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AP Chem 5.5,5.6,5.7 Review

Total questions: 43

Worksheet time: 1hrs 6mins

Name
Class
Date
1.

What is required for two molecules to react according to collision theory?

a)

They must be in the same state of matter.

b)

They must have enough energy to disrupt existing bonds.

c)

They must be of the same size.

d)

They must be in a vacuum.

2.

What is the main focus of collision theory in chemistry?

a)

The speed of light

b)

The interaction of molecules

c)

The color of compounds

d)

The weight of atoms

3.

According to collision theory, what must reacting particles do for a chemical reaction to occur?

a)

Absorb light

b)

Collide with one another

c)

Change color

d)

Emit sound

4.

What is the role of activation energy in a chemical reaction?

a)

It slows down the reaction

b)

It provides the necessary energy for the reaction to occur

c)

It changes the color of the reactants

d)

It emits light during the reaction

5.

Which of the following is a condition for a successful reaction according to the theory?

a)

High temperature with molecules moving in circles.

b)

Sufficient energy and proper orientation

c)

Low energy and heavy molecules.

d)

molecules that are friendly

6.

What is the likelihood of bond breakage upon collision when temperature increases?

a)

It decreases.

b)

It remains the same.

c)

It greatly increases.

d)

It becomes impossible.

7.

What does the shaded area under the Maxwell Boltzmann Curve represent?

a)

Molecules with insufficient energy to react

b)

Molecules with enough energy to react

c)

Molecules at equilibrium

d)

Molecules with zero energy

8.

What is the effect of temperature on the number of collisions according to the Maxwell Boltzmann Curve?

a)

Temperature has no effect

b)

Temperature decreases the number of collisions

c)

Temperature increases the number of collisions

d)

Temperature stabilizes the number of collisions

9.

Which curve in the diagram above represents the reaction occurring at the lowest temperature?

a)

blue curve

b)

green curve

c)

purple curve

10.

What effect will increasing [H⁺] at constant temperature have on the reaction below? Cl⁻(aq) + ClO⁻(aq) + 2H⁺(aq) → Cl₂(g) + H₂O(l)

a)

The activation energy of the reaction will increase.

b)

The activation energy of the reaction will decrease.

c)

The frequency of collisions between H⁺(aq) ions and ClO⁻(aq) ions will increase.

d)

The value of the rate constant will increase.

11.
Under the collision theory, the particles must collide with  ____ and ____ for a reaction to occur.
a)
sufficient rate and sufficient energy
b)
sufficient surface area and correct orientation
c)
sufficient catalyst and sufficient energy
d)
sufficent energy and correct orientation
12.

What did the principal say when oxygen, hydrogen, sulfur, sodium, and phosphorous walked into the school?

a)

Take off your hat please.

b)

Go Clippers!

c)

Where is your ID?

d)

OH SNaP

13.

Which one of the following is NOT a key concept of the collision theory:

a)

particles must collide in order to react

b)

particles must move slowly when they collide, otherwise they simply “bounce off” one another

c)

particles must collide with the proper orientation

d)

particles must collide with sufficient energy to reach the activated complex in order to react

14.

Which species in the mechanism below is the intermediate?


A + B → C + D Fast

D + E → F + B Slow

a)

A

b)

B

c)

C

d)

D

15.

How many intermediates are in the following rate mechanism?

a)

0

b)

1

c)

2

d)

3

16.

The reaction represented by this energy profile is _____________

because the ____________________ have more energy than the __________________.

a)

exothermic, reactants, products

b)

endothermic, reactants, products

c)

exothermic, products, reactants

d)

endothermic, products, reactants

17.

Which vertial line represents activation energy Ea?

a)

A

b)

B

c)

C

d)

D

18.

When temperature is increased, the reaction increases due to ....

a)

fewer collisions of particles.

b)

moleclues moving faster causing more successful collisions.

c)

molecules moving slower and having more time to collide.

d)

a greater concentration of reactants.

19.
More collisions correspond to a: 
a)
Faster reaction rate  
b)
Slower reaction rate
c)
Constant reaction rate 
d)
None of the above
20.

What is activation energy?

a)

The change in energy between reactants and products

b)

The minimum amount of energy required for a reaction to start

c)

The energy of the reactants

d)

The energy possessed by the products

21.

For all reactions, which letter represents the REACTANTS?

a)

A

b)

B

c)

C

d)

D

22.

Which PE Diagram represents an endothermic reaction?

a)

A

b)

B

23.

Decreasing the concentration of a substance will usually........

a)

Slow down the reaction

b)

Speed up the reaction

c)

Have no affect on the reaction

24.
Consider the following energy profile diagram for a reaction represented by the equation X+Y→Z
Which one of the following provides the correct values of the activation energy (in kJ mol-1) and the ΔH (in kJ mol-1) for the reaction
a)
Activation Energy = +75; ΔH = +100 
b)
Activation Energy = +100; ΔH = +175
c)
Activation Energy = +175; ΔH = +100
d)
Activation Energy = +200; ΔH = -125
25.

Which letter represents the transition state?

a)

A

b)

B

c)

C

d)

D

e)

E

26.

Which letter corresponds to the activation energy of the forward reaction?

a)

A

b)

B

c)

C

d)

D

27.

Which of the following best describes activation energy?

a)

The energy released during a reaction

b)

The energy required to start a reaction

c)

The energy absorbed during a reaction

d)

The energy at the end of a reaction

28.

In an endothermic reaction, the energy profile diagram shows:

a)

Products having higher energy than reactants

b)

Reactants having higher energy than products

c)

No change in energy between reactants and products

d)

Energy being released to the surroundings

29.

Which of the following is true for an exothermic reaction?

a)

The energy of the products is higher than the energy of the reactants

b)

The energy of the reactants is higher than the energy of the products

c)

The energy of the reactants and products are equal

d)

The reaction absorbs energy from the surroundings

30.

Which curve shown here represents N2O at a higher temperature?

a)

TA

b)

TB

c)

Neither curve

31.

Which gas molecule has the highest average velocity at a constant temperature? Hint: Lighter particles move faster.

a)

O2

b)

H2O

c)

H2

d)

Xe

32.

Which temperature has the highest average particle speed?

a)

- 100 C

b)

100 C

c)

500 C

d)

The particle speed is constant

33.

How would a catalyst affect the diagram below?

a)

The hill would be smaller.

b)

The activation energy live would shift to the right.

c)

The activiation energy line would shift to the left.

d)

Nothing would change.

34.

In this reaction mechanism, what is the catalyst?


NO + O3
\rightarrow NO2 + O2

O3 \rightarrow O2 + O

NO2 + O \rightarrow NO + O2

a)

NO

b)

O3

c)

NO2

d)

O

35.

In this reaction mechanism, what are

the intermediate(s)?


NO + O3
\rightarrow NO2 + O2

O3 \rightarrow O2 + O

NO2 + O \rightarrow NO + O2

a)

NO and O3

b)

O and O3

c)

NO2 and O2

d)

NO2 and O

e)

NO and O

36.

What is the overall change in enthalpy for this reacton energy profile?

a)

-60 kJ

b)

+25 kJ

c)

+5 kJ

d)

-8 kJ

e)

+20 kJ

37.

Which letter represents the change in enthalpy of this reaction?

a)

A

b)

B

c)

C

d)

D

e)

E

38.

In this two step reaction, is the second step exothermic or endothermic?

a)

exotheromic

b)

endothermic

39.

What is the activation energy of the first step in this reaction energy profile?

a)

-18 kJ

b)

+18 kJ

c)

+13 kJ

d)

-5 kJ

40.

Why did the bear dissolve in water?

a)

It was a grizzle bear.

b)

It was a panda bear.

c)

It was a polar bear.

41.

If a reaction energy profile has a taller ‘hill’ (or activation energy) then this step in the reaction reaction is ____________________?

a)

Faster

b)

Slower

42.

What does the dashed curve represent in this diagram?

a)

the moles of reactants

b)

the presence of an intermediate

c)

the Δ\Delta H of the overall reaction

d)

the presence of a catalyst

43.

One more from the 9.2 Edpuzzle!

Which equation would be used to find the change in entropy?

a)

b)

c)

d)