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AP Chem Unit 10 Mock Exam

Total questions: 30

Worksheet time: 45mins

Name
Class
Date
1.

Of the following molecules, which has the smallest dipole moment?

SELECT ALL THAT APPLY

a)

N2

b)

CH4

c)

HBr

d)

NO

2.
Which of the following could be the identity of a white crystalline solid that exhibits the following properties?
•It melts at 320° Celsius
•It does not conduct electricity as a solid.
•It conducts electricity in an aqueous solution.
a)

C6H12O6(s)

b)

NaOH(s)

c)

Cdiamond(s)

d)

Cu(s)

3.

Sigma AND Pi bonding occurs in each which of the following?

SELECT ALL THAT APPLY

a)

CO32-

b)

NH4+

c)

O2

d)

CH2O

4.

Which of the following best helps to explain why the value of ΔH° for the dissolving of CaF2 in water is positive?

SELECT ALL THAT APPLY

a)

Ca2+ ions have very strong ion-dipole interactions with water molecules in the solution, illustrated in Step 3.

b)

Ca2+ ions have very strong ion-ion interactions with F- ions in the crystal lattice, illustrated in Step 2.

c)

H2O molecules have strong dipole-dipole interactions known as hydrogen bonding, illustrated in Step 1.

5.

Which of the following steps in the solution process is the value of ΔH° for that step positive?

SELECT ALL THAT APPLY

a)

Step 1

b)

Step 2

c)

Step 3

6.

For which of the following molecules are resonance structures necessary to describe the bonding satisfactorily?

SELECT ALL THAT APPLY

a)

SO2

b)

SO3

c)

I3-

d)

H2O

7.

Organize the bond angles in H2O, NH3, and CH4. Explain.

a)

H2O < NH3 < CH4

Unshared pairs of electrons repel more strongly than bonded pairs.

b)

H2O < NH3 < CH4

The hybridization of the central atom decreases with decreased core charge.

c)

CH4 < NH3 < H2O

The hybridization of the central atom increases with increased core charge.

d)

CH4 < NH3 < H2O

Bonded pairs of electrons repel more strongly than unshared pairs.

8.
What is the hybridization at the atom indicated by the arrow in the following molecule?
a)
sp
b)
sp3 
c)
sp3d
d)
sp2
9.

Consider the molecule below. Determine the molecular geometry at each of the 2 labeled atoms.

a)

1 = tetrahedral

2 = bent

b)

1 = tetrahedral

2 = tetrahedral

c)

1 = trigonal planar

2 = bent

d)

1 = trigonal planar

2 = tetrahedral

10.
Why is I2 a solid while H2 is a gas at room temperature?
a)

I2 is more polarizable than H2 and, thus, have stronger London dispersion forces.

b)

I2 is less polarizable than H2 and, thus, have weaker London dispersion forces.

c)

I2 has a smaller permanent dipole than H2 and, thus, have weaker dipole-dipole forces.

d)

I2 has a larger permanent dipole than H2 and, thus, have stronger dipole-dipole forces.

11.

How do the molecular geometries and polarities of the two molecules compare?

a)

CO2 is linear and non-polar.

H2O is bent and polar.

b)

CO2 is linear and polar.

H2O is bent and non-polar.

c)

CO2 is linear and polar.

H2O is linear and polar.

d)

CO2 is bent and polar.

H2O is bent and polar.

12.

Consider the following ionic compounds BaO NaCl KCl MgO Order from lowest to highest melting point:

a)

KCl < NaCl < BaO < MgO

b)

KCl < NaCl < MgO < BaO

c)

MgO < BaO < KCl < NaCl

d)

NaCl < MgO < KCl < BaO

13.
Consider the following boiling point data and decide which liquid has the highest vapor pressure at room temperature:
a)
Water 
H2O
BP=100°C
b)
Methanol
 CH3OH
BP=64.96°C
c)
Ethanol
CH3CH2OH
BP=78.5°C
d)
Diethyl ether
CH3CH2–O–CH2CH3
BP=4.5°C
14.
Which of the following is a list of the compounds in order of increasing boiling points?
a)
Butane < 1-propanol < acetone
b)
Butane < acetone < 1-propanol
c)
1-propanol < acetone < butane
d)
Acetone = butane < 1-propanol
15.
Which of the following molecules are structural isomers?
a)
I and III 
b)
II and III
c)
III and IV 
d)
I and II
16.
The BF3 molecule is nonpolar, whereas the NF3 molecule is polar. Which of the following statements accounts for the difference in polarity of the two molecules?
a)
In NF3, each F is joined to N with multiple bonds, whereas in BF3 , each F is joined to
B with single bonds.
b)
N − F bonds are polar, whereas B − F bonds are nonpolar.
c)
NF3 is an ionic compound, whereas BF3 is a molecular compound.
d)
Unlike BF3, NF3 has a nonplanar geometry due to an unshared pair of electrons on the N atom.
17.
The electron-dot structure (Lewis structure) for which of the following molecules would have two  unshared pairs of electrons on the central atom?
a)
H2S
b)
NH3
c)
HCN
d)
CO2
18.
Based on formal charge, which Lewis structure best represents a sulfuric acid molecule?
a)
Structure A is the better structure because all of its atoms have a formal charge of zero. 
b)
Structure B is the better structure because all of its atoms have a formal charge of zero. 
c)
Structure A is the better structure because NOT all of its atoms have a formal charge of zero. 
d)
Structure B is the better structure because NOT all of its atoms have a formal charge of zero. 
19.
Which best represents the process on the heating curve of water at section 2 as one approaches section 3?
a)
The molecules are leaving the solid phase. 
b)
The liquid and gas phases are in equilibrium.
c)
The molecules are leaving the liquid phase.
d)
The boiling point of water is reached.
20.
What section on the heating curve of water represents the boiling point of water?
a)
2
b)
3
c)
4
d)
5
21.

In the reaction,

NO + O3 → NO2 + O2

the N atom in the NO molecule must strike a terminal O atom in the O3 molecule. Which of the diagrams below would most likely result in the formation of the products?

NO CALCULATOR:)

a)
b)
c)
d)
22.

For the reaction

2A + B → products

use the experimental data provided to determine the rate law.

a)

rate = k [A] [B] 

b)

rate = k [A]

c)

rate = k [A] [B]0 

d)

rate = k [A]2

23.

A 50.0mL sample of an acid, HA, of unknown molarity is titrated, and the pH of the resulting solution is measured with a pH meter and graphed as a function of the volume of 0.100M NaOH added. Based on the data, which of the following is the approximate molar concentration of the unknown acid, HA?

a)

0.0800M

b)

0.125M

c)

0.800M

d)

0.0125M

24.

Giant molecules, such as diamonds, in which each atom forms strong covalent bonds with all of its neighboring atoms lends what characteristics to covalent network substances?

SELECT ALL THAT APPLY

a)

Shared electrons.

b)

Low melting points.

c)

Very hard substances.

d)

Poor conductivity.

e)

Transfer of electrons to form ions.

25.

Which of the following would make a strong electrolyte when dissolved in water?

SELECT ALL THAT APPLY.

a)

CH3COCH3

b)

NaNO3

c)

C6H12O6

d)

HCl

26.

 Identify all types of intermolecular attractive forces present in pyridine.

a)

London Dispersion Forces

b)

Dipole-Dipole Attractions

c)

Hydrogen Bonding Attractions

d)

Ion-Dipole Attractions

27.

 Identify all types of intermolecular attractive forces present in benzene.

a)

London Dispersion Forces

b)

Dipole-Dipole Attractions

c)

Hydrogen Bonding Attractions

d)

Ion-Dipole Attractions

28.

Solubility of Pyridine in Water at 25oC

54.5g per 100mL of water

Solubility of Benzene in Water at 25oC

0.00452g per 100mL of water

Explain the solubility difference between pyridine and benzene in water.

a)

The intermolecular forces between molecules of pyridine and water must be STRONGER than the intermolecular forces between molecules of benzene of water because pyridine is MORE soluble than benzene in water.

b)

The intermolecular forces between molecules of pyridine and water must be STRONGER than the intermolecular forces between molecules of benzene of water because pyridine is LESS soluble than benzene in water.

c)

The intermolecular forces between molecules of pyridine and water must be WEAKER than the intermolecular forces between molecules of benzene of water because pyridine is MORE soluble than benzene in water.

d)

The intermolecular forces between molecules of pyridine and water must be WEAKER than the intermolecular forces between molecules of benzene of water because pyridine is LESS soluble than benzene in water.

29.

What is the strongest type of intermolecular or intramolecular attractive force that must be overcome for the decomposition of ammonia, NH3?

2NH3(g) → N2(g) + 3H2(g)

a)

Hydrogen Bonding Attractions

b)

Dipole-Dipole Attractions

c)

London Dispersion Forces Attractions

d)

Covalent Bonds

e)

Ion-Dipole Attractions

30.

What is the strongest type of intermolecular or intramolecular attractive force that must be overcome for the vaporization of ammonia, NH3?

NH3(l) → NH3(g)

a)

Hydrogen Bonding Attractions

b)

Dipole-Dipole Attractions

c)

London Dispersion Forces Attractions

d)

Covalent Bonds

e)

Ion-Dipole Attractions