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Unit 10 Review

Total questions: 19

Worksheet time: 27mins

Name
Class
Date
1.

What is the enthalpy change when 2 mol of CaO reacts completely with water?

a)

-127 kJ

b)

+127 kJ

c)

-63.5 kJ

d)

+63.5 kJ

2.

Which thermochemical equation is the most correct equivalent to the chemical reaction and enthalpy given?

a)

CaO (s) + H2O (l) - 65.3kJ → Ca(OH)2

b)

CaO (s) + H2O (l) - 65.3kJ → Ca(OH)2

c)

CaO (s) + H2O (l) + 65.3kJ → Ca(OH)2

d)

CaO (s) + H2O (l) → Ca(OH)2 + 65.3kJ

3.

Which of the following can be concluded from this thermochemical equation?

a)

The products of this reaction have more potential energy than the reactants.

b)

The formation of calcium hydroxide is an endothermic process.

c)

The total bond energies associated with forming bonds is greater than the total bond energies associated with breaking bonds.

d)

63.5 kJ of heat must be absorbed from the surroundings for every 1 mole of calcium hydroxide formed.

4.

A certain amount of 15.75 kJ of heat is needed to increase the temperature of 150.0g of a liquid hydrocarbon from 25.0°C to 55.0°C. Calculate the specific heat capacity of this hydrocarbon using the appropriate formula.

a)

1.26 J/g°C

b)

0.84 J/g°C

c)

2.10 J/g°C

d)

3.15 J/g°C

5.

What occurs energetically when solid A, at 100.0°C, is placed in liquid B, at 80.0°C?

a)

Heat energy flows from A to B as the average kinetic energy of the particles in solid A decreases.

b)

Heat energy flows from A to B as the average kinetic energy of the particles in solid A increases.

c)

Heat energy flows from B to A as the average kinetic energy of the particles in liquid B increases.

d)

Heat energy flows from B to A as the average kinetic energy of the particles in liquid B decreases.

6.

Which of the following changes to a chemical system would increase the rate of a reaction?

a)

Place the reaction vessel in a cooler

b)

Use large chunks of solid reactant instead of fine powder.

c)

Change the concentration of the reactants from 0.1 M to 1 M.

d)

Decrease the catalyst concentration

7.

Calculate the ΔH_rxn in units of kJ/mol given the table of bond energies for the reaction: Br2 (g) + 3 F2 (g) → 2 BrF3 (g).

a)

-516 kJ/mol

b)

-410 kJ/mol

c)

-611 kJ/mol

d)

-720 kJ/mol

8.

Ice cubes are placed in a glass of water that is at room temperature. Which statement BEST describes the temperature of the water after 10 minutes?

a)

The temperature decreases because some of the water's heat is lost to the ice.

b)

The temperature increases because some of the coolness of the water is absorbed by the ice.

c)

The temperature decreases because some of the ice's heat is lost to the water.

d)

The temperature increases because some of the coolness of the ice is absorbed by the water.

9.

Which of the following is TRUE with respect to the collision theory of chemical reactions?

a)

Every collision of reactant molecules in a reaction vessel creates a product.

b)

Reactions that occur at a faster rate overall have a higher proportion of effective collisions.

c)

Reactions that occur at a slower rate have a lower proportion of ineffective collisions.

d)

A catalyst increases the proportion of ineffective collisions to increase the rate of reaction.

10.

The graph shows a typical energy distribution for particles of an ideal gas in a sealed container at a fixed temperature. Which of the following statements is TRUE?

a)

The area under the curve to the right of E_a represents the number of molecules with enough energy to react.

b)

The area under the curve to the left of E_a represents the number of molecules with enough energy to react.

c)

Adding a catalyst to the reaction would shift E_a to the right.

d)

Adding a catalyst to the reaction would lower the height of the peak and shift the peak right.

11.

Use the Maxwell-Boltzmann Distribution diagram provided to determine which curve, Ta or Tb, represents the sample of dinitrogen monoxide gas particles AFTER the gases have cooled. Justify your answer.

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12.

What would the Maxwell-Boltzmann curve look like for oxygen gas (O2) at the same temperature as Tb?

a)

It would be steeper and shift left

b)

It would be steeper and shift right

c)

It would be flatter and shift left

d)

It would be flatter and shift right

13.

Using the reaction coordinate diagram provided, determine the enthalpy of reaction. Include units in your answer

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14.

Using evidence from the reaction coordinate diagram, explain whether this chemical reaction has more energy associated with breaking bonds or forming bonds. Justify your answer using reasoning.

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15.

Write the thermochemical equation for the reaction shown in the diagram. Include the reactants, the products, and enthalpy in your balanced chemical equation.

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16.

What would the curve on the reaction coordinate diagram look like for this process with the addition of a catalyst?

a)

The potential energy of the reactants would increase

b)

The potential energy of the products would increase

c)

The peak of the curve would move down

d)

The curve of the peak would move up

17.

Explain how thermal energy is transferred during the process of calorimetry. Draw an arrow either from the metal to the water or from the water to the metal on the calorimetry set up shown to support your answer.

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18.

The data in the table above was collected during the calorimetry experiment. Determine the specific heat of the unknown metal using the data provided. Remember to use the equations in your Reference Packet to determine your answer. Round your answer to the nearest tenths place (0.1).

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19.

In this calorimetry experiment, the change in temperature of the water is drastically different than the change in temperature of the metal. The water changed approximately 4°C. In the same trial the metal changed over 70°C. Since the amount of heat transferred from one substance to another in calorimetry is assumed to be the same, why is the change in temperature so different for metal and water? Explain your answer with evidence and reasoning.

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