/3
5/3
The half-life of following first order reaction A → B + C is 10min. The
concentration of A would be reduced to 12.5% of original concentration in
30 min
40 min
70 min
90 min
In the given reaction 2A + B →products , it is observed on quadrupling the conc.
of B, rate of reaction increases 16times. The order of reaction with respect to B is
0
1
2
-1
If rate constant for any reaction is equal to rate of reaction at all concentrations. Then the order of reaction will be
Zero
One
Two
Three
The rate of chemical reaction roughly doubles for every 10
oC rise of temperature. If temperature is raised by 20 C, the rate may become
4 times
16 times
8 times
8 times
In Rate = k[A][B] the second order reaction become ____ if [A] is in large excess
2nd order
3rd order
Zero order
Pseudo 1st order
Determine partial pressure of NO at equilibrium if partial pressure of N2 and O2 are 2 and 8 torr respectively (Kp = 4.0) N2 + O2 2NO
8 torr
16 torr
4 torr
64 torr
For the reaction A + B C + D one starts with 6 moles A and 7 moles B per dm3. When equilibrium is attained, 4.5 moles of C is formed, what is the value of Kc for the reaction
3
1.8
3.78
5.4
Kc value for decomposition of HF is 10–13 at 2000°C it means that
Reactants are more stable
Products are more stable
Reactants are unstable
Reactants and products are equally stable
At equilibrium, relationship between concentrations of reactants and products
[Reactants] > [Products]
[Reactants] = [Products]
[Reactants] < [Products]
All are possible
A2 +B2 2AB
If in the above reaction the value kf is 2.0 and kr is 0.1 then calculate the value of Kc for reaction
2
20
0.1
0.05
For endothermic reaction, Ea is activation energy in kJ/mol. The maximum value of
enthalpy of reaction (ΔH) will be
Less than Ea
More than Ea
Equal to Ea
Zero
In N2 + 3H2 2NH3 , the yield of product will be minimum if
Temperature is increased and pressure remains same
Temperature is increased and pressure is decreased
Both temperature and pressure are increased
Amount of catalyst is increased
When 1 mole of HCl is added to 1 molar aqueous solution of H2S then
pH of solution decreases
S-2 ion concentration decreases
Ionization of H2S decreases
All of these
Correct optimum conditions for synthesis of ammonia by Haber process
200-300 atm, 400°C, Fe/MgO, Al2O3 and SiO2
1-2 atm 400-500°C, V2O5
200-300 atm, 650°C, Pt
10-20atm, 200°C
Which one will affect both equilibrium position and equilibrium constant?
Pressure or volume change
Concentration change
Temperature change
Catalyst
Ksp values of four salts are given, which is least soluble in water
10^-23
10^-25
10^-20
10^-21
The value of Kc for endothermic reversible reaction
Increases with increase in temperature
Decreases with increase in temperature
Is independent of temperature
No prediction can be made
Select the buffer which is not acidic
HCOOH and HCOONa
NH4OH and NH4NO3
CH3COOH and CH3COOK
C6H5COONa and C6H5COOH
A buffer is prepared by mixing the solutions of equimolar acetic acid and sodium
acetate. The pH should be equal to
pKa of acid
Less than pKa of acid
Number of moles of acid
More than pKa of acid
Solubility product of a salt AB is 1.6×10^–7mol2/ dm^6, what will be its solubility(mol/dm^3)
4×10^-4
2×10^–4
4×10^-8
2×106-8
Following is the condition of reversible reaction that is not affected by pressure
(where ∆n = number of moles of product–number of moles of reactants)
∆n = 0
∆n = 1
∆n = -1
∆n = 2
In a reaction, A + B → Product, rate is doubled when the concentration of B is
doubled, and rate increases by a factor of 8 when the concentrations of both the
reactants A and B. are doubled, rate law for the reaction can be written as
Rate = k [A][B]
Rate = k [A]2[B]
Rate = k [A]3[B]
Rate = k [A][B]2
When the change in concentration is 6×10^–5 moldm^-3 and time for that change is
100 seconds, the rate of reaction will be
6×10^–3 moldm^–3
sec^–1
6×10^–7 moldm^–3
sec^–1
6×10^–4 moldm^–3
sec^-1
6×10^–5 moldm^–3
sec^-1
For reaction A+2B →C, if concentration of A and B is doubled, then rate of reaction
will increase
4 times
8 times
6 times
16 times
Half-life of 1st order reaction A →B is 0.693/2
seconds its rate constant is
0.231s–1
2s–1
4s–1
20s–1
Rate of first order reaction depends on ______
Concentration of one reactant
Concentration of two reactants
Concentration of three reactants
Independence of the initial concentration
For which order of reaction rate constant has same units as rate of reaction
First order reaction
Third order reaction
Second order reaction
Zero order reaction
Arrhenius equation describes the effect of
Temperature on rate of reaction
Volume on rate of reaction
Pressure on rate of reaction
Number of moles on rate of reaction
Following first order reaction is 50 percent completed in 24 minutes at 300K
2N2O5 → 4NO2 + O2 [N2O5] given = 10g
How many grams of N2O5 will be left behind after 72 minutes?
1.77g
1.25g
2.5g
0.630g
The rate expression of a reaction is, Rate = k[A][B]2
What happens to rate of reaction if concentrations of A and B are doubled?
Increased two times
Increased four times
Increased eight times
Increased nine times
If Ef and Eb are the activation energies for forward and backward reaction
respectively. How these can be compared for the exothermic reaction.
Ef > Eb
Ef < Eb
Ef = Eb
No prediction can be made
The units of second order rate constant are usually expressed as
mole^1 dm^–3s–1
mol–1 dm3s–1
s–1
mol–2 dm
At zero activation energy (Ea) value of Arrhenius constant A is
K
K/2
2K
Zero
For the following reaction 2A(g) + B(g) 3C(g). we can write
Kc > Kp
Kp – Kc = 0
Kc < Kp
Kp – Kc = -1
Kp and Kc has following relationship Kp = Kc (RT) n
. Here n is equal to
nP - nR
nP + nR
nP / nR
nP nR
If Ksp = [M+^2]3[X^-3]2
, the chemical formula of compound is
MX2
M2X3
M3X2
M2X
Which relationship correctly represent that precipitation occurs.
Ionic product > Ksp
Ionic product < Ksp
Ionic product = Ksp
None of these
The term common ion effect is used to describe the behavior of a solution in which
________ ion is produced by __________ compounds
Same, different
Different, same
Same, same
If Kc has every small value, the extent of reaction in the forward direction is
Very small
Very large
Equal to backward reaction
Reaction does not move in reverse direction
All of the following methods are used to calculate the rate of reaction except one
Optical rotation method
Conductometric method
Half-life method
Spectrometric method
Arrhenius equation describes the effect of
Temperature on rate of reaction
Volume on rate of reaction
Pressure on rate of reaction
Number of moles on rate of reaction
A
B
C
D
A
B
C
D
A
B
C
D
A
B
C
D
A
B
C
D
A
B
C
D
A
B
C
D
A
B
C
D
