wayground logo

Free Printable Worksheets

Font size

S
M
L
XL
Worksheets

Chemical Equilibrium & Chemical Kinetics

Total questions: 50

Worksheet time: 50mins

Name
Class
Date
1.

The rate law for the reaction is rate = k[A] [B] . The order of reaction is

a)

Zero

b)

2/3

c)

1/3

d)

5/3

2.

The half-life of following first order reaction A → B + C is 10min. The

concentration of A would be reduced to 12.5% of original concentration in

a)

30 min

b)

40 min

c)

70 min

d)

90 min

3.

In the given reaction 2A + B →products , it is observed on quadrupling the conc.

of B, rate of reaction increases 16times. The order of reaction with respect to B is

a)

0

b)

1

c)

2

d)

-1

4.

If rate constant for any reaction is equal to rate of reaction at all concentrations. Then the order of reaction will be

a)

Zero

b)

One

c)

Two

d)

Three

5.

The rate of chemical reaction roughly doubles for every 10

oC rise of temperature. If temperature is raised by 20 C, the rate may become

a)

4 times

b)

16 times

c)

8 times

d)

8 times

6.

In Rate = k[A][B] the second order reaction become ____ if [A] is in large excess

a)

2nd order

b)

3rd order

c)

Zero order

d)

Pseudo 1st order

7.

Determine partial pressure of NO at equilibrium if partial pressure of N2 and O2 are 2 and 8 torr respectively (Kp = 4.0) N2 + O2 2NO

a)

8 torr

b)

16 torr

c)

4 torr

d)

64 torr

8.

For the reaction A + B C + D one starts with 6 moles A and 7 moles B per dm3. When equilibrium is attained, 4.5 moles of C is formed, what is the value of Kc for the reaction

a)

3

b)

1.8

c)

3.78

d)

5.4

9.

Kc value for decomposition of HF is 10–13 at 2000°C it means that

a)

Reactants are more stable

b)

Products are more stable

c)

Reactants are unstable

d)

Reactants and products are equally stable

10.

At equilibrium, relationship between concentrations of reactants and products

a)

[Reactants] > [Products]

b)

[Reactants] = [Products]

c)

[Reactants] < [Products]

d)

All are possible

11.

A2 +B2 2AB

If in the above reaction the value kf is 2.0 and kr is 0.1 then calculate the value of Kc for reaction

a)

2

b)

20

c)

0.1

d)

0.05

12.

For endothermic reaction, Ea is activation energy in kJ/mol. The maximum value of

enthalpy of reaction (ΔH) will be

a)

Less than Ea

b)

More than Ea

c)

Equal to Ea

d)

Zero

13.

In N2 + 3H2 2NH3 , the yield of product will be minimum if

a)

Temperature is increased and pressure remains same

b)

Temperature is increased and pressure is decreased

c)

Both temperature and pressure are increased

d)

Amount of catalyst is increased

14.

When 1 mole of HCl is added to 1 molar aqueous solution of H2S then

a)

pH of solution decreases

b)

S-2 ion concentration decreases

c)

Ionization of H2S decreases

d)

All of these

15.

Correct optimum conditions for synthesis of ammonia by Haber process

a)

200-300 atm, 400°C, Fe/MgO, Al2O3 and SiO2

b)

1-2 atm 400-500°C, V2O5

c)

200-300 atm, 650°C, Pt

d)

10-20atm, 200°C

16.

Which one will affect both equilibrium position and equilibrium constant?

a)

Pressure or volume change

b)

Concentration change

c)

Temperature change

d)

Catalyst

17.

Ksp values of four salts are given, which is least soluble in water

a)

10^-23

b)

10^-25

c)

10^-20

d)

10^-21

18.

The value of Kc for endothermic reversible reaction

a)

Increases with increase in temperature

b)

Decreases with increase in temperature

c)

Is independent of temperature

d)

No prediction can be made

19.

Select the buffer which is not acidic

a)

HCOOH and HCOONa

b)

NH4OH and NH4NO3

c)

CH3COOH and CH3COOK

d)

C6H5COONa and C6H5COOH

20.

A buffer is prepared by mixing the solutions of equimolar acetic acid and sodium

acetate. The pH should be equal to

a)

pKa of acid

b)

Less than pKa of acid

c)

Number of moles of acid

d)

More than pKa of acid

21.

Solubility product of a salt AB is 1.6×10^–7mol2/ dm^6, what will be its solubility(mol/dm^3)

a)

4×10^-4

b)

2×10^–4

c)

4×10^-8

d)

2×106-8

22.

Following is the condition of reversible reaction that is not affected by pressure

(where ∆n = number of moles of product–number of moles of reactants)

a)

∆n = 0

b)

∆n = 1

c)

∆n = -1

d)

∆n = 2

23.

In a reaction, A + B → Product, rate is doubled when the concentration of B is

doubled, and rate increases by a factor of 8 when the concentrations of both the

reactants A and B. are doubled, rate law for the reaction can be written as

a)

Rate = k [A][B]

b)

Rate = k [A]2[B]

c)

Rate = k [A]3[B]

d)

Rate = k [A][B]2

24.

When the change in concentration is 6×10^–5 moldm^-3 and time for that change is

100 seconds, the rate of reaction will be

a)

6×10^–3 moldm^–3

sec^–1

b)

6×10^–7 moldm^–3

sec^–1

c)

6×10^–4 moldm^–3

sec^-1

d)

6×10^–5 moldm^–3

sec^-1

25.

For reaction A+2B →C, if concentration of A and B is doubled, then rate of reaction

will increase

a)

4 times

b)

8 times

c)

6 times

d)

16 times

26.

Half-life of 1st order reaction A →B is 0.693/2

seconds its rate constant is

a)

0.231s–1

b)

2s–1

c)

4s–1

d)

20s–1

27.

Rate of first order reaction depends on ______

a)

Concentration of one reactant

b)

Concentration of two reactants

c)

Concentration of three reactants

d)

Independence of the initial concentration

28.

For which order of reaction rate constant has same units as rate of reaction

a)

First order reaction

b)

Third order reaction

c)

Second order reaction

d)

Zero order reaction

29.

Arrhenius equation describes the effect of

a)

Temperature on rate of reaction

b)

Volume on rate of reaction

c)

Pressure on rate of reaction

d)

Number of moles on rate of reaction

30.

Following first order reaction is 50 percent completed in 24 minutes at 300K

2N2O5 → 4NO2 + O2 [N2O5] given = 10g

How many grams of N2O5 will be left behind after 72 minutes?

a)

1.77g

b)

1.25g

c)

2.5g

d)

0.630g

31.

The rate expression of a reaction is, Rate = k[A][B]2

What happens to rate of reaction if concentrations of A and B are doubled?

a)

Increased two times

b)

Increased four times

c)

Increased eight times

d)

Increased nine times

32.

If Ef and Eb are the activation energies for forward and backward reaction

respectively. How these can be compared for the exothermic reaction.

a)

Ef > Eb

b)

Ef < Eb

c)

Ef = Eb

d)

No prediction can be made

33.

The units of second order rate constant are usually expressed as

a)

mole^1 dm^–3s–1

b)

mol–1 dm3s–1

c)

s–1

d)

mol–2 dm

34.

At zero activation energy (Ea) value of Arrhenius constant A is

a)

K

b)

K/2

c)

2K

d)

Zero

35.

For the following reaction 2A(g) + B(g) 3C(g). we can write

a)

Kc > Kp

b)

Kp – Kc = 0

c)

Kc < Kp

d)

Kp – Kc = -1

36.

Kp and Kc has following relationship Kp = Kc (RT) n

. Here n is equal to

a)

nP - nR

b)

nP + nR

c)

nP / nR

d)

nP nR

37.

If Ksp = [M+^2]3[X^-3]2

, the chemical formula of compound is

a)

MX2

b)

M2X3

c)

M3X2

d)

M2X

38.

Which relationship correctly represent that precipitation occurs.

a)

Ionic product > Ksp

b)

Ionic product < Ksp

c)

Ionic product = Ksp

d)

None of these

39.

The term common ion effect is used to describe the behavior of a solution in which

________ ion is produced by __________ compounds

a)

Same, different

b)

Different, same

c)

Same, same

40.

If Kc has every small value, the extent of reaction in the forward direction is

a)

Very small

b)

Very large

c)

Equal to backward reaction

d)

Reaction does not move in reverse direction

41.

All of the following methods are used to calculate the rate of reaction except one

a)

Optical rotation method

b)

Conductometric method

c)

Half-life method

d)

Spectrometric method

42.

Arrhenius equation describes the effect of

a)

Temperature on rate of reaction

b)

Volume on rate of reaction

c)

Pressure on rate of reaction

d)

Number of moles on rate of reaction

43.
a)

A

b)

B

c)

C

d)

D

44.
a)

A

b)

B

c)

C

d)

D

45.
a)

A

b)

B

c)

C

d)

D

46.
a)

A

b)

B

c)

C

d)

D

47.
a)

A

b)

B

c)

C

d)

D

48.
a)

A

b)

B

c)

C

d)

D

49.
a)

A

b)

B

c)

C

d)

D

50.
a)

A

b)

B

c)

C

d)

D