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Exam #3 Review

Total questions: 29

Worksheet time: 55mins

Name
Class
Date
1.

Alkenes undergo

(a)  

2.

Carbocation Stability

a)

Tertiary

b)

Secondary

c)

Primary

1)
2)
3)
3.

Draw the mechanism

4.

​ Carbocation intermediates can be rearranged by two methods (a)   ,​ (b)  

Choose from the below words
1,2-hydride shifts
1,2-methyl shifts
1,4-hydride shifts
1,2-bromide shifts
1,1-methyl shifts
5.
Is this hydrocarbon saturated or unsaturated? 
a)
saturated
b)
unsaturated
6.
What type of molecule is it:
a)
alkene
b)
alkyne
c)
alkane
d)
amino acid
7.

Why can carbon combine with itself to make substances that have very different properties? (ex. graphite and diamond).

a)

Because of carbon's 4 valence electrons it can form a variety of bonds with other carbons.

b)

Because carbon is polar it can combine in a variety of ways.

c)

Because carbon will either give or take 4 electrons so it can form various substances

d)

Because carbon forms cations it combines in various ways.

8.

Name the following compound

a)

Benzene

b)

Benzol

c)

Phenyl

d)

Phenol

9.
Name this structure.
a)
1,2,4-dimethylcyclopentane
b)
1,2,4-trimethylcyclopentane
c)
1,3,4-trimethylcyclopentane
d)
1,3,4-dimethylcyclopentane
10.

Use your understanding of the bonding in benzene to identify the compound that has the most exothermic enthalpy of hydrogenation.

a)
b)
c)
d)
11.

Why does aromatic compounds prefer to undergo electrophilic substitution reaction?

a)

Aromatic compounds are electron rich so they attract electrophiles

b)

Aromatic compounds are electron rich so they attract nucleophiles

c)

Aromatic compounds are electron poor so they attract electrophiles

d)

Aromatic compounds are electron poor so they attract nucleophiles

12.
a)

Aromatic

b)

Anti-aromatic

c)

Non-aromatic

13.

a)

Aromatic

b)

Anti-Aromatic

c)

Non-Aromatic

14.

a)

Aromatic

b)

Anti-Aromatic

c)

Non-aromatic

15.

Name the structure shown in the image:

a)

But-1-ene

b)

But-4-yne

c)

But-2-yne

d)

But-1-yne

16.

What is the expected product?

a)
b)
c)
d)
17.

What is the expected product?

a)
b)
c)
d)
18.

Which conditions produce an aldehyde?

a)
b)
c)
d)
19.

Under which conditions might you see evidence of carbocation rearrangement?

a)

1. O3, 78 °C-78\ \degree C  

2. CH3SCH3

b)

1. BH3-THF

2. H2O2, NaOH

c)

HBr

d)

1. Hg(OAc)2, H2O

2. NaBH4

20.

Which is the expected product?

a)
b)
c)
d)
21.

"full"

a)

saturated

b)

unsaturated

c)

supersaturated

d)

aqueous

22.

"not full"

a)

saturated

b)

unsaturated

c)

supersaturated

d)

aqueous

23.

Is this showing an endothermic or an exothermic reaction?

a)

Endothermic

b)

Exothermic

24.

Which letter represents the products?

a)

A

b)

B

c)

C

d)

D

e)

E

25.

Which letter represents the transition state?

a)

A

b)

B

c)

C

d)

D

e)

E

26.

Hydroboration-oxidation is overall a --- addition of water

(a)  

27.

The hydroboration of an internal alkyne creates a ---, of a terminal alkyne creates a ---

4 lines
28.

Conjugated double bond are separated by...

a)

two single bonds

b)

one double bond

c)

one single bond

d)

two double bonds

29.

Diels-Alder reactions occur within conjugated dienes.

a)

True

b)

False