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CHM 101 Exam Practice Problems

Total questions: 20

Worksheet time: 33mins

Name
Class
Date
1.

1. The standard reduction potential of two half cell are: Zn++ + 2e- = Zn ; Eo = -0.76V 2Ag+ + 2e- = 2Ag Eo = +0.80V. The cell voltage for the electrochemical cell formed by connecting two half cell is ;

a)

+0.04V

b)

+1.56V

c)

-2.36V

d)

-1.50V

2.

Hydrolysis is reverse of (a)  

3.

The ∆Eo for the reaction: Fe + Zn++ = Zn + Fe++ is -0.32. The equilibrium constant for the reaction is

a)

1.4x10-11

b)

2.8x10-11

c)

1.5x10-4

d)

1.8x10-12

4.

If half reaction is multiplied by a positive number, its electrode potential:

a)

Increases by two times

b)

Increases by four times

c)

Remains unchanged

d)

Becomes half of its initial

5.

In galvanic cell, which statement is not true?

a)

Oxidation occurs at anode

b)

Reduction occurs at cathode

c)

Electrical energy produces the chemical reaction

d)

Chemical reaction produces the electrical energy

6.

Greater the reduction potential, greater is its tendency to be …………………and can be used as …… (a)  

7.

In the lead storage battery:

a)

A reversible reaction can occur to recharge the battery

b)

Lead is oxidized to create a flow of electrons

c)

Lead forms the cathode when it is being reduced

d)

All of the above

8.

A concentration cell is constructed by placing identical Zn electrodes in two Zn2+ solutions. If the concentrations of the two Zn2+ solutions are 0.10 M and 0.00010 M, respectively, what is the potential of the cell?

a)

+ 0.763 V

b)

+ 0.089 V

c)

+ 0.053 V

d)

+ 0.24 V

9.

Given the reaction: Pb(s) + Cu2+(aq) → Pb2+(aq) + Cu(s). What is the reducing agent?

a)

Pb2+(aq)

b)

Cu2+(aq)

c)

Pb(s)

d)

Cu(s)

10.

In an electrolytic cell, the charge on the electrode that gives electrons to the species in solution is _____; the chemical change that occurs at this electrode is called _______.

(a)  

11.

Which of the following statements associated with corrosion is incorrect?

a)

iron corrodes more readily than aluminium because iron is more active than aluminium

b)

cathodic protection prevents corrosion by using a sacrificial anode

c)

a corroding metal has both anodic and cathodic areas

d)

corrosion involves both oxidation and reduction

12.

The concentration of [H3O+] in the equilibrium with pure solution of NH4Cl whose chloride concentration is 0.1M, is [ Given, Kh = 5.6x10-10]

a)

8.5x10-5M

b)

1.2x10-6M

c)

5.5x10-2M

d)

7.5x10-6M

13.

If the solubility of Ag2 CrO4 in pure water is 0.78 x 10-4 M then its solubility in 0.05 M AgNO3 is:

a)

7.9 × 10-8 M

b)

2.8 × 10-9 M

c)

7.2 × 10-7 M

d)

7.6 × 10-10 M

14.

Which one of the following sets produces the precipitate of CaF2 (Ksp = 1.7x10-10), when equal volumes of followings are mixed?

a)

10-4 M Ca2+ and 10-4 M F-

b)

10-5 M Ca2+ and 10-3 M F-

c)

10-2 M Ca2+ and 10-3 M F-

d)

10-3 M Ca2+ and 10-5 M F-

15.

Which of the following has pH above seven?

a)

NH4Cl solution

b)

NaCl solution

c)

CuSO4 solution

d)

CH3COONa solution

16.

The pH of a buffer solution which contains 0.6 M NH4OH and 2 M NH4Cl is………… ………………. (Given, Kb for NH3 = 1.8x10-5)

(a)  

17.

The conjugate acid of the HPO4 - - is conjugate acid ……..

(a)  

18.

The best indicator for titrating HCl with NH4OH is

a)

litmus

b)

phenolphthalein

c)

methyl orange

d)

phenol red

19.

All nucleophiles are

a)

Arrhenius acid

b)

Lowry-Bronsted bases

c)

Lewis acids

d)

Lewis bases

20.

Weaker the acid, greater is the

a)

ionic product

b)

dissociation constant

c)

hydrolysis constant

d)

degree of ionization